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Ta có: \(n_{SO_2}=\dfrac{16,8}{22,4}=0,75\left(mol\right)\)
\(m_{H_2SO_4}=300.78,4\%=235,2\left(g\right)\Rightarrow n_{H_2SO_4}=\dfrac{235,2}{98}=2,4\left(mol\right)\)
PT: \(2Fe+6H_2SO_{4\left(đ\right)}\underrightarrow{t^o}Fe_2\left(SO_4\right)_3+3SO_2+6H_2O\)
____0,5____1,5________0,25______0,75 (mol)
\(\Rightarrow n_{H_2SO_4\left(dư\right)}=2,4-1,5=0,9\left(mol\right)\)
Ta có: m dd sau pư = mFe + m dd H2SO4 - mSO2
= 0,5.56 + 300 - 0,75.64 = 280 (g)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{H_2SO_4\left(dư\right)}=\dfrac{0,9.98}{280}.100\%=31,5\%\\C\%_{Fe_2\left(SO_4\right)_3}=\dfrac{0,25.400}{280}.100\%\approx35,7\%\end{matrix}\right.\)
Bạn tham khảo nhé!
Bài 1:
PTHH: \(Fe+H_2SO_4\rightarrow FeSO_4+H_2\uparrow\)
\(Fe_2O_3+3H_2SO_4\rightarrow Fe_2\left(SO_4\right)_3+3H_2O\)
Ta có: \(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)=n_{Fe}\)
\(\Rightarrow\%m_{Fe}=\dfrac{0,1\cdot56}{37,6}\cdot100\%\approx14,89\%\)
\(\Rightarrow\%m_{Fe_2O_3}=85,11\%\)
Bài 3:
PTHH: \(2HNO_3+Ba\left(OH\right)_2\rightarrow Ba\left(NO_3\right)_2+2H_2O\)
Ta có: \(\left\{{}\begin{matrix}n_{HNO_3}=0,05\cdot1=0,05\left(mol\right)\\n_{Ba\left(OH\right)_2}=\dfrac{342\cdot5\%}{171}=0,1\left(mol\right)\end{matrix}\right.\)
Xét tỉ lệ: \(\dfrac{0,05}{2}< \dfrac{0,1}{1}\) \(\Rightarrow\) Axit p/ứ hết, Bazơ còn dư sau p/ứ
\(\Rightarrow\) Dung dịch sau p/ứ làm quỳ tím hóa xanh
Theo PTHH: \(n_{Ba\left(NO_3\right)_2}=\dfrac{1}{2}n_{HNO_3}=0,025\left(mol\right)\) \(\Rightarrow m_{Ba\left(NO_3\right)_2}=0,025\cdot261=6,525\left(g\right)\)
Bài 1:
\(n_{H_2SO_4}=\dfrac{300.19,6\%}{98}=0,6\left(mol\right);n_{Al}=\dfrac{2,7}{27}=0,1\left(mol\right)\\ PTHH:2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\\ Vì:\dfrac{0,1}{2}< \dfrac{0,6}{3}\Rightarrow H_2SO_4dư\\ n_{Al_2\left(SO_4\right)_3}=\dfrac{3n_{Al}}{2}=\dfrac{3.0,1}{2}=0,15\left(mol\right)\\ a,m_{Al_2\left(SO_4\right)_3}=342.0,15=51,3\left(g\right)\\ b,m_{ddsau}=m_{Al}+m_{ddH_2SO_4}-m_{H_2}=2,7+300-\dfrac{3}{2}.0,1.2=302,4\left(g\right)\\ c,C\%_{ddAl_2\left(SO_4\right)_3}=\dfrac{51,3}{302,4}.100\%\approx16,964\%\\ n_{H_2SO_4\left(dư\right)}=0,6-\dfrac{3}{2}.0,1=0,45\left(mol\right)\\ C\%_{ddH_2SO_4\left(dư\right)}=\dfrac{0,45.98}{302,4}.100\%\approx14,583\%\)
