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Bài 1 :
$n_{CO_2} = \dfrac{3,136}{22,4} = 0,14(mol)$
$n_{Ca(OH)_2} = 0,8.0,1 = 0,08(mol)$
CO2 + Ca(OH)2 → CaCO3 + H2O
0,08.......0,08...........0,08........................(mol)
CaCO3 + CO2 + H2O → Ca(HCO3)2
0,06........0,06........................................(mol)
Suy ra : $m_{CaCO_3} = (0,08 - 0,06).100 = 2(gam)$
Bài 2 :
$n_{CO_2} = \dfrac{2,24}{22,4} = 0,1(mol) ; n_{NaOH} = 0,1.1,5 = 0,15(mol)$
2NaOH + CO2 → Na2CO3 + H2O
0,15........0,075.......0,075....................(mol)
Na2CO3 + CO2 + H2O → 2NaHCO3
0,025........0,025...................0,05..............(mol)
Suy ra:
$C_{M_{NaHCO_3}} = \dfrac{0,05}{0,1} = 0,5M$
$C_{M_{Na_2CO_3}} = \dfrac{0,075 - 0,025}{0,1} = 0,5M$
b)
$NaOH + HCl \to NaCl + H_2O$
$n_{HCl} = n_{NaOH} = 0,15(mol)$
$m_{dd\ HCl} = \dfrac{0,15.36,5}{25\%} = 21,9(gam)$
\(a.n_{CO_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\\ a.Ca\left(OH\right)_2+CO_2\rightarrow CaCO_3+H_2O\\ 0,25.......0,25............0,25..........0,25\left(mol\right)\\ C_{MddCa\left(OH\right)_2}=\dfrac{0,25}{0,1}=2,5\left(M\right)\\ b.m_{\downarrow}=m_{CaCO_3}=100.0,25=25\left(g\right)\)
`n_[Na_2 CO_3]=[2,76]/106=0,03(mol)`
`Na_2 CO_3 +2CH_3 COOH->2CH_3 COONa+H_2 O+CO_2\uparrow`
`0,03` `0,06` `0,03` `(mol)`
`CO_2 +Ca(OH)_2 ->CaCO_3 \downarrow+H_2 O`
`0,03` `0,03`
`a)CH_3 COONa` là muối natri axetat.
`V_[dd CH_3 COOH]=[0,06]/[0,2]=0,3(l)`
`b)m_[CaCO_3]=0,03.100=3(g)`
a, CH3COONa: Natri axetat
PT: \(Na_2CO_3+2CH_3COOH\rightarrow2CH_3COONa+CO_2+H_2O\)
Ta có: \(n_{Na_2CO_3}=\dfrac{2,76}{106}=0,026\left(mol\right)\)
Theo PT: \(n_{CH_3COOH}=2n_{Na_2CO_3}=0,052\left(mol\right)\Rightarrow V_{CH_3COOH}=\dfrac{0,052}{0,2}=0,26\left(l\right)\)
b, \(CO_2+Ca\left(OH\right)_2\rightarrow CaCO_{3\downarrow}+H_2O\)
Theo PT: \(n_{CaCO_3}=n_{CO_2}=n_{Na_2CO_3}=0,026\left(mol\right)\)
\(\Rightarrow m_{CaCO_3}=0,026.100=2,6\left(g\right)\)
\(n_{CH_4}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\\ PTHH:CH_4+2O_2\underrightarrow{t^o}CO_2\uparrow+2H_2O\\ \left(mol\right)....0,25\rightarrow.......0,25\\ PTHH:CO_2+Ca\left(OH\right)_2\rightarrow CaCO_3\downarrow+H_2O\\ \left(mol\right)....0,25\rightarrow..0,25...........0,25\\ a,m_{CaCO_3}=0,25.100=25\left(g\right)\\ c,m_{Ca\left(OH\right)_2}=0,25.56=14\left(g\right)\\ C\%_{Ca\left(OH\right)_2}=\dfrac{14}{200}.100\%=7\%\)
\(n_{C_2H_4}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\\ PTHH:C_2H_4+3O_2\rightarrow\left(t^o\right)2CO_2+2H_2O\\ n_{O_2}=3.0,4=1,2\left(mol\right);n_{CO_2}=0,4.2=0,8\left(mol\right)\\ a,V_{O_2\left(đktc\right)}=22,4.1,2=26,88\left(l\right)\\ b,V_{kk\left(đktc\right)}=\dfrac{100}{20}.26,88=134,4\left(l\right)\\ c,CO_2+Ca\left(OH\right)_2\rightarrow CaCO_3\downarrow\left(trắng\right)+H_2O\\ n_{CaCO_3}=n_{CO_2}=0,8\left(mol\right)\\ m_{kết.tủa}=m_{CaCO_3}=100.0,8=80\left(g\right)\)
1.
