tính nồng độ ion của 50g dd HCl 7.3% ( D = 1.25g/ml)
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D
2
B
17 tháng 3 2022
nCaCO3=\(\dfrac{50}{100}\)=0,5(mol)
PTHH: CaCO3+2HCl→CaCl2+H2O+CO2↑
Theo PT ta có: nCaCO3=nCaCl2=nCO2=0,5(mol)
Theo PT ta có: nHCl=0,5.21=1(mol)
⇒mddHCl=\(\dfrac{1.36,5}{20\%}\)=182,5(g)
⇒mddsau−pư=mCaCO3+mHCl−mCO2
⇔mddHCl=50+182,5−22=210,5(g)
⇒C%CaCl2=\(\dfrac{0,5.111}{210,5}\).100%≈26,37%
17 tháng 3 2022
nCaCO3 = 50/100 = 0,5 (mol(
PTHH: CaCO3 + 2HCl -> CaCl2 + CO2 + H2O
Mol: 0,5 ---> 0,1 ---> 0,5 ---> 0,5 ---> 0,5
mHCl = 1 . 36,5 = 36,5 (g)
mddHCl = 36,5/20% = 182,5 (g)
mCO2 = 0,5 . 44 = 22 (g)
mdd (sau p/ư) = 50 + 182,5 - 22 = 210,5 (g)
mCaCl2 = 0,5 . 111 = 55,5
C%CaCl2 = 55,5/210,5 = 26,36%
MN
28 tháng 7 2021
\(n_{NaOH}=\dfrac{200\cdot2\%}{40}=0.1\left(mol\right)\)
\(n_{H_2SO_4}=\dfrac{50\cdot49\%}{98}=0.25\left(mol\right)\)
\(2NaOH+H_2SO_4\rightarrow Na_2SO_4+2H_2O\)
\(0.1...............0.05...........0.05\)
\(n_{Na_2SO_4}=0.05\left(mol\right)\)
\(n_{H_2SO_4\left(dư\right)}=0.25-0.05=0.2\left(mol\right)\)
\(V_{dd}=\dfrac{200}{1}+\dfrac{50}{1.05}=247.6\left(ml\right)=0.2476\left(l\right)\)
\(\left[Na^+\right]=\dfrac{0.05\cdot2}{0.2476}=0.4\left(M\right)\)
\(\left[H^+\right]=\dfrac{0.2\cdot2}{0.2476}=1.6\left(M\right)\)
\(\left[SO_4^{2-}\right]=\dfrac{0.05+0.2}{0.2476}=1\left(M\right)\)
H
28 tháng 7 2021
$n_{NaOH} = \dfrac{200.2\%}{40} = 0,1(mol)$
$n_{H_2SO_4} = \dfrac{50.49\%}{98} = 0,25(mol)$
$2NaOH + H_2SO_4 \to Na_2SO_4 + 2H_2O$
$n_{NaOH} : 2 < n_{H_2SO_4} : 1$ nên $H_2SO_4$ dư
$n_{H_2SO_4\ dư} = 0,25 - 0,1.0,5 = 0,2(mol)$
$n_{H^+\ dư} = 0,2.2 = 0,4(mol)$
Sau phản ứng :
$V_{dd} = \dfrac{200}{1} + 50.1,05 = 252,5(ml) = 0,2525(lít)$
Bảo toàn Na, S ta có :
$[Na^+] = \dfrac{0,1}{0,2525} = 0,4M$
$[SO_4^{2-}] = \dfrac{0,25}{0,2525} = 0,99M$
$[H^+] = \dfrac{0,4}{0,2525} = 1,58M$
13 tháng 9 2021
\(b.n_{NaOH\left(tổng\right)}=0,4.0,5+\dfrac{100.1,33.20\%}{40}=0,865\left(mol\right)\\ \left[Na^+\right]=\left[OH^-\right]=\left[NaOH\left(sau\right)\right]=\dfrac{0,865}{0,4+0,1}=1,73\left(M\right)\\ c.n_{HCl}=0,05.0,12=0,006\left(mol\right)\\ n_{HNO_3}=0,15.0,1=0,015\left(mol\right)\\ \left[H^+\right]=\dfrac{0,006+0,015}{0,05+0,15}=0,105\left(M\right)\\ \left[NO^-_3\right]=\dfrac{0,015}{0,05+0,15}=0,075\left(M\right)\\ \left[Cl^-\right]=\dfrac{0,006}{0,05+0,15}=0,03\left(M\right)\)
\(d.n_{H_2SO_4}=0,4.0,05=0,02\left(mol\right)\\ n_{HCl}=0,35.0,2=0,07\left(mol\right)\\ \left[H^+\right]=\dfrac{0,02.2+0,07}{0,05+0,35}=0,275\left(M\right)\\ \left[SO^{2-}_4\right]=\dfrac{0,02}{0,05+0,35}=0,05\left(M\right)\\ \left[Cl^-\right]=\dfrac{0,07}{0,05+0,35}=0,175\left(M\right)\\ f.n_{KOH}=\dfrac{20.1,31.32\%}{56}=\dfrac{131}{875}\left(mol\right)\\ n_{Ba\left(OH\right)_2}=0,08.1=0,08\left(mol\right)\\ \left[OH^-\right]=\dfrac{\dfrac{131}{875}+0,08.2}{0,02+0,08}=\dfrac{542}{175}\left(M\right)\\ \left[Ba^{2+}\right]=\dfrac{0,08}{0,02+0,08}=0,8\left(M\right)\)