Bài 2:
\(PTHH:2Al+6HCl\rightarrow2AlCl_3+3H_2\\ Mg+2HCl\rightarrow MgCl_2+H_2\\ Đặt:n_{Al}=a\left(mol\right);n_{Mg}=b\left(mol\right)\left(a,b>0\right)\\ Hpt:\left\{{}\begin{matrix}27a+24b=7,8\\1,5a+b=\dfrac{8,96}{22,4}=0,4\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,2\\b=0,1\end{matrix}\right.\\ \%m_{Al}=\dfrac{0,2.27}{7,8}.100\%\approx69,231\%\Rightarrow\%m_{Mg}\approx100\%-69,231\%\approx30,769\%\)
\(n_{FeO}=\dfrac{7,2}{72}=0,1mol\)
\(FeO+H_2SO_4\rightarrow FeSO_4+H_2O\)
0,1 0,1 0,1
\(m_{H_2SO_4}=0,1\cdot98=9,8g\)
\(m_{ddH_2SO_4}=\dfrac{9,8}{24,5\%}\cdot100\%=40g\)
\(m_{FeSO_4}=0,1\cdot152=15,2g\)
\(m_{ddsau}=7,2+40=47,2g\)
\(n_{FeSO_4.7H_2O}=a\left(mol\right)\Rightarrow m=278a\left(g\right)\)
\(m_{FeSO_4còn}=15,2-152a\left(g\right)\)
Dung dịch sau khi làm lạnh có khối lượng:
\(m_{ddsaull}=47,2-278a\left(g\right)\)
\(\Rightarrow C\%=\dfrac{15,2-152a}{47,2-278a}\cdot100\%=13,6\%\Rightarrow a=0,08mol\)
\(\Rightarrow m=278a=278\cdot0,08=22,24g\)
\(n_{Al_2O_3}=\dfrac{10,2}{102}=0,1(mol)\\ Al_2O_3+3H_2SO_4\to Al_2(SO_4)_3+3H_2O\\ \Rightarrow n_{H_2SO_4}=0,3(mol)n_{Al_2(SO_4)_3}=0,1(mol)\\ \Rightarrow C\%_{H_2SO_4}=\dfrac{0,3.98}{300}.100\%=9,8\%\\ \Rightarrow C\%_{Al_2(SO_4)_3}=\dfrac{0,1.342}{10,2+300}.100\%=11,03\%\)
mH2SO4= 147*10%/100%=14.7g
nH2SO4= 1.47/98=0.15 mol
nBaSO4 = 46.6/233=0.2 mol
BaCl2 + H2SO4 --> BaSO4 + 2HCl
_________0.15------>0.15
nBaSO4(còn lại)= 0.2-0.15=0.05 mol
Na2SO4 + BaCl2 --> BaSO4 + 2NaCl
0.05<--------------------0.05
mNa2SO4= 0.05*142=7.1g
mX=mNa2SO4 + mddH2SO4=7,1+147=154,1(g)
=>C%Na2SO4=(7,1*100%)/154,1= 4,61%
Bạn sửa đề hộ mình là 147g dd nhé
mH2SO4= 147*10/100=14.7g
nH2SO4= 1.47/98=0.15 mol
nBaSO4 = 46.6/233=0.2 mol
BaCl2 + H2SO4 --> BaSO4 + 2HCl
_________0.15_____0.15
nBaSO4(cl)= 0.2-0.15=0.05 mol
Na2SO4 + BaCl2 --> BaSO4 + 2NaCl
0.05________________0.05
mNa2SO4= 0.05*142=7.1g
C%Na2SO4 = 7.1/147*100%= 4.83%
$m_{dd\ sau\ pư} = 2,4 + 300 = 302,4(gam)$
$Fe_2O_3 + 3H_2SO_4 \to Fe_2(SO_4)_3 + 3H_2O$
$n_{Fe_2(SO_4)_3} = n_{Fe_2O_3} = \dfrac{2,4}{160} = 0,015(mol)$
$C\%_{Fe_2(SO_4)_3} = \dfrac{0,015.400}{302,4}.100\% = 1,98\%$
Hi em mddFe2(SO4)3= mFe2O3+ mddH2SO4=302,4(g) chứ em!