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a) PTHH: Mg +2 HCl -> MgCl2 + H2
nH2=11,2/22,4=0,5(mol)
=> nMg=nMgCl2=nH2=0,5(mol)
m=mMg=0,5.24=12(g)
b) mMgCl2=0,5.95=47,5(g)
mddMgCl2= mMg + mddHCl - mH2= 12+100-0,5.2= 111(g)
=>C%ddMgCl2= (47,5/111).100=42,793%
$a\big)$
$M_A=9,4.2=18,8(g/mol)$
$\to \dfrac{n_{CO_2}}{n_{H_2}}=\dfrac{18,8-2}{44-18,8}=\dfrac{2}{3}$
Mà $n_{CO_2}+n_{H_2}=\dfrac{11,2}{22,4}=0,5(mol)$
\(\begin{array} {l} \to n_{CO_2}=0,2(mol);n_{H_2}=0,3(mol)\\ Fe+2HCl\to FeCl_2+H_2\\ FeCO_3+2HCl\to FeCl_2+CO_2+H_2O\\ \text{Theo PT: }n_{Fe}=n_{H_2}=0,3(mol);n_{FeCO_3}=n_{CO_2}=0,2(mol)\\ \to m=0,3.56+0,2.116=40(g) \end{array}\)
$b\big)$
Đổi $400ml=0,4l$
\(\begin{array} {l} \text{Theo PT: }n_{FeCl_2}=n_{H_2}+n_{CO_2}=0,5(mol)\\ \to C_{M\,FeCl_2}=\dfrac{0,5}{0,4}=1,25M \end{array}\)
$c\big)$
\(\begin{array}{l} m_{dd\,FeCl_2}=\dfrac{400}{1,2}\approx 333,33(g)\\ \to C\%_{FeCl_2}=\dfrac{0,5.127}{333,33}.100\%=19,05\%\end{array}\)
a) 2Al + 6HCl --> 2AlCl3 + 3H2
b) \(n_{Al}=\dfrac{2,7}{27}=0,1\left(mol\right)\); nHCl = 0,5.2 = 1 (mol)
Xét tỉ lệ: \(\dfrac{0,1}{2}< \dfrac{1}{6}\) => Al hết, HCl dư
PTHH: 2Al + 6HCl --> 2AlCl3 + 3H2
0,1->0,3---->0,1---->0,15
=> VH2 = 0,15.22,4 = 3,36 (l)
c) \(\left\{{}\begin{matrix}C_{M\left(AlCl_3\right)}=\dfrac{0,1}{0,5}=0,2M\\C_{M\left(HCl.dư\right)}=\dfrac{1-0,3}{0,5}=1,4M\end{matrix}\right.\)
a,\(n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right);n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
PTHH: Fe + 2HCl → FeCl2 + H2
Mol: 0,15 0,3
Ta có: \(\dfrac{0,2}{1}>\dfrac{0,15}{1}\) ⇒ H2 pứ hết,Fe dư
\(V_{H_2}=3,36\left(l\right)\) (đề cho)
b, ko tính đc k/lg dd ,chỉ tính đc thể tích dd
\(V_{ddHCl}=\dfrac{0,2}{1}=0,2\left(l\right)=200\left(ml\right)\)
\(n_{Zn}=\dfrac{6,5}{65}=0,1\left(mol\right)\\
pthh:Zn+2HCl\rightarrow ZnCl_2+H_2\)
0,1 0,2 0,1 0,1
\(m_{HCl}=0,2.36,5=7,3\left(g\right)\\
V_{H_2}=0,1.22,4=2,24l\\
m_{\text{dd}}=6,5+200-\left(0,1.2\right)=206,3g\)
bài 2 :
\(n_{Mg}=\dfrac{4,8}{24}=0,2\left(mol\right)\\
pthh:Mg+2HCl\rightarrow MgCl_2+H_2\)
0,2 0,4 0,2 0,2
\(m_{HCl}=0,4.36,5=14,6g\\
V_{H_2}=0,2.22,4=4,48l\\
m\text{dd}=4,8+200-0,4=204,4g\\
