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a) nFe= 16/56 =~ 0,3 mol
mH2S04 =( C% .mdd ) /100%= ( 20.100) /100 = 20g
nH2SO4 = 20/98 =~ 0,2mol
lập pthh của pu
Fe + H2SO4 ----------> FeSO4 + H2
1mol 1mol 1mol 1mol
0,3mol 0,2mol
xét tỉ lệ nFe dư sau pư vậy tính theo mol H2SO4
nFe (pư) = (0,2 .1 )/1 =0,2mol
nFe (dư) = 0,3 -0,2 =0,1mol
mFe dư = 0,1 . 56 = 5,6 g
mFeSO4 = 0,2 .152 = 30,4 g
b) mdd sau pư = mFe + m dung môi = 16 +100=116 g
c% Fe = (5,6 / 116) .100%=~ 4,83%
c% FeSO4 =(30,4/116).100%=~ 26,21%
a) đối 200ml =0,2 lít
CMFe =n/v = 0,1 / 0,2 =0,5 mol/lít
CMFeSO4 =n/v = 0,2/0,2=1 mol /lít
\(n_{Fe_2O_3}=\dfrac{8}{160}=0,05\left(mol\right)\)
PTHH: Fe2O3 + 3H2SO4 --> Fe2(SO4)3 + 3H2O
______0,05------>0,15--------->0,05
=> mH2SO4 = 0,15.98 = 14,7(g)
=> \(C\%\left(H_2SO_4\right)=\dfrac{14,7}{100}.100\%=14,7\%\)
\(C\%\left(Fe_2\left(SO_4\right)_3\right)=\dfrac{0,05.400}{8+100}.100\%=18,52\%\)
PTHH: Fe2(SO4)3 + 6NaOH --> 2Fe(OH)3\(\downarrow\) + 3Na2SO4
________0,05----------------------->0,1
=> mFe(OH)3 = 0,1.107=10,7(g)
Ta có: \(n_{Fe_2O_3}=\dfrac{9,6}{160}=0,06\left(mol\right)\)
a. PTHH: Fe2O3 + 3H2SO4 ---> Fe2(SO4)3 + 3H2O (1)
Theo PT(1): \(n_{H_2SO_4}=3.n_{Fe_2O_3}=3.0,06=0,18\left(mol\right)\)
=> \(m_{H_2SO_4}=0,18.98=17,64\left(g\right)\)
Ta có: \(C_{\%_{H_2SO_4}}=\dfrac{17,64}{m_{dd_{H_2SO_4}}}.100\%=9,8\%\)
=> \(m_{dd_{H_2SO_4}}=180\left(g\right)\)
b. Ta có: \(m_{dd_{Fe_2\left(SO_4\right)_3}}=9,6+180=189,6\left(g\right)\)
Theo PT(1): \(n_{Fe_2\left(SO_4\right)_3}=n_{Fe_2O_3}=0,06\left(mol\right)\)
=> \(m_{Fe_2\left(SO_4\right)_3}=0,06.400=24\left(g\right)\)
=> \(C_{\%_{Fe_2\left(SO_4\right)_3}}=\dfrac{24}{189,6}.100\%=12,66\%\)
c. PTHH: Fe2(SO4)3 + 3BaCl2 ---> 3BaSO4↓ + 2FeCl3 (2)
Theo PT(2): \(n_{BaSO_4}=3.n_{Fe_2\left(SO_4\right)_3}=3.0,06=0,18\left(mol\right)\)
=> \(m_{BaSO_4}=0,18.233=41,94\left(g\right)\)
Theo PT(2): \(n_{BaCl_2}=n_{BaSO_4}=0,18\left(mol\right)\)
=> \(m_{BaCl_2}=0,18.208=37,44\left(g\right)\)
Ta có: \(C_{\%_{BaCl_2}}=\dfrac{37,44}{m_{dd_{BaCl_2}}}.100\%=10,4\%\)
=> \(m_{dd_{BaCl_2}}=360\left(g\right)\)
Ta có: \(n_{ZnO}=\dfrac{16,2}{81}=0,2\left(mol\right)\)
a, PT: \(ZnO+2HCl\rightarrow ZnCl_2+H_2O\)
______0,2_____0,4____0,2 (mol)
b, \(m_{HCl}=0,4.36,5=14,6\left(g\right)\Rightarrow m_{ddHCl}=\dfrac{14,6}{10\%}=146\left(g\right)\)
c, \(C\%_{ZnCl_2}=\dfrac{0,2.136}{16,2+146}.100\%\approx16,77\%\)
Bạn tham khảo nhé!
