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nNa2CO3 = 10,6 / 106 = 0,1 (mol)
Na2CO3 + 2CH3COOH -> 2CH3COONa + H2O + CO2
0,1 0,2 0,2 0,1
mdd CH3COOH = 0,2 * 60 / 5 * 100 = 240 (gam)
CO2 + Ca(OH)2 -> CaCO3 + H2O
0,1 0,1
mCaCO3 = 0,1 * 100 = 10 (gam)
mdd = 240 + 10,6 - 0,1 * 44 = 246,2 (gam)
C% = 82 * 0,2 / 246,2 * 100% = 6,66%
\(n_{Na_2CO_3}=\dfrac{10,6}{106}=0,1\left(mol\right)\)
PTHH:
Na2CO3 + 2CH3COOH ---> 2CH3COONa + CO2 + H2O
0,1---------->0,2----------------->0,2--------------->0,1
CO2 + Ca(OH)2 ---> CaCO3 + H2O
0,1------------------------->0,1
=> \(\left\{{}\begin{matrix}m_{ddCH_3COOH}=\dfrac{0,2.60}{5\%}=240\left(g\right)\\m_{CaCO_3}=0,1.100=10\left(g\right)\end{matrix}\right.\)
\(m_{dd}=10,6+240-0,1.44=246,2\left(g\right)\\ C\%_{CH_3COONa}=\dfrac{82.0,2}{246,2}.100\%=6,66\%\)
Na2CO3 + 2HCl \(\rightarrow\)2NaCl + CO2 + H2O (1)
Ca(OH)2 + CO2 \(\rightarrow\)CaCO3 + H2O (2)
nNa2CO3=\(\dfrac{10,6}{106}=0,1\left(mol\right)\)
Theo PTHH 1 ta có:
2nNa2CO3=nHCl=0,2(mol)
V dd HCl=\(\dfrac{0,2}{0,5}=0,4\left(lít\right)\)
b;
Theo PTHH 1 ta có:
nNa2CO3=nCO2=0,1(mol)
Theo PTHH 2 ta có:
nCO2=nCaCO3=0,1(mol)
mCaCO3=100.0,1=10(g)
`n_[Na_2 CO_3]=[2,76]/106=0,03(mol)`
`Na_2 CO_3 +2CH_3 COOH->2CH_3 COONa+H_2 O+CO_2\uparrow`
`0,03` `0,06` `0,03` `(mol)`
`CO_2 +Ca(OH)_2 ->CaCO_3 \downarrow+H_2 O`
`0,03` `0,03`
`a)CH_3 COONa` là muối natri axetat.
`V_[dd CH_3 COOH]=[0,06]/[0,2]=0,3(l)`
`b)m_[CaCO_3]=0,03.100=3(g)`
a, CH3COONa: Natri axetat
PT: \(Na_2CO_3+2CH_3COOH\rightarrow2CH_3COONa+CO_2+H_2O\)
Ta có: \(n_{Na_2CO_3}=\dfrac{2,76}{106}=0,026\left(mol\right)\)
Theo PT: \(n_{CH_3COOH}=2n_{Na_2CO_3}=0,052\left(mol\right)\Rightarrow V_{CH_3COOH}=\dfrac{0,052}{0,2}=0,26\left(l\right)\)
b, \(CO_2+Ca\left(OH\right)_2\rightarrow CaCO_{3\downarrow}+H_2O\)
Theo PT: \(n_{CaCO_3}=n_{CO_2}=n_{Na_2CO_3}=0,026\left(mol\right)\)
\(\Rightarrow m_{CaCO_3}=0,026.100=2,6\left(g\right)\)
\(MgCO_3+2HCl\rightarrow MgCl_2+H_2O+CO_2\)
\(CO_2+Na\left(OH\right)_2\rightarrow CaCO_3+H_2O\)
b. \(n_{MgCO_3}=\dfrac{21}{84}=0,25mol\) \(\Rightarrow n_{HCl}=2.0,25=0,5mol\)
\(V_{ddHCl}=\dfrac{0,5}{2}=0,25l\)
c. \(n_{CO_2}=n_{MgCO_3}=0,25mol\)
\(n_{CaCO_3}=n_{CO_2}=0,25mol\)
\(\Rightarrow m_{CaCO_3}=0,25.100=25g\)
\(a)n_{K_2CO_3}=\dfrac{2,76}{138}=0,02mol\\ K_2CO_3+2CH_3COOH\rightarrow2CH_3COOK+CO_2+H_2O\)
0,02 0,04 0,04 0,02 0,02
\(V_{ddCH_3COOH}=\dfrac{0,04}{0,2}=0,2l\\ b)n_{Ca\left(OH\right)_2}=2.0,0075=0,015mol\\ T=\dfrac{0,015}{0,02}=0,75\\ \Rightarrow0,5< T< 1\)
Tạo 2 muối
\(n_{CaCO_3}=a;n_{Ca\left(HCO_3\right)_2}=b\\ Ca\left(OH\right)_2+CO_2\rightarrow CaCO_3+H_2O\)
a a a a
\(Ca\left(OH\right)_2+2CO_2\rightarrow Ca\left(HCO_3\right)_2\)
b 2b b
\(\Rightarrow\left\{{}\begin{matrix}a+b=0,015\\a+2b=0,02\end{matrix}\right.\\ \Rightarrow a=0,01;b=0,005\\ m_{CaCO_3}=0,01.100=1g\)
\(a,n_{Mg}=\dfrac{4,8}{24}=0,2\left(mol\right)\\ Mg+2HCl\rightarrow MgCl_2+H_2\\ b,n_{MgCl_2}=n_{H_2}=n_{Mg}=0,2\left(mol\right)\\ b,V_{H_2\left(25\text{đ}\text{ộ}C,1bar\right)}=0,2.24,79=4,958\left(l\right)\\ c,n_{HCl}=2.0,2=0,4\left(mol\right)\\ m_{\text{dd}HCl}=\dfrac{0,4.36,5.100}{10}=146\left(g\right)\\ m_{\text{dd}A}=m_{Mg}+m_{\text{dd}HCl}-m_{H_2}=4,8+146-0,2.2=150,4\left(g\right)\\ d,C\%_{\text{dd}MgCl_2}=\dfrac{95.0,2}{150,4}.100\approx12,633\%\)
\(PTHH:Zn+H_2SO_4\to ZnSO_4+H_2\\ CuO+H_2SO_4\to CuSO_4+H_2O\\ \Rightarrow n_{Zn}=n_{H_2}=\dfrac{4,48}{22,4}=0,2(mol)\\ \Rightarrow m_{Zn}=0,2.65=13(g)\\ \Rightarrow \%_{Zn}=\dfrac{13}{21}.100\%=61,9\%\\ \Rightarrow \%_{CuO}=100\%-61,9\%=38,1\%\\ \Rightarrow n_{CuO}=\dfrac{21-13}{80}=0,1(mol)\\ \Rightarrow \Sigma n_{H_2SO_4}=0,1+0,2=0,3(mol)\\ \Rightarrow V_{dd_{H_2SO_4}}=\dfrac{0,3}{0,5}=0,6(l)\)