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![](https://rs.olm.vn/images/avt/0.png?1311)
A: MgO, CuO
B: MgCl2, CuCl2
C: Mg(OH)2, Cu(OH)2
PT: \(2Mg+O_2\underrightarrow{t^o}2MgO\)
\(2Cu+O_2\underrightarrow{t^o}2CuO\)
\(MgO+2HCl\rightarrow MgCl_2+H_2O\)
\(CuO+2HCl\rightarrow CuCl_2+H_2O\)
\(MgCl_2+2NaOH\rightarrow2NaCl+Mg\left(OH\right)_{2\downarrow}\)
\(CuCl_2+2NaOH\rightarrow2NaCl+Cu\left(OH\right)_{2\downarrow}\)
\(Mg\left(OH\right)_2\underrightarrow{t^o}MgO+H_2O\)
\(Cu\left(OH\right)_2\underrightarrow{t^o}CuO+H_2O\)
![](https://rs.olm.vn/images/avt/0.png?1311)
1. Gọi mol của Mg và Al là x, y mol
=> 24x + 27y = 12,6 (1)
nH2 = 0,6 mol => x + 1,5y = 0,6 (2)
Từ (1) (2) => x = 0,3 ; y = 0,2
=> %Mg = 57,14%
=> %Al = 42,86%
nH2=13,44/22,4=0,6(mol)
Đặt: nMg=a(mol); nAl=b(mol) (a,b>0)
1) PTHH: Mg + H2SO4 -> MgSO4 + H2
a__________a________a_____a(mol)
2Al +3 H2SO4 -> Al2(SO4)3 + 3 H2
b___1,5b______0,5b____1,5b(mol)
Ta có hpt:
\(\left\{{}\begin{matrix}24a+27b=12,6\\a+1,5b=0,6\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,3\\b=0,2\end{matrix}\right.\)
=> mMg=0,3.24=7,2(g)
=>%mMg= (7,2/12,6).100=57,143%
=>%mAl=42,857%
2) mMgSO4=120.a=120.0,3=36(g)
mAl2(SO4)3=342.0,5b=342.0,5.0,2= 34,2(g)
mH2SO4= (0,3+0,2.1,5).98=58,8(g)
=>mddH2SO4=58,8: 14,7%=400(g)
=>mddsau= 12,6+400 - 2.0,6= 411,4(g)
=>C%ddAl2(SO4)3= (34,2/411,4).100=8,313%
C%ddMgSO4=(36/411,4).100=8,751%
![](https://rs.olm.vn/images/avt/0.png?1311)
\(n_{O_2}=\frac{1.68}{22.4}=0.075\left(mol\right)\)
\(4Na+O_2\rightarrow2Na_2O\)
x \(\frac{1}{4}x\) \(\frac{1}{2}x\)
\(4K+O_2\rightarrow2K_2O\)
x \(\frac{1}{4}x\) \(\frac{1}{2}x\)
Theo bài ra ta có \(\begin{cases}23x+39y=10.1\\\frac{1}{4}x+\frac{1}{4}y=0.075\end{cases}\) \(\begin{cases}0.1\\0.2\end{cases}\)
\(m_{Na}=0.1\times23=2.3\left(g\right)\)
\(m_K=0.2\times39=7.8\left(g\right)\)
\(\%m_{Na}=\frac{2.3}{10.1}\times100=22.7\%\)\(\%m_K=100\%-22.7\%=77.3\%\)![](https://rs.olm.vn/images/avt/0.png?1311)
Chất rắn D là Cu, chất rắn E là CuO
\(m_{tăng}=m_{O_2}=0,16\left(g\right)\)
=> \(n_{O_2}=\dfrac{0,16}{32}=0,005\left(mol\right)\)
PTHH: 2Cu + O2 --to--> 2CuO
0,01<-0,005
=> mCu = 0,01.64 = 0,64 (g)
Gọi số mol K, Ba là a, b (mol)
=> 39a + 137b = 3,18 - 0,64 = 2,54 (1)
PTHH: 2K + 2H2O --> 2KOH + H2
a--------------->a
Ba + 2H2O --> Ba(OH)2 + H2
b--------------->b
=> 56a + 171b = 3,39 (2)
(1)(2) => a = 0,03 (mol); b = 0,01 (mol)
=> \(\left\{{}\begin{matrix}\%m_{Cu}=\dfrac{0,64}{3,18}.100\%=20,126\%\\\%m_K=\dfrac{0,03.,39}{3,18}.100\%=36,792\%\\\%m_{Ba}=\dfrac{0,01.137}{3,18}.100\%=43,082\%\end{matrix}\right.\)
\(m_{O_2}=m+0,16-m=0,16\left(g\right)\\ \rightarrow n_{O_2}=\dfrac{0,16}{32}=0,005\left(mol\right)\)
PTHH: 2Cu + O2 --to--> 2CuO
0,01 0,005
Gọi \(\left\{{}\begin{matrix}n_K=a\left(mol\right)\\n_{Ba}=b\left(mol\right)\end{matrix}\right.\)
PTHH:
2K + 2H2O ---> 2KOH + H2
a a
Ba + 2H2O ---> Ba(OH)2 + H2
b b
Hệ pt \(\left\{{}\begin{matrix}39a+137b=3,18-0,01.64=2,54\\56a+171b=3,39\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,03\left(mol\right)\\b=0,01\left(mol\right)\end{matrix}\right.\)
\(\rightarrow\left\{{}\begin{matrix}\%m_{Cu}=\dfrac{0,01.64}{3,18}=20,13\%\\\%m_K=\dfrac{0,03.39}{3,18}=36,79\%\\\%m_{Ba}=100\%-20,13\%-36,79\%=43,08\%\end{matrix}\right.\)
Đặt: nK= x mol
nMg= 2x mol
mhh= 39x + 24x*2= 8.7g
<=> x= 0.1
2K + 1/2O2 -to-> K2O
0.1__0.025______0.05
Mg + 1/2O2 -to-> MgO
0.2____0.1______0.2
VO2= (0.1+0.025)*22.4=2.8l
Rắn A: K2O, MgO
K2O + H2O --> 2KOH
0.05__________0.1
mK2O= 0.05*94=4.7g
dd B: KOH
Rắn C: MgO
CM KOH= 0.1/0.2=0.5M
mKOH= 0.1*56=5.6g
mH2O= 200*1=200g
mdd sau hòa tan= mK2O + mH2O= 4.7+200=204.7g
C% KOH= 5.6/204.7*100%= 2.73%