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19 tháng 7 2021

Đặt x,y, z lần lượt là số mol của Na,Al,Mg trong m gam hỗn hợp A

m gam A + H2O dư

\(Na+H_2O\rightarrow NaOH+\dfrac{1}{2}H_2\)

x--------------------x--------->0,5x

2Al + 2NaOH + 2H2O → 2NaAlO2 + 3H2

x<------x-------------------------------------->1,5x

=> \(0,5x+1,5x=\dfrac{2,24}{22,4}=0,1\left(mol\right)\) (1)

2m gam A + NaOH

\(Na+H_2O\rightarrow NaOH+\dfrac{1}{2}H_2\)

2x------------------------------->x

2Al + 2NaOH + 2H2O → 2NaAlO2 + 3H2

2y---------------------------------------------->3y

=> \(x+3y=\dfrac{8,96}{22,4}=0,4\left(mol\right)\) (2) 

3m gam A + HCl

\(Na+HCl\rightarrow NaCl+\dfrac{1}{2}H_2\)

3x--------------------------->1,5x

\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)

3y----------------------------->4,5y

\(Mg+2HCl\rightarrow MgCl_2+H_2\)

3z----------------------------->3z

=> \(1,5x+4,5y+3z=\dfrac{22,4}{22,4}=1\left(mol\right)\) (3)

Từ (1), (2), (3) =>\(\left\{{}\begin{matrix}x=0,05\\y=\dfrac{7}{60}\\z=\dfrac{2}{15}\end{matrix}\right.\)

=> \(m_{Na}=0,05.23=1,15\left(g\right)\)

\(m_{Al}=\dfrac{7}{60}.27=3,15\left(g\right)\)

\(m_{Mg}=\dfrac{2}{15}.24=3,2\left(g\right)\)

=> \(m=1,15+3,15+3,2=7,5\left(g\right)\)

=> \(\%m_{Na}=\dfrac{1,15}{7,5}.100=15,33\%\)

\(\%m_{Al}=\dfrac{3,15}{7,5}.100=42\%\)

\(\%m_{Mg}=\dfrac{3,2}{7,5}.100=42,67\%\)

 

 

13 tháng 7 2021

\(2Na+2H2O\rightarrow2NaOH+H2\left(1\right)\)

\(2Al+2NaOH+2H2O\rightarrow2NaAlO2+3H2\left(2\right)\)

\(2Al+6HCl\rightarrow2AlCl3+3H2\left(3\right)\)

\(2Na+2HCl\rightarrow2NaCl+H2\left(4\right)\)

\(Mg+2HCl\rightarrow MgCl2+H2\left(5\right)\)

\(n_{H2\left(1\right)}=0,1\left(mol\right)\rightarrow n_{Na}=0,2\left(mol\right)\rightarrow m_{Na}=4,6\left(g\right)\)

\(n_{H2\left(2\right)}=0,4\left(mol\right)\Rightarrow n_{Al}=\dfrac{4}{15}\left(mol\right)\Rightarrow m_{Al}=7,2\left(g\right)\)

\(\Rightarrow n_{H2\left(3\right)}=\dfrac{3}{2}n_{Al}=0,4\left(mol\right)\)

\(n_{H2\left(4\right)}=\dfrac{1}{2}n_{Na}=0,1\left(mol\right)\)

\(\Rightarrow n_{H2\left(5\right)}=1-0,4-0,1=0,5\left(mol\right)\)

\(\Rightarrow n_{Mg}=0,5\left(mol\right)\Rightarrow m_{Mg}=12\left(g\right)\)

\(\Rightarrow m=12+4,6+7,2=23,8\left(g\right)\)

\(\%m_{Na}=\dfrac{4,6}{23,8}.100\%=19,33\%\)

\(\%m_{Al}=\dfrac{7,2}{23,8}.100\%=30,25\%\)

\(\%m_{Mg}=100-19,33-30,25=50,42\%\)

Chúc bạn học tốt

14 tháng 7 2021

thanks

29 tháng 1 2022

TN1: Gọi \(\left(n_{Mg};n_{Al};n_{Zn}\right)=\left(a;b;c\right)\)

=> 24a + 27b + 65c = 28,6 (1)

\(n_{O_2}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\)

PTHH: 2Mg + O2 --to--> 2MgO

             a--->0,5a

            4Al + 3O2 --to--> 2Al2O3

             b-->0,75b

            2Zn + O2 --to--> 2ZnO

             c--->0,5c

=> 0,5a + 0,75b + 0,5c = 0,5 (2)

TN2: Gọi \(\left(n_{Mg};n_{Al};n_{Zn}\right)=\left(ak;bk;ck\right)\)

=> ak + bk + ck = 0,8 (3)

PTHH: Mg + 2HCl --> MgCl2 + H2

           ak----------------------->ak

            2Al + 6HCl -->2AlCl3 + 3H2

           bk------------------------>1,5bk

           Zn + 2HCl --> ZnCl2 + H2

          ck---------------------->ck

=> \(ak+1,5bk+ck=\dfrac{22,4}{22,4}=1\) (4)

(1)(2)(3)(4) => \(\left\{{}\begin{matrix}a=0,2\\b=0,4\\c=0,2\\k=1\end{matrix}\right.\)

=> \(\left\{{}\begin{matrix}\%m_{Mg}=\dfrac{0,2.24}{28,6}.100\%=16,783\%\\\%m_{Al}=\dfrac{0,4.27}{28,6}.100\%=37,762\%\\\%m_{Zn}=\dfrac{0,2.65}{28,6}.100\%=45,455\end{matrix}\right.\)

 

\(n_{H_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\)

Gọi số mol O2 pư là x (mol)

2H+1 + 2e --> H20

            0,8<--0,4

O20 + 4e --> 2O-2

x---->4x

=> 4x = 0,8

=> x = 0,2 (mol)

=> m = 15 + 0,2.32 = 21,4 (g)

17 tháng 5 2022

\(n_{H_2}=\dfrac{1,68}{22,4}=0,075\left(mol\right)\)

PTHH:

\(CH_3COOC_2H_5+NaOH\rightarrow CH_3COONa+C_2H_5OH\)

0,1<-----------------0,1-------------------------------->0,1

\(C_2H_5OH+Na\rightarrow C_2H_5ONa+\dfrac{1}{2}H_2\)

0,15<--------------------------------0,075

\(\rightarrow n_{C_2H_5OH\left(bđ\right)}=0,15-0,1=0,05\left(mol\right)\\ \rightarrow m=0,05.46+88.0,1=11,1\left(g\right)\)

20 tháng 11 2021

Bài 1:

\(PTHH:2NaOH+H_2SO_4\rightarrow Na_2SO_4+2H_2O\\ Zn+H_2SO_4\rightarrow ZnSO_4+H_2\\ n_{NaOH}=\dfrac{6}{40}=0,15\left(mol\right)\\ \Rightarrow n_{H_2SO_4}=\dfrac{1}{2}n_{NaOH}=\dfrac{1}{2}\cdot0,15=0,075\left(mol\right)\\ \Rightarrow m=m_{H_2SO_4}=0,075\cdot98=7,35\left(g\right)\\ n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\\ \Rightarrow n_{H_2}=0,2\left(mol\right)\\ \Rightarrow V=V_{H_2}=0,2\cdot22,4=4,48\left(l\right)\)