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\(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
PTHH:
\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
0,2 0,2 0,2 0,2
\(a,\%m_{Fe}=\dfrac{0,2.56}{20}.100\%=56\%\)
\(\%m_{Cu}=100\%-56\%=44\%\)
\(b,C_{M\left(H_2SO_4\right)}=\dfrac{0,2}{0,1}=2\left(M\right)\)
\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
\(1\) \(1\) \(1\)
\(0,2\) \(0,2\) \(0,2\)
\(n_{H_2}=\dfrac{V}{22,4}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
\(m_{Fe}=n.M=0,2.56=11,2\left(g\right)\)
\(^0/_0Fe=\dfrac{11,2}{20}.100^0/_0=56^0/_0\)
\(^0/_0Cu=100^0/_0-56^0/_0=44^0/_0\)
\(C_{M_{H_2SO_4}}=\dfrac{n}{V_{dd}}=\dfrac{0,2}{0,1}=2M\)
\(n_{Fe} = a(mol) ; n_{Mg} = b(mol)\\ \Rightarrow 56a + 24b = 16,8 - 6,4 = 10,4(1)\\ Fe + 2HCl \to FeCl_2 + H_2\\ Mg + 2HCl \to MgCl_2 + H_2\\ n_{H_2} = a + b = \dfrac{6,72}{22,4} = 0,3(2)\)
Từ (1)(2) suy ra: a = 0,1 ; b = 0,2
Vậy :
\(\%m_{Fe} = \dfrac{0,1.56}{16,8}.100\% = 33,33\%\\ \%m_{Mg} = \dfrac{0,2.24}{16,8}.100\% = 28,57\%\\ \%m_{Cu} = 100\% - 33,33\% - 28,57\% = 38,1\%\)
\(n_{H_2}=\dfrac{1,12}{22,4}=0,05(mol)\\ Fe+2HCl\to FeCl_2+H_2\\ \Rightarrow n_{Fe}=0,05(mol)\\ \Rightarrow \%_{Fe}=\dfrac{0,05.56}{20}.100\%=14\%\\ \Rightarrow \%_{Cu}=100\%-14\%=86\%\)
a, \(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
b, Ta có: 27nAl + 56nFe = 5,5 (1)
Theo PT: \(n_{H_2}=\dfrac{3}{2}n_{Al}+n_{Fe}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\left(2\right)\)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{Al}=0,1\left(mol\right)\\n_{Fe}=0,05\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Al}=\dfrac{0,1.27}{5,5}.100\%\approx49,09\%\\\%m_{Fe}\approx50,91\%\end{matrix}\right.\)
PTHH: \(Mg+2HCl\rightarrow MgCl_2+H_2\uparrow\) (1)
\(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\) (2)
a) Ta có: \(\Sigma n_{H_2}=\dfrac{17,92}{22,4}=0,8\left(mol\right)\)
Gọi số mol của Mg là \(a\) \(\Rightarrow n_{H_2\left(1\right)}=a\)
Gọi số mol của Fe là \(b\) \(\Rightarrow n_{H_2\left(2\right)}=b\)
Ta lập được hệ phương trình:
\(\left\{{}\begin{matrix}a+b=0,8\\24a+56b=25,6\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}a=0,6\\b=0,2\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}n_{Mg}=0,6mol\\n_{Fe}=0,2mol\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}m_{Mg}=0,6\cdot24=14,4\left(g\right)\\m_{Fe}=11,2\left(g\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}\%m_{Mg}=\dfrac{14,4}{25,6}\cdot100\%=56,25\%\\\%m_{Fe}=43,75\%\end{matrix}\right.\)