\(n_{CO_2}=\dfrac{2.24}{22.4}=0.1\left(mol\right)\)
\(n_{Ca\left(OH\right)_2}=0.075\left(mol\right)\)
\(T=\dfrac{0.1}{0.075}=1.33\)
=> Tạo ra 2 muối
\(n_{CaCO_3}=a\left(mol\right),n_{Ca\left(HCO_3\right)_2}=b\left(mol\right)\)
Khi đó :
\(a+b=0.075\)
\(a+2b=0.1\)
\(\Rightarrow\left\{{}\begin{matrix}a=0.05\\b=0.025\end{matrix}\right.\)
\(m_{sp}=0.05\cdot100+0.025\cdot162=9.05\left(g\right)\)
2.
\(n_{CO_2}=\dfrac{1.12}{22.4}=0.05\left(mol\right)\)
\(n_{Ba\left(OH\right)_2}=0.2\cdot0.2=0.04\left(mol\right)\)
\(T=\dfrac{0.005}{0.04}=1.25\)
=> Tạo ra 2 muối
\(n_{BaCO_3}=a\left(mol\right),n_{Ba\left(HCO_3\right)_2}=b\left(mol\right)\)
Ta có :
\(a+b=0.04\)
\(a+2b=0.05\)
\(\Rightarrow\left\{{}\begin{matrix}a=0.03\\b=0.01\end{matrix}\right.\)
\(m_{BaCO_3}=0.03\cdot197=5.91\left(g\right)\)
a) $CaCO_3 + 2HCl \to CaCl_2 + CO_2 + H_2O$
Theo PTHH :
$n_{CO_2} = n_{CaCO_3} = \dfrac{10}{100} = 0,1(mol)$
$V_{CO_2} = 0,1.22,4 = 2,24(lít)$
b) $n_{HCl} = 2n_{CaCO_3} = 0,2(mol)$
$C_{M_{HCl}} = \dfrac{0,2}{0,25} = 0,8M$
c) $CO_2 + Ca(OH)_2 \to CaCO_3 + H_2O$
$n_{CaCO_3} = n_{CO_2} = 0,1(mol)$
$m_{CaCO_3} = 0,1.100 = 10(gam)$
a, \(n_{CO_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\)
PTHH: CO2 + Ca(OH)2 → CaCO3 ↓ + H2O
Mol: 0,25 0,25 0,25
\(C_{M_{ddCa\left(OH\right)_2}}=\dfrac{0,25}{0,1}=2,5M\)
b, \(m_{CaCO_3}=0,25.100=25\left(g\right)\)
c,
PTHH: Ca(OH)2 + 2HCl → CaCl2 + 2H2O
Mol: 0,25 0,5
\(m_{ddHCl}=\dfrac{0,5.36,5.100}{20}=91,25\left(g\right)\)
\(a.n_{CO_2}=\dfrac{0,672}{22,4}=0,03mol\\ CO_2+Ca\left(OH\right)_2\rightarrow CaCO_3+H_2O\)
\(n_{CO_2}=n_{Ca\left(OH\right)_2}=n_{CaCO_3}=0,03mol\\ m_{CaCO_3}=0,03.100=3g\\ b.V_{ddCa\left(OH\right)_2}=\dfrac{0,03}{1,5}=0,02l\)
672 mà đâu phải 0.672