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`n_[Na_2 CO_3]=[2,76]/106=0,03(mol)`
`Na_2 CO_3 +2CH_3 COOH->2CH_3 COONa+H_2 O+CO_2\uparrow`
`0,03` `0,06` `0,03` `(mol)`
`CO_2 +Ca(OH)_2 ->CaCO_3 \downarrow+H_2 O`
`0,03` `0,03`
`a)CH_3 COONa` là muối natri axetat.
`V_[dd CH_3 COOH]=[0,06]/[0,2]=0,3(l)`
`b)m_[CaCO_3]=0,03.100=3(g)`
a, CH3COONa: Natri axetat
PT: \(Na_2CO_3+2CH_3COOH\rightarrow2CH_3COONa+CO_2+H_2O\)
Ta có: \(n_{Na_2CO_3}=\dfrac{2,76}{106}=0,026\left(mol\right)\)
Theo PT: \(n_{CH_3COOH}=2n_{Na_2CO_3}=0,052\left(mol\right)\Rightarrow V_{CH_3COOH}=\dfrac{0,052}{0,2}=0,26\left(l\right)\)
b, \(CO_2+Ca\left(OH\right)_2\rightarrow CaCO_{3\downarrow}+H_2O\)
Theo PT: \(n_{CaCO_3}=n_{CO_2}=n_{Na_2CO_3}=0,026\left(mol\right)\)
\(\Rightarrow m_{CaCO_3}=0,026.100=2,6\left(g\right)\)
nNa2CO3 = 10,6 / 106 = 0,1 (mol)
Na2CO3 + 2CH3COOH -> 2CH3COONa + H2O + CO2
0,1 0,2 0,2 0,1
mdd CH3COOH = 0,2 * 60 / 5 * 100 = 240 (gam)
CO2 + Ca(OH)2 -> CaCO3 + H2O
0,1 0,1
mCaCO3 = 0,1 * 100 = 10 (gam)
mdd = 240 + 10,6 - 0,1 * 44 = 246,2 (gam)
C% = 82 * 0,2 / 246,2 * 100% = 6,66%
\(n_{Na_2CO_3}=\dfrac{10,6}{106}=0,1\left(mol\right)\)
PTHH:
Na2CO3 + 2CH3COOH ---> 2CH3COONa + CO2 + H2O
0,1---------->0,2----------------->0,2--------------->0,1
CO2 + Ca(OH)2 ---> CaCO3 + H2O
0,1------------------------->0,1
=> \(\left\{{}\begin{matrix}m_{ddCH_3COOH}=\dfrac{0,2.60}{5\%}=240\left(g\right)\\m_{CaCO_3}=0,1.100=10\left(g\right)\end{matrix}\right.\)
\(m_{dd}=10,6+240-0,1.44=246,2\left(g\right)\\ C\%_{CH_3COONa}=\dfrac{82.0,2}{246,2}.100\%=6,66\%\)
\(a.n_{CO_2}=\dfrac{0,672}{22,4}=0,03mol\\ CO_2+Ca\left(OH\right)_2\rightarrow CaCO_3+H_2O\)
\(n_{CO_2}=n_{Ca\left(OH\right)_2}=n_{CaCO_3}=0,03mol\\ m_{CaCO_3}=0,03.100=3g\\ b.V_{ddCa\left(OH\right)_2}=\dfrac{0,03}{1,5}=0,02l\)
a, \(C_2H_4+3O_2\underrightarrow{t^o}2CO_2+2H_2O\)
\(CO_2+Ca\left(OH\right)_2\rightarrow CaCO_{3\downarrow}+H_2O\)
Ta có: \(n_{C_2H_4}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\)
Theo PT: \(n_{O_2}=3n_{C_2H_4}=0,75\left(mol\right)\Rightarrow V_{O_2}=0,75.22,4=16,8\left(l\right)\)
b, Theo PT: \(n_{CaCO_3}=n_{CO_2}=2n_{C_2H_4}=0,5\left(mol\right)\)
\(\Rightarrow m_{CaCO_3}=0,5.100=50\left(g\right)\)
\(a,n_{K_2CO_3}=\dfrac{20,7}{138}=0,15(mol)\\ PTHH:K_2CO_3+2HCl\to 2KCl+H_2O+CO_2\uparrow\\ \Rightarrow n_{HCl}=2n_{K_2CO_3}=0,3(mol)\\ \Rightarrow m_{HCl}=0,3.36,5=10,95(g)\\ \Rightarrow m_{dd_{HCl}}=\dfrac{10,95}{7,3\%}=150(g)\\ b,n_{CO_2}=n_{K_2CO_3}=0,15(mol)\\ \Rightarrow V_{CO_2}=0,15.22,4=3,36(l)\)
\(c,n_{KCl}=n_{HCl}=0,3(mol);n_{H_2O}=n_{CO_2}=0,15(mol)\\ \Rightarrow m_{KCl}=0,3.74,5=22,35(g)\\ m_{H_2O}=0,15.18=2,7(g);m_{CO_2}=0,15.44=6,6(g)\\ \Rightarrow m_{dd_{KCl}}=20,7+150-2,7-6,6=161,4(g)\\ \Rightarrow C\%_{KCl}=\dfrac{22,35}{161,4}.100\%\approx13,85\%\\ d,PTHH:CO_2+Ba(OH)_2\to BaCO_3\downarrow+H_2O\\ \Rightarrow n_{BaCO_3}=n_{CO_2}=0,15(mol)\\ \Rightarrow m_{BaCO_3}=0,15.197=29,55(g)\\ \Rightarrow m_{BaCO_3(\text{Thực tế})}=29,55.75\%=22,1625(g)\)
a) \(n_{MgCO_3}=\dfrac{16,8}{84}=0,2\left(mol\right)\)
PTHH: MgCO3 + 2HCl ---> MgCl2 + CO2 + H2O
0,2--------------------->0,2----->0,2
=> \(m=m_{MgCl_2}=0,2.95=19\left(g\right)\)
\(m_{\text{dd}.sau.p\text{ư}}=150+16,8-0,2.44=158\left(g\right)\)
=> \(C\%_{MgCl_2}=\dfrac{19}{158}.100\%=12,025\%\)
b) CO2 + Ca(OH)2 ---> CaCO3 + H2O
0,2----->0,2------------>0,2
=> \(\left\{{}\begin{matrix}m_{kt}=m_{CaCO_3}=0,2.100=20\left(g\right)\\V_{\text{dd}Ca\left(OH\right)_2}=\dfrac{0,2}{3}=\dfrac{1}{15}\left(l\right)\end{matrix}\right.\)
a)
nBr2 = 0,2.0,2 = 0,04 (mol)
nCaCO3 = \(\dfrac{10}{100}=0,1\left(mol\right)\)
PTHH: C2H4 + Br2 --> C2H4Br2
0,04<--0,04---->0,04
C2H4 + 3O2 --to--> 2CO2 + 2H2O
0,04--------------->0,08
CH4 + 2O2 --to--> CO2 + 2H2O
0,02<-------------0,02
Ca(OH)2 + CO2 --> CaCO3 + H2O
0,1<------0,1
=> \(\left\{{}\begin{matrix}\%V_{CH_4}=\dfrac{0,02}{0,02+0,04}.100\%=33,33\%\\\%V_{C_2H_4}=\dfrac{0,04}{0,02+0,04}.100\%=66,67\%\end{matrix}\right.\)
b) mC2H4Br2 = 0,04.188 = 7,52 (g)
Cảm ơn bạn