b) Theo PTHH: \(\left\{{}\begin{matrix}n_{HCl\left(1\right)}=2n_{Mg}=1,2mol\\n_{HCl\left(2\right)}=2n_{Fe}=0,4mol\end{matrix}\right.\)
\(\Rightarrow\Sigma n_{HCl}=1,6mol\) \(\Rightarrow V_{ddHCl}=\dfrac{1,6}{2}=0,8\left(l\right)=800ml\)
c) PTHH: \(MgCl_2+2NaOH\rightarrow2NaCl+Mg\left(OH\right)_2\downarrow\)
\(FeCl_2+2NaOH\rightarrow2NaCl+Fe\left(OH\right)_2\downarrow\)
Theo các PTHH: \(\left\{{}\begin{matrix}n_{Mg\left(OH\right)_2}=n_{MgCl_2}=n_{Mg}=0,6mol\\n_{Fe\left(OH\right)_2}=n_{FeCl_2}=n_{Fe}=0,2mol\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}m_{Fe\left(OH\right)_2}=0,2\cdot90=18\left(g\right)\\m_{Mg\left(OH\right)_2}=0,6\cdot58=34,8\left(g\right)\end{matrix}\right.\)
\(\Rightarrow m_{kếttủa}=18+34,8=52,8\left(g\right)\)
\(n_{Fe}=\dfrac{0,224}{22,4}=0,01\left(mol\right)\)
Pt : \(Fe+2HCl\rightarrow FeCl_2+H_2|\)
1 2 1 1
0,01 0,02 0,01
a) \(n_{Fe}=\dfrac{0,01.1}{1}=0,01\left(mol\right)\)
\(m_{Fe}=0,01.56=0,56\left(g\right)\)
\(m_{Cu}=1,2-0,56=0,64\left(g\right)\)
0/0Fe = \(\dfrac{0,56.100}{1,2}=46,67\)0/0
0/0Cu = \(\dfrac{0,64.100}{1,2}=53,33\)0/0
b) \(n_{HCl}=\dfrac{0,01.2}{1}=0,02\left(mol\right)\)
⇒ \(m_{HCl}=0,02.36,5=0,73\left(g\right)\)
\(C_{ddHCl}=\dfrac{0,73.100}{10}=7,3\)0/0
Chúc bạn học tốt
Ta có: \(\left\{{}\begin{matrix}x=Fe\\y=Cu\end{matrix}\right.\) trong 40g hh
\(n_{H_2}=\dfrac{V_{H_2}}{22,4}=\dfrac{11,2}{22,4}=0,5mol\)
PTHH: Fe + 2HCl \(\rightarrow\) FeCl2 + H2
TL: 1 2 1 1
mol: 0,5 \(\leftarrow\) 1 \(\leftarrow\) 0,5 \(\leftarrow\) 0,5
\(m_{Fe}=n.M=0,5.56=28g\)
\(\%m_{Fe}=\dfrac{m_{Fe}}{m_{hh}}.100\%=\dfrac{28}{40}.100\%=70\%\)
\(\%m_{Cu}=100\%-70\%=30\%\)
Đặt \(\begin{cases} n_{Fe}=x(mol)\\ n_{Mg}=y(mol) \end{cases}\Rightarrow 56x+24y=8(1)\)
\(n_{H_2}=\dfrac{4,48}{22,4}=0,2(mol)\\ PTHH:Fe+2HCl\to FeCl_2+H_2\\ Mg+2HCl\to MgCl_2+H_2\\ \Rightarrow x+y=0,2(2)\\ (1)(2)\Rightarrow \begin{cases} x=0,1(mol)\\ y=0,1(mol) \end{cases}\Rightarrow \begin{cases} m_{Fe}=0,1.56=5,6(g)\\ m_{Mg}=0,1.24=2,4(g) \end{cases} \)
PTHH:
Fe + 2HCl ---> FeCl2 + H2
Cu + HCl ---x--->
Ta có: \(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
Theo PT: \(n_{Fe}=n_{H_2}=0,2\left(mol\right)\)
=> \(m_{Fe}=0,2.56=11,2\left(g\right)\)
=> \(\%_{m_{Fe}}=\dfrac{11,2}{15,6}.100\%=71,79\%\)
=> \(\%_{m_{Cu}}=100\%-71,79\%=28,21\%\)
\(n_{H_2}=\dfrac{4,48}{22,4}=0,2mol\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
0,2 0,2
\(m_{Fe}=0,2\cdot56=11,2\left(g\right)\) \(\Rightarrow\%m_{Fe}=\dfrac{11,2}{15,6}\cdot100\%\approx71,8\%\)
\(\Rightarrow\%m_{Cu}=100\%-71,8\%=28,2\%\)