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\(m_{ddNaCl}=25+100=125\left(g\right)\\ C\%_{ddNaCl}=\dfrac{25}{125}.100=20\%\\ \Rightarrow ChọnB\)
PTHH: \(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)
\(FeCl_2+2NaOH\rightarrow Fe\left(OH\right)_2\downarrow+2NaCl\)
Ta có: \(n_{Fe\left(OH\right)_2}=\dfrac{18}{90}=0,2\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{NaOH}=0,4\left(mol\right)\\n_{H_2}=0,2\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}V_{H_2}=0,2\cdot22,4=4,48\left(l\right)\\C\%_{NaOH}=\dfrac{0,4\cdot40}{160}\cdot100\%=10\%\end{matrix}\right.\)
\(n_{Na_2O}=\dfrac{12,4}{62}=0,2mol\)
\(Na_2O+H_2O\rightarrow2NaOH\)
0,2 \(\rightarrow\) 0,2 \(\rightarrow\) 0,4
\(C_{M_{NaOH}}=\dfrac{0,4}{\dfrac{500}{1000}}=0,8M\)
a) - Dung dịch A chứa chất tan NaOH
mddNaOH= 200(g)
=> C%ddNaOH= (4/200).100=2%
\(n_{CO_2}=\dfrac{V}{22,4}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\\ n_{NaOH}=\dfrac{m}{M}=\dfrac{m_{dd}.C\%}{M}=\dfrac{200.16\%}{40}=0,8\left(mol\right)\)
Có: \(\dfrac{n_{NaOH}}{n_{CO_2}}=4\)
=> Phản ứng tạo muối Na2CO3
PT:
\(CO_2+2NaOH\rightarrow Na_2CO_3+H_2O\)
0,2. 0,4 0,2
=> dd sau phản ứng có những chất tan là:
\(\left\{{}\begin{matrix}Na_2CO_3:0,2\left(mol\right)\\NaOH:0,4\left(mol\right)\end{matrix}\right.\)
mdd spu=0,2.44+200=208,8(g)
\(\%m_{NaOH}=\dfrac{0,4.40}{208,8}.100\%=7,66\%\\\%m_{Na_2CO_3}=\dfrac{0,2.106}{208,8}.100\%=10,15\% \)
Câu 1:
nAl= 0,1(mol)
PTHH: 2Al + 6 HCl -> 2 AlCl3 + 3 H2
nAlCl3= nAl=0,1(mol)
-> mAlCl3= 133,5 x 0,1= 13,35(g)
mddAlCl3= mAl + mddHCl - mH2 = 2,7 + 200 - 3/2 x 0,1 x 2= 202,4(g)
C%ddAlCl3= (13,35/202,4).100= 6,596%
Câu 1:
PTHH: \(Na_2O+H_2O\rightarrow2NaOH\)
\(2NaOH+CuSO_4\rightarrow Na_2SO_4+Cu\left(OH\right)_2\downarrow\)
\(Cu\left(OH\right)_2\xrightarrow[]{t^o}CuO+H_2O\)
a) Ta có: \(n_{NaOH}=2n_{Na_2O}=2\cdot\dfrac{12,4}{62}=0,4\left(mol\right)\)
\(\Rightarrow C\%_{NaOH}=\dfrac{0,4\cdot40}{12,4+193,8}\cdot100\%\approx7,76\%\)
b) Ta có: \(\left\{{}\begin{matrix}n_{NaOH}=0,4\left(mol\right)\\n_{CuSO_4}=\dfrac{100\cdot16\%}{160}=0,1\left(mol\right)\end{matrix}\right.\)
Xét tỉ lệ: \(\dfrac{0,4}{2}>\dfrac{0,1}{1}\) \(\Rightarrow\) NaOH còn dư, CuSO4 p/ứ hết
\(\Rightarrow n_{CuO}=n_{Cu\left(OH\right)_2}=n_{CuSO_4}=0,1\left(mol\right)\)
\(\Rightarrow m_{CuO}=0,1\cdot80=8\left(g\right)\)
Bài 2 :
a)
$Cu + 2H_2SO_{4_{đặc}} \to CuSO_4 + SO_2 + 2H_2O$
$n_{Cu} = n_{SO_2} = \dfrac{2,24}{22,4} = 0,1(mol)$
$\%m_{Cu} = \dfrac{0,1.64}{15}.100\% = 42,67\%$
$\%m_{CuO} = 100\% -42,67\% = 57,33\%$
b)
$NaOH + SO_2 \to NaHSO_3$
$n_{NaOH} = n_{SO_2} = 0,1(mol)$
$\Rightarrow V_{dd\ NaOH} = \dfrac{0,1}{1} = 0,1(lít) = 100(ml)$
Chọn C