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Gọi số mol H2SO4 là a (mol)
Bảo toàn H: \(n_{H_2}=a\left(mol\right)\)
Có: \(m_{tăng}=m_{KL}-m_{H_2}\)
=> \(m_{KL}=48,6+2a\left(g\right)\)
Theo ĐLBTKL: \(m_{KL}+m_{H_2SO_4}=m_{Muối}+m_{H_2}\)
=> \(48,6+2a+98a=161,3+2a\)
=> a = 1,15 (mol)
=> \(a=\dfrac{1,15}{0,55}=\dfrac{23}{11}M\)
PTHH: \(Mg+H_2SO_4\rightarrow MgSO_4+H_2\)
a______________________a (mol)
\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
b_____________________b (mol)
Ta lập HPT: \(\left\{{}\begin{matrix}24a+56b=10,4\\a+b=\dfrac{6,72}{22,4}=0,3\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}a=0,2\\b=0,1\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Mg}=\dfrac{0,2\cdot24}{10,4}\cdot100\%\approx46,15\%\\m_{ddH_2SO_4}=\dfrac{\left(0,2+0,1\right)\cdot98}{10\%}=294\left(g\right)\end{matrix}\right.\)
a, Gọi \(\left\{{}\begin{matrix}n_{Al}=a\left(mol\right)\\n_{Mg}=b\left(mol\right)\end{matrix}\right.\)
\(n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
PTHH:
2Al + 3H2SO4 ---> Al2(SO4)3 + 3H2
a---->1,5a--------------------------->1,5a
Mg + H2SO4 ---> MgSO4 + H2
b------>b----------------------->b
Hệ pt \(\left\{{}\begin{matrix}27a+24b=6,3\\1,5a+b=0,3\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,1\left(mol\right)\\b=0,15\left(mol\right)\end{matrix}\right.\)
\(\rightarrow\left\{{}\begin{matrix}m_{Al}=0,1.27=2,7\left(g\right)\\m_{Mg}=0,15.24=3,6\left(g\right)\end{matrix}\right.\\ \rightarrow\left\{{}\begin{matrix}\%m_{Al}=\dfrac{2,7}{6,3}=42,86\%\\\%m_{Mg}=100\%-42,86\%=57,14\%\end{matrix}\right.\)
b, \(n_{H_2SO_4}=0,1.1,5+0,15=0,3\left(mol\right)\)
\(\rightarrow V_{ddH_2SO_4}=\dfrac{0,3}{0,5}=0,6\left(l\right)=600\left(ml\right)\)
c, đề yêu cầu jv?
