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![](https://rs.olm.vn/images/avt/0.png?1311)
a, Gọi \(\left\{{}\begin{matrix}n_{Fe_2O_3}=a\left(mol\right)\\n_{ZnO}=b\left(mol\right)\end{matrix}\right.\left(đk:a,b>0\right)\)
\(n_{HCl}=1,5.0,2=0,3\left(mol\right)\)
PTHH:
Fe2O3 + 6HCl ---> FeCl3 + 3H2O
a-------->6a
ZnO + 2HCl ---> ZnCl2 + H2
b----->2b
=> \(\left\{{}\begin{matrix}160a+81b=8,83\\6a+2b=0,3\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,04\left(mol\right)\\b=0,03\left(mol\right)\end{matrix}\right.\left(TM\right)\)
=> \(\left\{{}\begin{matrix}m_{Fe_2O_3}=0,04.160=6,4\left(g\right)\\m_{ZnO}=0,03.81=2,43\left(g\right)\end{matrix}\right.\)
b, PTHH:
Fe2O3 + 3H2SO4 ---> Fe2(SO4)3 + 3H2O
0,04------>0,12
ZnO + H2SO4 ---> ZnSO4 + H2O
0,03->0,03
=> \(m_{H_2SO_4}=\left(0,12+0,03\right).98=14,7\left(g\right)\)
=> \(m_{ddH_2SO_4}=\dfrac{14,7.100}{30\%}=49\left(g\right)\)
gọi \(x,y\) lần lượt là số \(mol\) của\(CuO\) và \(ZnO\)
số \(mol\) \(HCl\)
\(N=Cm.V=3.0,1=0,3\left(mol\right)\)
lập \(PTHH\) :
\(CuO+2HCl\rightarrow CuCl2+H2O\)
\(x\Rightarrow2x\)
\(ZnO+2HCl\rightarrow ZnCl2+H2O\)
\(y\Rightarrow2y\)
theo \(PTP\) , ta có :
\(2x+2y=0,3\) \(\left(1\right)\)
theo đề ra :
\(mCuO+mZnO=80x+81y=12,1\left(g\right)\) \(\left(2\right)\)
từ \(\left(1\right);\left(2\right)\Rightarrow80x+81y=12,1\left(g\right)\Rightarrow x=0,05\left(mol\right)\)
\(2x+2y=0,3\Rightarrow y=0,1\left(mol\right)\)
\(a,\) \(\%CuO=\dfrac{0,05.80.100}{12,1}=33,06\%\)
\(\%ZnO=\dfrac{0,1.80.100}{12,1}=66,94\%\)
\(b,\) \(CuO+H2SO4\rightarrow CuOSO4+H2O\)
\(0,05\rightarrow0,05\)
\(ZnO+H2SO4\rightarrow ZnSO4+H2O\)
\(0,1\rightarrow0,1\)
\(nH2SO4=0,05+0,1=0,15\left(mol\right)\)
\(mH2SO4=0,15.98=14,7\left(g\right)\)
\(mddH2SO4=14,7:20=73,5\left(g\right)\)
![](https://rs.olm.vn/images/avt/0.png?1311)
\(n_{NaOH}=\dfrac{200\cdot4\%}{40}=0.2\left(mol\right)\)
\(2NaOH+H_2SO_4\rightarrow Na_2SO_4+H_2O\)
\(0.2..............0.1..............0.1\)
\(V_{dd_{H_2SO_4}}=\dfrac{0.1}{0.2}=0.5\left(l\right)\)
\(m_{Na_2SO_4}=0.1\cdot142=14.2\left(g\right)\)
\(m_{dd}=200+510=710\left(g\right)\)
\(C\%_{Na_2SO_4}=\dfrac{14.2}{710}\cdot100\%=2\%\)
Ta có: mNaOH = 200.4% = 8 (g)
\(\Rightarrow n_{NaOH}=\dfrac{8}{40}=0,2\left(mol\right)\)
PT: \(2NaOH+H_2SO_4\rightarrow Na_2SO_4+2H_2O\)
_____0,2______0,1_______0,1 (mol)
a, \(V_{ddH_2SO_4}=\dfrac{0,1}{0,2}=0,5\left(l\right)\)
b, Chất có trong dd sau pư là Na2SO4.
Ta có: m dd sau pư = m dd NaOH + m dd H2SO4 = 200 + 510 = 710 (g)
\(\Rightarrow C\%_{Na_2SO_4}=\dfrac{0,1.142}{710}.100\%=2\%\)
Bạn tham khảo nhé!
![](https://rs.olm.vn/images/avt/0.png?1311)
Bài 13 :
\(a)n_{Fe_2O_3} = \dfrac{9,6}{160} = 0,06(mol)\\ Fe_2O_3 + 6HCl \to 2FeCl_3 + 3H_2O\\ n_{HCl} = 6n_{Fe_2O_3} = 0,36(mol)\\ C\%_{HCl} = \dfrac{0,36.36,5}{150}.100\% = 8,76\%\\ \Rightarrow X = 8,76 b) n_{FeCl_3} = 2n_{Fe_2O_3} = 0,12(mol)\\ m_{FeCl_3} = 0,12.162,5 =19,5(gam)\)
\(m_{H_2SO_4}=\dfrac{C_{\%}.m_{dd}}{100\%}=\dfrac{15\%.200}{100\%}=30\left(g\right)\)
mH2SO4 = \(\dfrac{15\%.200}{100\%}\) = 30 (g)