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a) $Zn+ 2HCl \to ZnCl_2 + H_2$
b) $n_{HCl} = \dfrac{250.7,3\%}{36,5} = 0,5(mol)$
$n_{Zn} = n_{H_2} = \dfrac{1}{2}n_{HCl} = 0,25(mol)$
$m = 0,25.65 =16,25(gam) ; V_{H_2} = 0,25.22,4 = 5,6(lít)$
c)
$m_{dd\ sau\ pư} = 16,25 + 250 - 0,25.2 = 265,75(gam)$
$C\%_{ZnCl_2} = \dfrac{0,25.136}{265,75}.100\% = 12,8\%$
\(a/ 4Zn+2HCl \to ZnCl_2+H_2 \\ n_{HCl}=\frac{250.7,3\%}{36,5}=0,5(mol)\\ b/ \\ n_{Zn}=n_{H_2}=n_{ZnCl_2}=\frac{1}{2}.n_{HCl}=\frac{1}{2}.0,5=0,25(mol)\\ m_{Zn}=0,25.65=16,25(g)\\ V_{H_2}=0,25.22,4=5,6(l)\\ c/ \\ C\%_{ZnCl_2}=\frac{0,25.136}{16,25+250-0,25.2}.100=12,8\% \)
a)
Zn+2HCl→ZnCl2+H2
b)
nHCl=250.7,3%/36,5=0,5(mol)
nZn=nH2=12nHCl=0,25(mol)
m=0,25.65=16,25(gam);VH2=0,25.22,4=5,6(lít)
c)
mdd sau pư=16,25+250−0,25.2=265,75(gam)
C%ZnCl2=0,25.136/265,75.100%=12,8%
Sửa: \(14,7\%\)
\(n_{H_2SO_4}=\dfrac{200.14,7\%}{100\%.98}=0,3(mol)\\ a,PTHH:2Al+3H_2SO_4\to Al_2(SO_4)_3+3H_2\\ \Rightarrow n_{H_2}=0,3(mol)\\ \Rightarrow V_{H_2}=0,3.22,4=6,72(l)\\ b,n_{Al}=\dfrac{2}{3}n_{H_2SO_4}=0,2(mol)\\ \Rightarrow m_{Al}=0,2.27=5,4(g)\\ c,n_{Al_2(SO_4)_3}=\dfrac{1}{2}n_{Al}=0,1(mol)\\ \Rightarrow C\%_{Al_2(SO_4)_3}=\dfrac{0,1.342}{200+5,4-0,3.2}.100\%=16,7\%\\ c,m_{Al_2(SO_4)_3}=0,1.342=34,2(g)\)
a) PTHH: \(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\uparrow\) (1)
\(ZnO+H_2SO_4\rightarrow ZnSO_4+H_2O\) (2)
b) Ta có: \(\left\{{}\begin{matrix}n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\\\Sigma n_{H_2SO_4}=0,2\cdot1=0,2\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow n_{Zn}=n_{ZnO}=n_{H_2SO_4\left(1\right)}=n_{H_2SO_4\left(2\right)}=0,1\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}m_{Zn}=0,1\cdot65=6,5\left(g\right)\\m_{ZnO}=0,1\cdot81=8,1\left(g\right)\end{matrix}\right.\)
c) Theo các PTHH: \(\left\{{}\begin{matrix}n_{Zn}=n_{ZnSO_4\left(1\right)}=0,1mol\\n_{ZnO}=n_{ZnSO_4\left(2\right)}=0,1mol\end{matrix}\right.\)
\(\Rightarrow\Sigma n_{ZnSO_4}=0,2mol\) \(\Rightarrow C_{M_{ZnSO_4}}=\dfrac{0,2}{0,2}=1\left(M\right)\)
(Coi như thể tích dd thay đổi không đáng kể)
Bài 1 :
\(n_{Zn}=\dfrac{13}{65}=0.2\left(mol\right)\)
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
\(0.2........0.4....................0.2\)
\(V_{dd_{HCl}}=\dfrac{0.4}{0.5}=0.8\left(l\right)\)
\(V_{H_2}=0.2\cdot22.4=4.48\left(l\right)\)
Bài 2 :
\(n_{Al}=\dfrac{5.4}{27}=0.2\left(mol\right)\)
\(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
\(0.2..........0.3.............................0.3\)
\(m_{H_2SO_4}=0.3\cdot98=29.4\left(g\right)\)
\(m_{dd_{H_2SO_4}}=\dfrac{29.4\cdot100}{10}=294\left(g\right)\)
\(V_{H_2}=0.3\cdot22.4=6.72\left(l\right)\)
\(n_{Al}=a\left(mol\right)\)
\(n_{Fe}=b\left(mol\right)\)
\(m=27a+56b=19.3\left(g\right)\left(1\right)\)
\(n_{H^+}=0.2\cdot2+0.2\cdot2.25\cdot2=1.3\left(mol\right)\)
\(2Al+6H^+\rightarrow2Al^{3+}+3H_2\)
\(Fe+2H^+\rightarrow Fe^{2+}+H_2\)
\(n_{H^+}=3a+2b=1.3\left(mol\right)\left(2\right)\)
\(\left(1\right),\left(2\right):a=0.3,b=0.2\)
\(\%Al=\dfrac{0.3\cdot27}{19.3}\cdot100\%=41.96\%\)
\(\%Fe=58.04\%\)
