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\(n_{NaOH}=0,02.2=0,04\left(mol\right)\\ 2NaOH+H_2SO_4\rightarrow Na_2SO_4+2H_2O\\ a.n_{H_2SO_4}=n_{Na_2SO_4}=\dfrac{0,04}{2}=0,02\left(mol\right)\\ C_{MddH_2SO_4}=\dfrac{0,02}{0,08}=0,25\left(M\right)\\ b.\left[Na^+\right]=\dfrac{0,02.2}{0,02+0,08}=0,4\left(M\right)\\ \left[SO^{2-}_4\right]=\dfrac{0,02}{0,02+0,08}=0,2\left(M\right)\)
a, \(\left[Ca^{2+}\right]=\dfrac{0,15.0,5}{0,15+0,05}=0,375M\)
\(\left[Na^+\right]=\dfrac{0,05.2}{0,15+0,05}=0,5M\)
\(\left[Cl^-\right]=\dfrac{0,15.2.0,5+0,05.2}{0,15+0,05}=1,25M\)
\(b.n_{NaOH\left(tổng\right)}=0,4.0,5+\dfrac{100.1,33.20\%}{40}=0,865\left(mol\right)\\ \left[Na^+\right]=\left[OH^-\right]=\left[NaOH\left(sau\right)\right]=\dfrac{0,865}{0,4+0,1}=1,73\left(M\right)\\ c.n_{HCl}=0,05.0,12=0,006\left(mol\right)\\ n_{HNO_3}=0,15.0,1=0,015\left(mol\right)\\ \left[H^+\right]=\dfrac{0,006+0,015}{0,05+0,15}=0,105\left(M\right)\\ \left[NO^-_3\right]=\dfrac{0,015}{0,05+0,15}=0,075\left(M\right)\\ \left[Cl^-\right]=\dfrac{0,006}{0,05+0,15}=0,03\left(M\right)\)
\(d.n_{H_2SO_4}=0,4.0,05=0,02\left(mol\right)\\ n_{HCl}=0,35.0,2=0,07\left(mol\right)\\ \left[H^+\right]=\dfrac{0,02.2+0,07}{0,05+0,35}=0,275\left(M\right)\\ \left[SO^{2-}_4\right]=\dfrac{0,02}{0,05+0,35}=0,05\left(M\right)\\ \left[Cl^-\right]=\dfrac{0,07}{0,05+0,35}=0,175\left(M\right)\\ f.n_{KOH}=\dfrac{20.1,31.32\%}{56}=\dfrac{131}{875}\left(mol\right)\\ n_{Ba\left(OH\right)_2}=0,08.1=0,08\left(mol\right)\\ \left[OH^-\right]=\dfrac{\dfrac{131}{875}+0,08.2}{0,02+0,08}=\dfrac{542}{175}\left(M\right)\\ \left[Ba^{2+}\right]=\dfrac{0,08}{0,02+0,08}=0,8\left(M\right)\)
\(\left[K^+\right]=\dfrac{\dfrac{131}{875}}{0,02+0,08}=\dfrac{262}{175}\left(M\right)\)
\(n_{HCl}=\dfrac{7,3}{36,5}=0,2\left(mol\right)\\ n_{H_2SO_4}=\dfrac{9,8}{98}=0,1\left(mol\right)\\ \left[HCl\right]=\dfrac{0,2}{0,2}=1\left(M\right)\\ \left[H_2SO_4\right]=\dfrac{0,1}{0,2}=0,5\left(M\right)\\ \left[SO_4^{2-}\right]=\left[H_2SO_4\right]=0,5\left(M\right)\\ \left[Cl^-\right]=\left[HCl\right]=1\left(M\right)\\ \left[H^+\right]=1+0,5.2=2\left(M\right)\)
a, \(\left\{{}\begin{matrix}n_{Ba^{2+}}=4.10^{-3}\left(mol\right)\\n_{Na^+}=3.10^{-3}\left(mol\right)\\n_{OH^-}=0,011\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\left[Ba^{2+}\right]=\dfrac{4.10^{-3}}{0,2+0,3}=0,008M\\\left[Na^+\right]=\dfrac{3.10^{-3}}{0,2+0,3}=0,006M\\\left[OH^-\right]=\dfrac{0,011}{0,2+0,3}=0,022M\end{matrix}\right.\)
b, Để trung hòa dung dịch A thì:
\(n_{H^+}=n_{OH^-}\)
\(\Leftrightarrow0,01.V_{ddHCl}=\left(0,02.2+0,01\right).0,2\)
\(\Leftrightarrow V_{ddHCl}=1\left(l\right)\)
a) Ta có: \(n_{Al\left(NO_3\right)_3}=\dfrac{4,26}{213}=0,02\left(mol\right)\) \(\Rightarrow\left\{{}\begin{matrix}n_{Al^+}=0,02\left(mol\right)\\n_{NO_3^-}=0,06\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\left[Al^+\right]=\dfrac{0,02}{0,1}=0,2\left(M\right)\\\left[NO_3^-\right]=\dfrac{0,06}{0,1}=0,6\left(M\right)\end{matrix}\right.\)
b) Ta có: \(\left[Na^+\right]=0,1+0,02\cdot2+0,3=0,304\left(M\right)\)
c) Bạn xem lại đề !!
a, \(n_{H^+}=n_{Cl^-}=n_{HCl}=0,003\left(mol\right)\)
\(\Rightarrow\left[H^+\right]=\left[Cl^-\right]=\dfrac{0,003}{0,1}=0,03M\)
b, \(n_{H^+}=2n_{H_2SO_4}=0,05\left(mol\right)\Rightarrow\left[H^+\right]=\dfrac{0,05}{0,05}=1M\)
\(n_{SO_4^{2-}}=n_{H_2SO_4}=0,025\left(mol\right)\Rightarrow\left[SO_4^{2-}\right]=\dfrac{0,025}{0,05}=0,5M\)
a) Dung dịch HCl 7.3% (D = 1.25g/ml)
Áp dụng công thức CM = C%*10D/M.
suy ra CM HCl = 7.3 *10*1,25/36.5= 2.5M.
Hay [HCl]= 2.5M
HCl là chất điện li mạnh trong dung dịch nên HCl --> H+ + Cl-
[H+]= [Cl-] = [HCl]= 2.5M
b) nK2SO4 = 0.022 mol.
Suy ra [K2SO4]= 0.022*0.4 = 0.0088M
K2SO4 là chất điện li mạnh nên có phương trình điện li:
K2SO4 --> 2K+ + SO4 2-
vậy [K+] = 2[K2SO4] = 0.0176M
[ SO4 2-] = [K2SO4] = 0.0088M
c) nH2SO4 = 0.24 mol.
[H2SO4] = 0.24*1.25 = 0.3M.
PT điện li : H2SO4 --> 2H+ + SO4 2-
vậy [H+] = 2[H2SO4] = 0.6M
[ SO4 2-] = [H2SO4] = 0.3M