C\%=\dfrac{0,2.136}{204,4}.100\%=13,3\%\)
`Fe + 2HCl -> FeCl_2 + H_2`
`0,2` `0,2` `0,2` `(mol)`
`n_[Fe]=[11,2]/56=0,2(mol)`
`a)m_[FeCl_2]=0,2.127=25,4(g)`
`b)V_[H_2]=0,2.22,4=4,48(l)`
`c)n_[O_2]=[4,48]/[22,4]=0,2(mol)`
`2H_2 + O_2` $\xrightarrow{t^o}$ `2H_2 O`
`0,2` `0,1` `0,2` `(mol)`
Ta có:`[0,2]/2 < [0,2]/1`
`=>O_2` dư
`=>m_[H_2 O]=0,2.18=3,6(g)`
\(\begin{array} {l} a)\\ Fe+2HCl\to FeCl_2+H_2\\ n_{Fe}=\dfrac{11,2}{56}=0,2(mol)\\ n_{FeCl_2}=n_{Fe}=0,2(mol)\\ m_{FeCl_2}=0,2.127=25,4(g)\\ b)\\ n_{H_2}=n_{Fe}=0,2(mol)\\ V_{H_2}=0,2.22,4=4,48(l)\\ c)\\ n_{O_2}=\dfrac{4,48}{22,4}=0,2(mol)\\ 2H_2+O_2\xrightarrow{t^o}2H_2O\\ \dfrac{n_{H_2}}{2}<n_{O_2}\to O_2\text{ dư}\\ n_{H_2O}=n_{H_2}=0,2(mol)\\ m_{H_2O}=0,2.18=3,6(g) \end{array}\)
a: \(Fe+2HCl\rightarrow FeCl_2+H_2\)
\(n_{Fe}=\dfrac{11.2}{56}=0.2\left(mol\right)\)
nên \(n_{FeCl_2}=0,2\left(mol\right)\)
\(m_{FeCl_2}=0.2\cdot127=25,4\left(g\right)\)
b: \(V_{H_2}=0.2\cdot22.4=4.48\left(lít\right)\)
Bài 1:
PTHH: \(Mg+2HCl\rightarrow MgCl_2+H_2\uparrow\)
Ta có: \(n_{Mg}=\dfrac{4,8}{24}=0,2\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{HCl}=0,4\left(mol\right)\\n_{H_2}=0,2\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{ddHCl}=\dfrac{0,4\cdot36,5}{14,6\%}=100\left(g\right)\\V_{H_2}=0,2\cdot22,4=4,48\left(l\right)\end{matrix}\right.\)
Bài 2:
PTHH: \(2KOH+H_2SO_4\rightarrow K_2SO_4+2H_2O\)
Ta có: \(\left\{{}\begin{matrix}n_{KOH}=\dfrac{100\cdot11,2\%}{56}=0,2\left(mol\right)\\n_{H_2SO_4}=\dfrac{150\cdot9,8\%}{98}=0,15\left(mol\right)\end{matrix}\right.\)
Xét tỉ lệ: \(\dfrac{0,2}{2}< \dfrac{0,15}{1}\) \(\Rightarrow\) H2SO4 còn dư, KOH p/ứ hết
\(\Rightarrow\left\{{}\begin{matrix}n_{K_2SO_4}=0,1\left(mol\right)\\n_{H_2SO_4\left(dư\right)}=0,05\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{K_2SO_4}=0,1\cdot174=17,4\left(g\right)\\m_{H_2SO_4\left(dư\right)}=0,05\cdot98=4,9\left(g\right)\end{matrix}\right.\)
Mặt khác: \(m_{dd}=m_{ddKOH}+m_{ddH_2SO_4}=250\left(g\right)\)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{K_2SO_4}=\dfrac{17,4}{250}\cdot100\%=6,96\%\\C\%_{H_2SO_4\left(dư\right)}=\dfrac{4,9}{250}\cdot100\%=1,96\%\end{matrix}\right.\)
Cảm ơn b nhiều ạ ❤️