\(n_{CuO}=\dfrac{1.6}{80}=0.02\left(mol\right)\)
\(n_{H_2SO_4}=\dfrac{100\cdot20\%}{98}=\dfrac{10}{49}\left(mol\right)\)
\(CuO+H_2SO_4\rightarrow CuSO_4+H_2O\)
\(1...........1\)
\(0.02..........\dfrac{10}{49}\)
\(LTL:\dfrac{0.02}{1}< \dfrac{10}{49}\Rightarrow H_2SO_4dư\)
\(m_{\text{dung dịch sau phản ứng}}=1.6+100=101.6\left(g\right)\)
\(C\%_{CuSO_4}=\dfrac{0.02\cdot160}{101.6}\cdot100\%=3.15\%\)
\(C\%_{H_2SO_4\left(dư\right)}=\dfrac{\left(\dfrac{10}{49}-0.02\right)\cdot98}{101.6}\cdot100\%=17.75\%\)
a) PTHH: CuO + H2SO4 → CuSO4 + H2O (1)
b) \(n_{CuO}=\dfrac{16}{80}=0,2\left(mol\right)\)
Theo PT1: \(n_{H_2SO_4}=n_{CuO}=0,2\left(mol\right)\)
\(\Rightarrow m_{H_2SO_4}=0,2\times98=19,6\left(g\right)\)
\(\Rightarrow C\%_{ddH_2SO_4}=\dfrac{19,6}{400}\times100\%=4,9\%\)
c) Theo PT1: \(n_{CuSO_4}=n_{CuO}=0,2\left(mol\right)\)
\(\Rightarrow m_{CuSO_4}=0,2\times160=32\left(g\right)\)
\(\Sigma m_{dd}=16+400=416\left(g\right)\)
\(\Rightarrow C\%_{ddCuSO_4}=\dfrac{32}{416}\times100\%=7,69\%\)
d) CuSO4 + BaCl2 → BaSO4↓ + CuCl2 (2)
Theo PT2: \(n_{BaSO_4}=n_{CuSO_4}=0,2\left(mol\right)\)
\(\Rightarrow m_{BaSO_4}=0,2\times233=46,6\left(g\right)\)
Vậy m=46,6
n Cu = 1,6 / 80 = 0,02 mol
mH2SO4= (20*100)/100=20g => nH2SO4= 20/98=0.204mol
a)CuO + H2SO4--> CuSO4 + H2O
0.02 0.204 0.204
=> Tỉ lệ: 0,02/1 < 0,204/1
=> H2SO4 dư ,nH2SO4 dư = 0,204 - 0,02 = 0,182 mol=> m H2SO4 dư = 0,182 . 98 =17,836 g
m dd sau p/ư = m dd H2SO4 + m CuO = 100 + 1,6 = 101,6 g
=> m CuSO4 = 0,02 . 160 = 3,2 g
=> C% CuSO4 = 3,2 / 101,6 . 100% = 3,15%
=> C% H2SO4dư = 17,836 / 101,6 . 100% = 17,83%
Chúc em học tốt!!!!
\(n_{CuO}=\dfrac{1,6}{80}=0,02\left(mol\right)\)
\(n_{H_2SO_4}=\dfrac{100.20\%}{98}=\dfrac{10}{49}\left(mol\right)\)
PTHH :
\(CuO+H_2SO_4\rightarrow CuSO_4+H_2O\)
0,02 0,02 0,02 0,02
\(\dfrac{0,02}{1}< \dfrac{\dfrac{10}{49}}{1}\) ---> H2SO4 dư và tính theo CuO
\(C\%_{CuSO_4}=\dfrac{0,02.160}{1,6+100}.100\%\approx3,15\%\)
\(C\%_{H_2SO_4dư}=\dfrac{\left(\dfrac{10}{49}-0,02\right).98}{100+1,6}\approx17,76\left(\%\right)\)
a) \(n_{Zn}=\dfrac{6,5}{65}=0,1\left(mol\right)\)
\(m_{H_2SO_4}=147.10\%=14,7\left(g\right)\Rightarrow n_{H_2SO_4}=\dfrac{14,7}{98}=0,15\left(mol\right)\)
PTHH: Zn + H2SO4 → ZnSO4 + H2
Mol: 0,1 0,1 0,1 0,1
Ta có: \(\dfrac{0,1}{1}< \dfrac{0,15}{1}\) ⇒ Zn hết, H2SO4 dư
b) \(V_{H_2}=0,1.22,4=2,24\left(l\right)\)
c) mdd sau pứ = 6,5 + 147 - 0,1.2 = 153,3 (g)
\(C\%_{ddZnSO_4}=\dfrac{0,1.161.100\%}{153,3}=10,502\%\)
\(C\%_{ddH_2SO_4dư}=\dfrac{\left(0,15-0,1\right).98.100\%}{153,3}=3,196\%\)
a) PTHH: Fe2O3 + 3H2SO4 ➜ Fe2(SO4)3 + 3H2O
b) \(n_{Fe_2O_3}=\dfrac{16}{160}=0,1\left(mol\right)\)
\(m_{H_2SO_4}=500.98\%=49\left(g\right)\)
⇒ \(n_{H_2SO_4}=\dfrac{49}{98}=0,5\left(mol\right)\)
Theo PT: \(n_{Fe_2O_3}=\dfrac{1}{3}n_{H_2SO_4}\)
Theo bài: \(n_{Fe_2O_3}=\dfrac{1}{5}n_{H_2SO_4}\)
Vì \(\dfrac{1}{5}< \dfrac{1}{3}\) ⇒ Fe2O3 hết, H2SO4 dư
Theo PT: \(n_{Fe_2\left(SO_4\right)_3}=n_{Fe_2O_3}=0,1\left(mol\right)\)
⇒ \(m_{Fe_2\left(SO_4\right)_3}=0,1.400=40\left(g\right)\)
c) Dung dịch sau phản ứng gồm: H2SO4 dư và Fe2(SO4)3
\(n_{H_2SO_4}pư=3n_{Fe_2O_3}=3.0,1=0,3\left(mol\right)\)
⇒ \(n_{H_2SO_4}dư=0,5-0,3=0,2\left(mol\right)\)
⇒ \(m_{H_2SO_4}dư=0,2.98=19,6\left(g\right)\)
\(m_{dd}=16+500=516\left(g\right)\)
\(C\%_{dd_{H_2SO_4}}=\dfrac{19,6}{516}.100\%=3,8\%\)
\(C\%_{Fe_2\left(SO_4\right)_3}=\dfrac{40}{516}.100\%=7,75\%\)
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