\(\left[K^+\right]=\dfrac{\dfrac{131}{875}}{0,02+0,08}=\dfrac{262}{175}\left(M\right)\)
4 tháng 10 2021
\(n_{H^+}=n_{HCl}=0,03mol\)
\(n_{OH^-}=2n_{Ba\left(OH\right)_2}=0,07mol\)
\(H^+\) + \(OH^-\) \(\rightarrow\) \(H_2O\)
bđ 0,03 0,07
pư 0,03 0,03 0,03
kt 0 0,04 0,03
\(\Rightarrow\)\(\left[OH^-\right]=\dfrac{n_{sau}}{V}=\dfrac{0,04}{1}=0,04M\)
17 tháng 5 2016
a) GS có x mol HCl
\(\Rightarrow m_{HCl}\)mHClHCl=36,5x
\(\Rightarrow m_{dd_{HCl}}\)=36,5x/37%=98,65x
\(\Rightarrow V_{dd}=\frac{m_{dd}}{D}\)=\(\frac{98,65x}{1,19}\)=82,9x (ml)
\(\Rightarrow CM_{dd_{HCl}}\)=x/0,0829x=12M
b) GS có x mol HCl
\(\Rightarrow m_{HCl}\)=36,5x
\(V_{dd_{HCl}}\)=x/10,81 lít
\(\Rightarrow m_{dd_{HCl}}\)=1/10,81.1000.1,17.x=108,233x
\(\Rightarrow\)C%=36,5/108,233.100%=33,72%
DM
17 tháng 5 2016
GS có x mol HClHCl
=>mHClHCl=36,5x
=>mdd HClHCl=36,5x/37%=98,65x
=>Vdd=mdd/D=98,65x/1,19=82,9x (ml)
=>CM dd HClHCl=x/0,0829x=12M
b) GS có x mol HClHCl
=>mHClHCl=36,5x
Vdd HClHCl=x/10,81 lít
=>mdd HClHCl=1/10,81.1000.1,17.x=108,233x
=>C%=36,5/108,233.100%=33,72%
HP
17 tháng 9 2021
a, \(\left\{{}\begin{matrix}n_{Ba^{2+}}=4.10^{-3}\left(mol\right)\\n_{Na^+}=3.10^{-3}\left(mol\right)\\n_{OH^-}=0,011\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\left[Ba^{2+}\right]=\dfrac{4.10^{-3}}{0,2+0,3}=0,008M\\\left[Na^+\right]=\dfrac{3.10^{-3}}{0,2+0,3}=0,006M\\\left[OH^-\right]=\dfrac{0,011}{0,2+0,3}=0,022M\end{matrix}\right.\)
b, Để trung hòa dung dịch A thì:
\(n_{H^+}=n_{OH^-}\)
\(\Leftrightarrow0,01.V_{ddHCl}=\left(0,02.2+0,01\right).0,2\)
\(\Leftrightarrow V_{ddHCl}=1\left(l\right)\)
19 tháng 2 2019
\(n_{CaCO_3}=\dfrac{50}{100}=0,5\left(mol\right)\)
PTHH: \(CaCO_3+2HCl\rightarrow CaCl_2+H_2O+CO_2\uparrow\)
Theo PT ta có: \(n_{CaCO_3}=n_{CaCl_2}=n_{CO_2}=0,5\left(mol\right)\)
Theo PT ta có: \(n_{HCl}=\dfrac{0,5.2}{1}=1\left(mol\right)\)
\(\Rightarrow mdd_{HCl}=\dfrac{1.36,5}{20\%}=182,5\left(g\right)\)
\(\Rightarrow mdd_{sau-pư}=m_{CaCO_3}+m_{HCl}-m_{CO_2}\)
\(\Leftrightarrow mdd_{HCl}=50+182,5-22=210,5\left(g\right)\)
\(\Rightarrow C\%_{CaCl_2}=\dfrac{mct}{mdd}.100\%=\dfrac{0,5.111}{210,5}.100\%\approx26,37\%\)
17 tháng 2 2020
\(CuCl_2+H_2S\rightarrow CuS+2HCl\)
\(m_{dd_{CuCl2}}=3,38.50=169\left(g\right)\)
\(n_{CuCl2}=\frac{169.20\%}{135}=0,25\left(mol\right)\)
\(n_{H2S}=\frac{50.20,4\%}{34}=0,3\left(mol\right)\)
Suy ra H2S dư
\(n_{CuS}=n_{CuCl2}=0,25\left(mol\right)\)
\(n_{HCl}=0,25.2=0,5\left(mol\right)\)
\(m_{dd_{Spu}}=169+50-0,25.96=195\left(g\right)\)
\(C\%_{HCl}=\frac{0,5.36,5}{195}.100\%=9,36\%\)
ta có : \(D=\dfrac{m}{V}\Leftrightarrow1,25=\dfrac{50}{V}\Rightarrow V=40\left(ml\right)\)
đổi \(40ml=0,04l\)
ta có : \(C\%=\dfrac{m_{ct}}{m_{dd}}\times100\)
\(\Rightarrow7,3=\dfrac{36,5\times n_{HCl}}{50}\Leftrightarrow n_{HCl}=0,1\left(mol\right)\)
PT ion : \(HCl\rightarrow H^++Cl^-\)
\(\Rightarrow CM_{H^+}=\dfrac{n_{H^+}}{V}=\dfrac{0,1}{0,04}=2,5M\)
\(CM_{OH^-}=\dfrac{n_{OH^-}}{V}=\dfrac{0,1}{0,04}=2,5M\)
mình dùng công thức CM = \(\dfrac{C\%.10D}{M}\)
đc k?