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![](https://rs.olm.vn/images/avt/0.png?1311)
\(n_{hh}=\dfrac{13,44}{22,4}=0,6mol\)
\(\overline{M_x}=24.2=48\)
\(\left\{{}\begin{matrix}SO_2:64\\O_2:32\end{matrix}\right.\) 48 = \(\dfrac{16}{16}=1\)
\(\Rightarrow n_{SO_2=}n_{O_2}=0,3mol\)
1. \(m_{hh}=0,3.64+0,3.32=28,8g\)
2. \(\%V_{SO_2}=\dfrac{0,3.22,4}{13,44}.100\%=50\%\)
\(\Rightarrow\%V_{O_2}=50\%\)
3. \(m_{SO_2}=0,3.64=19,2g\)
\(m_{O_2}=0,3.32=9,6g\)
![](https://rs.olm.vn/images/avt/0.png?1311)
\(I,M_{hh}=M_{O_2}.0,3125=32.0,3125=10\left(\dfrac{g}{mol}\right)\\ Đặt:n_{N_2}=a\left(\%\right)\\ \Rightarrow\dfrac{28a+2\left(100\%-a\right)}{100\%}=10\\ \Leftrightarrow a\approx30,769\%=\%n_{N_2}=\%V_{N_2}\\ \Rightarrow\%V_{H_2}\approx69,231\%\\ II,Đặt:n_{N_2\left(thêm\right)}=k\left(mol\right)\\ n_{hh}=\dfrac{29,12}{22,4}=1,3\left(mol\right)\\ M_{hh.khí.mới}=M_{O_2}.0,46875=32.0,46875=15\left(\dfrac{g}{mol}\right)\\ \Leftrightarrow\dfrac{\left(k+0,13.0,30769\right).28+2.0,69231}{k+0,13}=15\\ \Leftrightarrow k=\left(ra.âm\right)\)
Nói chung làm được ý 1, anh thấy ý 2 ra âm. Em xem lại đề nha
Bài 1.
Gọi \(\left\{{}\begin{matrix}n_{N_2}=x\left(mol\right)\\n_{H_2}=y\left(mol\right)\end{matrix}\right.\)
\(\dfrac{d_{N_2,H_2}}{M_{O_2}}=0,3125\Rightarrow d_{N_2,H_2}=0,3125\cdot32=10\)
Sơ đồ chéo:
\(N_2\) 28 8
\(10\)
\(H_2\) 2 18
\(\Rightarrow\dfrac{N_2}{H_2}=\dfrac{x}{y}=\dfrac{8}{18}=\dfrac{4}{9}\)\(\Rightarrow9x-4y=0\left(1\right)\)
Mà \(x+y=\dfrac{29,12}{22,4}=1,3\left(2\right)\)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}x=0,4\\y=0,9\end{matrix}\right.\)
\(\%V_{N_2}=\dfrac{0,4}{0,4+0,9}\cdot100\%=30,77\%\)
\(\%V_{H_2}=100\%-30,77\%=69,23\%\)
![](https://rs.olm.vn/images/avt/0.png?1311)
Gọi số mol H2, O2 là a, b (mol)
=> \(\left\{{}\begin{matrix}a+b=\dfrac{22,4}{22,4}=1\\M_B=\dfrac{2a+32b}{a+b}=5,5.2=11\left(g/mol\right)\end{matrix}\right.\)
=> a = 0,7 (mol); b = 0,3 (mol)
PTHH: 2H2 + O2 --to--> 2H2O
Xét tỉ lệ: \(\dfrac{0,7}{2}>\dfrac{0,3}{1}\) => H2 dư, O2 hết
PTHH: 2H2 + O2 --to--> 2H2O
0,6<--0,3------->0,6
=> \(\left\{{}\begin{matrix}m_{H_2O}=0,6.18=10,8\left(g\right)\\m_{H_2\left(dư\right)}=\left(0,7-0,6\right).2=0,2\left(g\right)\end{matrix}\right.\)
![](https://rs.olm.vn/images/avt/0.png?1311)
a) \(\left\{{}\begin{matrix}n_{Cl_2}+n_{O_2}=\dfrac{6,72}{22,4}=0,3\\\overline{M}=\dfrac{71.n_{Cl_2}+32.n_{O_2}}{n_{Cl_2}+n_{O_2}}=2.29=58\end{matrix}\right.\)
=> \(\left\{{}\begin{matrix}n_{Cl_2}=0,2\left(mol\right)\\n_{O_2}=0,1\left(mol\right)\end{matrix}\right.\)
\(\left\{{}\begin{matrix}\%V_{Cl_2}=\dfrac{0,2}{0,3}.100\%=66,67\%\\\%V_{O_2}=\dfrac{0,1}{0,3}.100\%=33,33\%\end{matrix}\right.\)
b) \(\left\{{}\begin{matrix}m_{Cl_2}=0,2.71=14,2\left(g\right)\\m_{O_2}=0,1.32=3,2\left(g\right)\end{matrix}\right.\)
![](https://rs.olm.vn/images/avt/0.png?1311)
1)
Coi \(n_X = 1(mol)\)
Gọi : \(n_{CO_2} = a(mol) ; n_{N_2} = b(mol)\)
Ta có :
\(n_X = a + b = 1(mol)\\ m_X = 44a + 28b = 1.1,225.32(gam)\\ \Rightarrow a = 0,7 ; b = 0,3\)
Vậy :
\(\%V_{CO_2} = \dfrac{0,7}{1}.100\% = 70\%\\ \%V_{N_2} = 100\% - 70\% = 30\%\)
2)
\(n_X = \dfrac{1}{22,4}(mol)\\ \Rightarrow m_X = n.M = \dfrac{1}{22,4}.1,225.32 = 1,75(gam)\)
![](https://rs.olm.vn/images/avt/0.png?1311)
nX = 0,672/22,4 = 0,03 (mol)
Gọi nN2 = a (mol); nO2 = b (mol)
a + b = 0,03
28a + 32b = 0,88
=> a = 0,02 (mol); b = 0,01 (mol)
%VN2 = 0,02/0,03 = 66,66%
%VO2 = 100% - 66,66% = 33,34%
M(X) = 0,88/0,03 = 88/3 (g/mol)
nX = 2,2 : 88/3 = 0,075 (mol)
VH2 = VX = 0,075 . 22,4 = 1,68 (l)
gọi số mol N2 là xmol ,H2 là ymol
n khí = 22,4/22,4=1mol=>x + y =1(1)
theo bài ra hỗn hợp khí có tỉ khối với H2 là 3,6 nên ta có pt
x-4y=0(2)
từ (1) và (2) => x=0,8 mol : y=0,2 mol
=> mN2 = 0,8 * 14=11,2 g , mH2=0,2*2=0,2 g
=> m Khí = 11,2 + 0,4=11,6 g
=>%mN2=11,2*100/11,6=96,55%
=>%mH2=100-96,55=3,45%