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![](https://rs.olm.vn/images/avt/0.png?1311)
\(n_{MgCO_3}=\dfrac{12,6}{84}=0,15\left(mol\right)\)
\(MgCO_3+2HCl\rightarrow MgCl_2+H_2O+CO_2\)
0,15 0,15
\(V_{CO_2}=0,15.22,4=3,36\left(l\right)\)
--> A
![](https://rs.olm.vn/images/avt/0.png?1311)
$CaCO_3 + 2HCl \to CaCl_2 + CO_2 + H_2O$
$n_{CO_2} = n_{CaCO_3} = \dfrac{50}{100} = 0,5(mol)$
$V_{CO_2} = 0,5.22,4 = 11,2(lít)$
Đáp án A
![](https://rs.olm.vn/images/avt/0.png?1311)
\(Ba+2HCl \to BaCl_2+H_2\\ n_{Ba}=\frac{13,7}{137}=0,1(mol)\\ n_{H_2}=n_{Ba}=0,1(mol)\\ V_{H_2}=0,1.22,4=2,24(l)\\ \text{Vậy chon đáp án C }\)
![](https://rs.olm.vn/images/avt/0.png?1311)
2CH3COOH+CaCO3-to>(CH3COO)2Ca+H2O+CO2
0,4-----------------0,2----------------------------------------0,2
2CH3COOH+CaO->(CH3COO)2Ca+H2O
0,1----------------0,05
n CO2=0,2 mol
=>%m CaCO3=\(\dfrac{0,2.100}{22,8}100=87,72\%\)
=>%m CaO=12,28%
=>n CaO=0,05 mol
=>VCH3COOH=\(\dfrac{0,5}{2}=0,25l\)
a)
\(n_{CO_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
PTHH: CaCO3 + 2CH3COOH --> (CH3COO)2Ca + CO2 + H2O
0,2<---------0,4<------------------------------0,2
=> \(m_{CaCO_3}=0,2.100=20\left(g\right)\)
=> \(\left\{{}\begin{matrix}\%m_{CaCO_3}=\dfrac{20}{22,8}=87,72\%\\\%m_{CaO}=100\%-87,72\%=12,28\%\end{matrix}\right.\)
b)
\(n_{CaO}=\dfrac{22,8-20}{56}=0,05\left(mol\right)\)
PTHH: CaO + 2CH3COOH --> (CH3COO)2Ca + H2O
0,05---->0,1
=> \(V_{dd.CH_3COOH}=\dfrac{0,1+0,4}{2}=0,25\left(l\right)\)
c) \(\left\{{}\begin{matrix}n_{CH_3COOH}=\dfrac{a}{60}\left(mol\right)\\n_{C_2H_5OH}=\dfrac{1,5a}{46}\left(mol\right)\\n_{CH_3COOC_2H_5}=\dfrac{1,2a}{88}\left(mol\right)\end{matrix}\right.\)
PTHH: CH3COOH + C2H5OH --H2SO4(đ),to--> CH3COOC2H5 + H2O
Xét tỉ lệ: \(\dfrac{\dfrac{a}{60}}{1}< \dfrac{\dfrac{1,5a}{46}}{1}\) => HIệu suất tính theo CH3COOH
\(n_{CH_3COOH\left(pư\right)}=\dfrac{1,2a}{88}\left(mol\right)\)
=> \(H=\dfrac{\dfrac{1,2a}{88}}{\dfrac{a}{60}}.100\%=81,82\%\)
a
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