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Gọi số mol O2, CO2 là a, b
Có: \(\overline{M}=\dfrac{32a+44b}{a+b}=19,5.2=39\)
=> \(a=\dfrac{5}{7}b\)
=> \(\left\{{}\begin{matrix}\%V_{O_2}=\dfrac{a}{a+b}.100\%=\dfrac{\dfrac{5}{7}b}{\dfrac{5}{7}b+b}.100\%=41,67\%\\\%V_{CO_2}=\dfrac{b}{a+b}.100\%=\dfrac{b}{\dfrac{5}{7}b+b}.100\%=58,33\%\end{matrix}\right.\)
\(\left\{{}\begin{matrix}\%m_{O_2}=\dfrac{32a}{32a+44b}.100\%=34,188\%\\\%m_{CO_2}=\dfrac{44b}{32a+44b}.100\%=65,812\%\end{matrix}\right.\)
thay a = \(\dfrac{5}{7}b\) thôi bn :)
\(\%m_{O_2}=\dfrac{32a}{32a+44b}.100\%=\dfrac{32.\dfrac{5}{7}b}{32.\dfrac{5}{7}b+44b}.100\%=34,188\%\)
\(Đặt:n_{hh}=1\left(mol\right)\)
\(n_{NO_2}=a\left(mol\right),n_{NO}=b\left(mol\right)\)
\(\Leftrightarrow a+b=1\left(1\right)\)
\(\overline{M}=\dfrac{46a+30b}{a+b}=18.2\cdot2=36.4\)
\(\Leftrightarrow46a+30b=36.4\left(2\right)\)
\(\left(1\right),\left(2\right):a=0.4,b=0.6\)
Tới đây tự tính tiếp nhé !!
Ta có: \(\overline{M}_{hh}=18,2\cdot2=36,4\left(đvC\right)\)
Theo sơ đồ đường chéo: \(\dfrac{n_{NO_2}}{n_{NO}}=\dfrac{6,4}{9,6}=\dfrac{2}{3}\)
\(\Rightarrow\left\{{}\begin{matrix}\%V_{NO_2}=\dfrac{2}{5}\cdot100\%=40\%\\\%V_{NO}=60\%\end{matrix}\right.\)
Giả sử \(n_{NO_2}=2\left(mol\right)\) \(\Rightarrow n_{NO}=3\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{NO_2}=\dfrac{2\cdot46}{2\cdot46+3\cdot30}\cdot100\%\approx50,55\%\\\%m_{NO}=49,45\%\end{matrix}\right.\)
a) \(\left\{{}\begin{matrix}n_{Cl_2}+n_{O_2}=\dfrac{6,72}{22,4}=0,3\\\overline{M}=\dfrac{71.n_{Cl_2}+32.n_{O_2}}{n_{Cl_2}+n_{O_2}}=2.29=58\end{matrix}\right.\)
=> \(\left\{{}\begin{matrix}n_{Cl_2}=0,2\left(mol\right)\\n_{O_2}=0,1\left(mol\right)\end{matrix}\right.\)
\(\left\{{}\begin{matrix}\%V_{Cl_2}=\dfrac{0,2}{0,3}.100\%=66,67\%\\\%V_{O_2}=\dfrac{0,1}{0,3}.100\%=33,33\%\end{matrix}\right.\)
b) \(\left\{{}\begin{matrix}m_{Cl_2}=0,2.71=14,2\left(g\right)\\m_{O_2}=0,1.32=3,2\left(g\right)\end{matrix}\right.\)
a)
$n_{Cl_2} : n_{O_2} = 1 : 2$
Suy ra :
$\%V_{Cl_2} = \dfrac{1}{1 + 2}.100\% = 33,33\%$
$\%V_{O_2} = \dfrac{2}{1 + 2}.100\% = 66,67\%$
b)
Coi $n_{Cl_2} = 1 (mol) \Rightarrow n_{O_2} = 2(mol)$
$\%m_{Cl_2} = \dfrac{1.71}{1.71 + 2.32}.100\% = 52,59\%$
$\%m_{O_2} = 100\% -52,59\% = 47,41\%$
c)
$M_A = \dfrac{71.1 + 32.2}{1 + 2} = 45(g/mol)$
$d_{A/B} = \dfrac{45}{28} = 1,607$
\(a.\)
\(GS:\)
\(n_{hh}=1\left(mol\right)\)
\(Đặt:n_{N_2}=a\left(mol\right),n_{CO_2}=b\left(mol\right)\)
\(\Rightarrow a+b=1\left(1\right)\)
\(m_A=28a+44b=18\cdot2=36\left(2\right)\)
\(\left(1\right),\left(2\right):\)
\(a=b=0.5\)
\(\%m_{N_2}=\dfrac{0.5\cdot28}{0.5\cdot28+0.5\cdot44}\cdot100\%=38.89\%\)
\(\%m_{CO_2}=61.11\%\)
\(b.\)
\(\dfrac{n_{N_2}}{n_{CO_2}}=\dfrac{0.5}{0.5}=\dfrac{1}{1}\)
\(n_{N_2}=n_{CO_2}=\dfrac{1}{2}\cdot n_A=\dfrac{0.2}{2}=0.1\left(mol\right)\)
\(Đặt:n_{CO_2}=x\left(mol\right)\)
\(\overline{M}=\dfrac{0.1\cdot28+0.1\cdot44+44x}{0.2+x}=20\cdot2=40\left(\dfrac{g}{mol}\right)\)
\(\Rightarrow x=0.2\)
\(m_{CO_2\left(cầnthêm\right)}=0.2\cdot44=8.8\left(g\right)\)
1, a, + 8.2=16 => CH4
+ 8,5 . 2 = 17 => NH3
+ 16 . 2 =32 => O2
+ 22 . 2 = 44 => CO2
b, + 0,138 . 29 \(\approx4\) => He
+ 1,172 . 29 \(\approx34\) => H2S
+ 2,448 . 29 \(\approx71\Rightarrow Cl_2\)
+ 0,965 . 29 \(\approx28\) => N
gọi số mol N2 là xmol ,H2 là ymol
n khí = 22,4/22,4=1mol=>x + y =1(1)
theo bài ra hỗn hợp khí có tỉ khối với H2 là 3,6 nên ta có pt
x-4y=0(2)
từ (1) và (2) => x=0,8 mol : y=0,2 mol
=> mN2 = 0,8 * 14=11,2 g , mH2=0,2*2=0,2 g
=> m Khí = 11,2 + 0,4=11,6 g
=>%mN2=11,2*100/11,6=96,55%
=>%mH2=100-96,55=3,45%
sao chỗ kia x=0,75 đâu ra đấy