\(b.\)
\(n_{H_2}=\dfrac{1}{2}n_{H^+}=0.65\left(mol\right)\)
Bảo toàn khối lượng :
\(m_{Muối}=19.3+0.4\cdot36.5+0.45\cdot98-0.65\cdot2=76.7\left(g\right)\)
nH2 = 4,48 : 22,4 = 0,2 mol
gọi x,y lần lượt là số mol của Fe và Mg
PTHH : Fe + 2HCl → FeCl2 + H2
x mol 2x mol x mol
Mg + 2HCl → MgCl2 + H2
y mol 2y mol y mol
Ta có hệt phương trình:
\(\begin{cases}56x+24y=8\\x+y=0,2\end{cases}\)
Giải hệ phương trình ta có : x= 0,1 ; y = 0,1
Thể tích HCl là : VHCl = ( 2x + 2y ) . 22,4
= ( 2.0,1 + 2.0,1 ) . 22,4 = 8,96 lit
Khối lượng Mg là : mMg = 0,1 . 24 = 2,4 g
Khối lượng Fe là : mFe = 0,1 .56 = 5,6 g
@Vy Kiyllie bài này hình như thầy bảo kh đk giải hệ pt thỳ f
Ta có : C1=2C2
=> Gọi nH2SO4 =x
=> n HCl = 2x
Bảo toàn nguyên tố H :\(n_{HCl}.1+n_{H_2SO_4}.2=n_{H_2}.2\)
\(\Rightarrow2a+2a=\dfrac{13,44}{22,4}=0,6.2\)
=>a = 0,3(mol)
=> CMHCl = \(\dfrac{0,6}{0,3}=2M\); CMH2SO4 = \(\dfrac{0,3}{0,3}=1M\)
Dung dịch B gồm : Mg 2+ , Al3+ , Cl- , SO4 2-
\(n_{Cl^-}=n_{HCl}=0,6\left(mol\right);n_{SO_4^{2-}}=n_{H_2SO_4}=0,3\left(mol\right)\)
Bảo toàn điện tích cho dung dịch B:
\(n_{Mg}.2+n_{Al}.3=0,6+0,3.2\) (1)
Theo đề bài : \(24.n_{Mg}+27.n_{Al}=12,6\) (2)
Từ (1), (2)=> \(\left\{{}\begin{matrix}n_{Mg}=0,3\\n_{Al}=0,2\end{matrix}\right.\)
=> \(\%m_{Mg}=\dfrac{0,3.24}{12,6}.100=57,14\%\)
=> % m Al = 100 -57.14 = 42,86%
Câu 1:
\(n_{H_2}=\dfrac{2.91362}{22.4}=0.13mol\)
\(Mg+H_2SO_4\rightarrow MgSO_4+H_2\)
a a a a
\(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
2b 3b b 3b
Ta có: \(\left\{{}\begin{matrix}24a+54b=2.58\\a+3b=0.13\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0.04\\b=0.03\end{matrix}\right.\)
\(m_{Mg}=0.04\times24=0.96g\)
\(m_{Al}=0.03\times2\times27=1.62g\)
\(V_{H_2SO_4}=\dfrac{0.04+3\times0.03}{0.5}=0.26l\)
Câu 2:
\(n_{H_2}=\dfrac{3.136}{22.4}=0.14mol\)
\(Mg+H_2SO_4\rightarrow MgSO_4+H_2\)
a a a a
\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
b b b b
Ta có: \(\left\{{}\begin{matrix}24a+56b=4.96\\a+b=0.14\end{matrix}\right.\)\(\Leftrightarrow\left\{{}\begin{matrix}a=0.09\\b=0.05\end{matrix}\right.\)
\(m_{Mg}=0.09\times24=2.16g\)
\(m_{Fe}=0.05\times56=2.8g\)
\(C\%_{H_2SO_4}=\dfrac{0.14\times98\times100}{200}=6.86\%\)
Câu 3:
\(n_{H_2}=\dfrac{1.568}{22.4}=0.07mol\)
\(Ba+H_2SO_4\rightarrow BaSO_4+H_2\)
a a a a
\(Mg+H_2SO_4\rightarrow MgSO_4+H_2\)
b b b b
Ta có: \(\left\{{}\begin{matrix}137a+24b=3.94\\a+b=0.07\end{matrix}\right.\)\(\Leftrightarrow\left\{{}\begin{matrix}a=0.02\\b=0.05\end{matrix}\right.\)
\(m_{Ba}=0.02\times137=2.74g\)
\(m_{Mg}=0.05\times24=1.2g\)
\(CM_{H_2SO_4}=\dfrac{0.07}{0.1}=0.7M\)
\(\text{Em sửa 7,1 thành 8,1g nha}\\ a/ 2Al+3H_2SO_4 \rightarrow Al_2(SO_4)_3+3H_2\\ b/ \\ n_{Al}=0,3mol\\ n_{H_2SO_4}=\frac{3}{2}n_{Al}=\frac{3}{2}.0,3=0,45mol V_{H_2SO_4}=\frac{0,45}{0,05}=9M\\ c/ \\ V_{H_2}=0,45.22,4=10,08l\)
a)\(n_{Al}=\dfrac{7,1}{27}\approx0,26\left(mol\right)\)
PTHH:\(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
0,26----->0,39-------->0,13------->0,39 (mol)
b)\(V_{H_2SO_4}=0,39\cdot22,4=8,736\left(l\right)\)
c)\(V_{H_2}=0,39\cdot22,4=8,736\left(l\right)\)