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a)
4Al + 3O2 --to--> 2Al2O3
2Mg + O2 --to--> 2MgO
b) Gọi số mol Al, Mg là a, b (mol)
=> 27a + 24b = 7,8 (1)
PTHH: 4Al + 3O2 --to--> 2Al2O3
a--->0,75a----->0,5a
2Mg + O2 --to--> 2MgO
b--->0,5b------->b
=> 102.0,5a + 40b = 14,2
=> 51a + 40b = 14,2 (2)
(1)(2) => a = 0,2 (mol); b = 0,1 (mol)
nO2 = 0,75a + 0,5b = 0,2 (mol)
=> VO2 = 0,2.22,4 = 4,48 (l)
=> Vkk = 4,48 : 20% = 22,4 (l)
c)
mAl = 0,2.27 = 5,4 (g)
mMg = 0,1.24 = 2,4 (g)
a)
4Al + 3O2 --to--> 2Al2O3
2Mg + O2 --to--> 2MgO
b) Gọi số mol Al, Mg là a, b (mol)
=> 27a + 24b = 7,8 (1)
PTHH: 4Al + 3O2 --to--> 2Al2O3
a--->0,75a----->0,5a
2Mg + O2 --to--> 2MgO
b--->0,5b------->b
=> 102.0,5a + 40b = 14,2
=> 51a + 40b = 14,2 (2)
(1)(2) => a = 0,2 (mol); b = 0,1 (mol)
nO2 = 0,75a + 0,5b = 0,2 (mol)
=> VO2 = 0,2.22,4 = 4,48 (l)
=> Vkk = 4,48 : 20% = 22,4 (l)
c)
mAl = 0,2.27 = 5,4 (g)
mMg = 0,1.24 = 2,4 (g)
a) Gọi số mol Al, Zn là 2a, a (mol)
PTHH: 4Al + 3O2 --to--> 2Al2O3
2a-->1,5a---------->a
2Zn + O2 --to--> 2ZnO
a---->0,5a------->a
=> \(102a+81a=18,3\)
=> a = 0,1 (mol)
=> \(\left\{{}\begin{matrix}\%m_{Al}=\dfrac{0,2.27}{0,2.27+0,1.65}.100\%=45,378\%\\\%m_{Zn}=\dfrac{0,1.65}{0,2.27+0,1.65}.100\%=54,622\%\end{matrix}\right.\)
b) \(n_{O_2}=1,5a+0,5a=0,2\left(mol\right)\)
=> \(V_{O_2}=0,2.22,4=4,48\left(l\right)\)
\(m_{Al}=27,8.19,2\%=5,4\left(g\right)\\ m_{Fe}=27,8-5,4=22,4\left(g\right)\\ \rightarrow\left\{{}\begin{matrix}n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\\n_{Fe}=\dfrac{22,4}{56}=0,4\left(mol\right)\end{matrix}\right.\)
PTHH:
4Al + 3O2 --to--> 2Al2O3
0,2-->0,15------->0,1
3Fe + 2O2 --to--> Fe3O4
0,4-->4/15--------->2/15
\(\rightarrow\left\{{}\begin{matrix}V_{kk}=\left(0,15+\dfrac{4}{15}\right).22,4.5=\dfrac{140}{3}\left(l\right)\\m_{Cran}=0,1.102+\dfrac{2}{15}.232=\dfrac{617}{15}\left(g\right)\end{matrix}\right.\)
mAl=27,8.19,42%=5,4g
⇒nAl=\(\dfrac{5,4}{27}\)=0,2mol
⇒nFe=\(\dfrac{27,8-5,4}{56}\)=0,4mol
4Al+3O2to→2Al2O34
3Fe+2O2to→Fe3O4
⇒nO2=\(\dfrac{3}{4}\)nAl+\(\dfrac{2}{3}\)nFe=\(\dfrac{5}{12}\)mol
⇒Vkk=\(\dfrac{5}{12}\).22,4.5=46,67l
b,
mrắn=27,8+mO2=27,8+\(\dfrac{5}{12}\)32=41,1g
\(m_{tăng}=m_{O_2}=7.2\left(g\right)\)
\(n_{O_2}=\dfrac{7.2}{32}=0.225\left(mol\right)\)
\(V_{kk}=5V_{O_2}=5\cdot0.225\cdot22.4=25.2\left(l\right)\)
\(Đặt:n_{Mg}a\left(mol\right),n_{Cu}=b\left(mol\right),n_{Al}=c\left(mol\right)\)
\(Mg+\dfrac{1}{2}O_2\underrightarrow{t^0}MgO\)
\(Cu+\dfrac{1}{2}O_2\underrightarrow{t^0}CuO\)
\(4Al+3O_2\underrightarrow{t^0}2Al_2O_3\)
\(TC:n_{O_2}=0.5a=0.5b=0.75c=\dfrac{0.225}{3}=0.075\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}a=0.15\\b=0.15\\c=0.1\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}m_{Mg}=0.15\cdot24=3.6\left(g\right)\\m_{Cu}=0.15\cdot64=9.6\left(g\right)\\m_{Al}=0.1\cdot27=2.7\left(g\right)\end{matrix}\right.\)
\(a,n_{Al}=\dfrac{19,2\%.27,8}{27}=\dfrac{1112}{5625}\left(mol\right)\\ n_{Fe}=\dfrac{\left(100\%-19,2\%\right).27,8}{56}=\dfrac{14039}{35000}\left(mol\right)\\ 4Al+3O_2\rightarrow\left(t^o\right)2Al_2O_3\\ 3Fe+2O_2\rightarrow\left(t^o\right)Fe_3O_4\\ n_{O_2\left(tổng\right)}=\dfrac{1112}{5625}.0,75+\dfrac{2}{3}.\dfrac{14039}{35000}\approx0,4156762\left(mol\right)\\ V_{kk\left(đktc\right)}\approx0,4156762.5.22,4\approx46,5557344\left(l\right)\\ b,n_{Al_2O_3}=\dfrac{\dfrac{1112}{5625}}{2}=\dfrac{556}{5625}\left(mol\right)\\ n_{Fe_3O_4}=\dfrac{\dfrac{14039}{35000}}{3}=\dfrac{14039}{105000}\left(mol\right)\\ m_{rắn}=\dfrac{14039}{105000}.232+\dfrac{556}{5625}.102=41,1016381\left(g\right)\)
a. Ag không phản ứng nên ta có PTHH: \(2Mg+O_2\rightarrow^{t^o}2MgO\)
\(\rightarrow m_{O_2}=m_{hh}-m_{\mu\text{ối}}=18,8-15,6=3,2g\)
\(\rightarrow n_{O_2}=\frac{3,2}{32}=0,1mol\)
b. \(\rightarrow V_{O_2}=n.22,4=22,4.0,1=2,24l\)
\(\rightarrow V_{kk}=4,48.5=11,2l\)
c. Có \(n_{Mg}=2n_{O_2}=0,2l\)
\(\rightarrow m_{Mg}=0,2.24=4,8g\)
\(\rightarrow\%m_{Mg}=\frac{4,8.100}{15,6}\approx30,77\%\)
\(\rightarrow\%m_{Ag}=100\%-30,77\%=69,23\%\)