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\(n_{H_2}=\dfrac{4,48}{22,4}=0,2mol\)
\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
0,2 0,2 ( mol )
\(m_{Fe}=0,2.56=11,2g\)
--> Chọn A
Fe + H2SO4-- > FeSO4 + H2
nH2 = 4,48 / 22,4 = 0,2 (mol)
=> nFe = 0,2 (mol)
= > mFe = 0,2.56 = 11,2 (g)
=> A
\(1.\\ n_A=\dfrac{16,8}{A}mol\\ n_{H_2}=\dfrac{7,437}{24,79}=0,3mol\\ A+2HCl\rightarrow ACl_2+H_2\\ \Rightarrow\dfrac{16,8}{A}=0,3\\ \Rightarrow A=56g/mol\\ \Rightarrow A.là.Fe\\ \Rightarrow Chọn.A\\ 2.\\ n_{Fe}=\dfrac{5,6}{56}=0,1mol\\ Fe+2HCl\rightarrow FeCl_2+H_2\\ n_{Fe}=n_{H_2}=0,1mol\\ V_{H_2}=0,1.24,79=2,479l\\ \Rightarrow Chọn.B\\ 3.\\ Axit:H_2SO_4;HCl\\ \Rightarrow Chọn.B\\ 4.\\ 3,719l\Rightarrow3,7185\\ CTHH:R\\ n_R=\dfrac{3,6}{R}mol\\ n_{H_2}=\dfrac{3,7185}{24,79}=0,15mol\\ R+2HCl\rightarrow RCl_2+H_2\\ \Rightarrow\dfrac{3,6}{R}=0,15\\ \Rightarrow R=24g/mol,Mg\\ \Rightarrow Chọn.B\)
PTHH: \(Fe_2O_3+3H_2\underrightarrow{t^o}2Fe+3H_2O\)
\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\uparrow\)
Ta có: \(n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)=n_{Fe}\)
\(\Rightarrow n_{Fe_2O_3}=0,15\left(mol\right)\) \(\Rightarrow m_{Fe_2O_3}=x=0,15\cdot160=24\left(g\right)\)
a) \(n_{Zn}=\dfrac{6,5}{65}=0,1\left(mol\right)\)
PTHH: Zn + 2HCl --> ZnCl2 + H2
0,1-->0,2------>0,1-->0,1
=> VH2 = 0,1.22,4 = 2,24 (l)
mZnCl2 = 0,1.136 = 13,6 (g)
b) \(C\%_{dd.HCl}=\dfrac{0,2.36,5}{200}.100\%=3,65\%\)
c) \(n_{O_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
PTHH: 2H2 + O2 --to--> 2H2O
Xét tỉ lệ: \(\dfrac{0,1}{2}< \dfrac{0,15}{1}\) => H2 hết, O2 dư
PTHH: 2H2 + O2 --to--> 2H2O
0,1--------------->0,1
=> mH2O = 0,1.18 = 1,8 (g)
\(\left\{{}\begin{matrix}m_{Mg}=\dfrac{40.9}{100}=3,6\left(g\right)\\m_{Al}=9-3,6=5,4\left(g\right)\end{matrix}\right.\\ \rightarrow\left\{{}\begin{matrix}n_{Mg}=\dfrac{3,6}{24}=0,15\left(mol\right)\\n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\end{matrix}\right.\)
PTHH:
Mg + 2HCl ---> MgCl2 + H2
0,15 ------------------------> 0,15
2Al + 6HCl ---> 2AlCl3 + 3H2
0,2 ---------------------------> 0,3
\(\rightarrow V_{H_2}=\left(0,15+0,3\right).22,4=10,08\left(l\right)\)
\(n_{H_2O}=\dfrac{6,48}{18}=0,36\left(mol\right)\)
PTHH: FexOy + yH2 --to--> xFe + yH2O
Theo pthh: \(n_{O\left(oxit\right)}=n_{H_2\left(pư\right)}=n_{H_2O}=0,36\left(mol\right)\)
\(\rightarrow m_{oxit}=15,12+16.0,36=20,88\left(g\right)\)
\(n_{Fe}=\dfrac{15,12}{56}=0,27\left(mol\right)\)
CTHH: FexOy
=> x : y = 0,27 : 0,36 = 3 : 4
=> CTHH: Fe3O4 (oxit sắt từ)
mMg = 40%x9 = 3,6(g) =>nMg=3,6:24 = 0,15 (mol)
=> mAl = 9-3,6 = 5,4(g) => nAl = 5,4:27 = 0,2 (mol)
pthh : 2Al+6HCl -> 2AlCl3+3H2
0,2 0,3
Mg+2HCl -> MgCl2 +H2
0,15 0,15
=> nH2 = 0,15 + 0,3 = 0,45 (mol)
=> VH2 = 0,45.22,4 = 10,08 (L)
mH2 = 0,45 . 2 = 0,9 (mol)
áp dụng BLBTKL ta có :
mH2 + moxit sắt = mFe + mH2O
=> moxit sắt = 20,7 (g)
Gọi \(n_{Fe}=x\left(mol\right)\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
\(n_{FeCl_2}=n_{Fe}=x\left(mol\right)\)
Vì khối lượng muối FeCl2 tăng 7,1g so với khối lượng bột Fe
\(\Rightarrow127x-56x=7,1\\ \Rightarrow x=0,1\)
\(n_{H_2}=n_{Fe}=0,1\left(mol\right)\\ V_{H_2\left(ĐKTC\right)}=0,1.22,4=2,24\left(l\right)\)
Chọn D
\(n_{Na}=\dfrac{4.6}{23}=0,2\left(mol\right)\)
\(n_{Fe}=\dfrac{8.4}{56}=0,15\left(mol\right)\)
\(n_{Al}=\dfrac{2.7}{27}=0,1\left(mol\right)\)
PTHH : Na + HCl -> NaCl + H2 ( 1 )
0,2 0,2
PTHH : Fe + HCl -> FeCl2 + H2 ( 2 )
0,15 0,15
PTHH : 2Al + 6HCl -> 2AlCl3 + 3H2 ( 3 )
0,1 0,15
\(V_{H_2\left(1\right)}=0,2.22,4=4,48\left(l\right)\)
\(V_{H_2\left(2\right)}=0,15.22,4=3,36\left(l\right)\)
\(V_{H_2\left(3\right)}=0,15.22,4=3,36\left(l\right)\)
\(n_{Fe_2O_3}=\dfrac{16}{160}=0,1\left(mol\right)\)
PTHH: Fe2O3 + 3H2 --to--> 2Fe + 3H2O
0,1---->0,3
Zn + H2SO4 --> ZnSO4 + H2
0,3<--------------------0,3
=> m = 0,3.65 = 19,5 (g)
nH2 = 4,958/24,79 = 0,2 (mol)
PTHH: Fe + 2HCl -> FeCl2 + H2
nFe = nH2 = 0,2 (mol)
mFe = 0,2 . 56 = 11,2 (g)
A