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\(n_{CO2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
a) Pt : \(CO_2+Ba\left(OH\right)_2\rightarrow BaCO_3+H_2O\)
Theo Pt : \(n_{CO2}=n_{Ba\left(OH\right)2}=n_{BaCO3}=0,1\left(mol\right)\)
b) \(V_{ddBa\left(OH\right)2}=\dfrac{0,1}{1}=0,1\left(l\right)\)
c) \(m_{kt}=m_{BaCO3}=0,1.197=19,7\left(g\right)\)
\(a.n_{CO_2}=\dfrac{0,672}{22,4}=0,03mol\\ CO_2+Ca\left(OH\right)_2\rightarrow CaCO_3+H_2O\)
\(n_{CO_2}=n_{Ca\left(OH\right)_2}=n_{CaCO_3}=0,03mol\\ m_{CaCO_3}=0,03.100=3g\\ b.V_{ddCa\left(OH\right)_2}=\dfrac{0,03}{1,5}=0,02l\)
PTHH : `Ba(OH)_2 + SO_2 -> BaSO_3 + H_2O`
`a)`
`600ml = 0,6l`
`n_{SO_2} = (6,72)/(22,4) = 0,3` `mol`
`n_{Ba(OH)_2} = n_{SO_2} = 0,3` `mol`
`C_{M_(Ba(OH)_2)} = (0,3)/(0,6) =0,5` `M`
`b)`
`n_{BaSO_3} = n_{SO_3} = 0,3` `mol`
`m_{BaSO_3} = 0,3 . 217 = 65,1` `gam`
`c)`
PTHH : `Ba(OH)_2 + 2HCl -> BaCl_2 + 2H_2O`
Ta có : `n_{Ba(OH)_2} = 0,3` `mol`
`n_{HCl} = 2 . n_{Ba(OH)_2} = 0,6` `mol`
`V_{HCl} = (0,6)/(3,5) = 6/35` `l`
1.
\(n_{CO_2}=\dfrac{2.24}{22.4}=0.1\left(mol\right)\)
\(n_{Ca\left(OH\right)_2}=0.075\left(mol\right)\)
\(T=\dfrac{0.1}{0.075}=1.33\)
=> Tạo ra 2 muối
\(n_{CaCO_3}=a\left(mol\right),n_{Ca\left(HCO_3\right)_2}=b\left(mol\right)\)
Khi đó :
\(a+b=0.075\)
\(a+2b=0.1\)
\(\Rightarrow\left\{{}\begin{matrix}a=0.05\\b=0.025\end{matrix}\right.\)
\(m_{sp}=0.05\cdot100+0.025\cdot162=9.05\left(g\right)\)
2.
\(n_{CO_2}=\dfrac{1.12}{22.4}=0.05\left(mol\right)\)
\(n_{Ba\left(OH\right)_2}=0.2\cdot0.2=0.04\left(mol\right)\)
\(T=\dfrac{0.005}{0.04}=1.25\)
=> Tạo ra 2 muối
\(n_{BaCO_3}=a\left(mol\right),n_{Ba\left(HCO_3\right)_2}=b\left(mol\right)\)
Ta có :
\(a+b=0.04\)
\(a+2b=0.05\)
\(\Rightarrow\left\{{}\begin{matrix}a=0.03\\b=0.01\end{matrix}\right.\)
\(m_{BaCO_3}=0.03\cdot197=5.91\left(g\right)\)