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a, \(Ba+2H_2O\rightarrow Ba\left(OH\right)_2+H_2\)
\(BaO+H_2O\rightarrow Ba\left(OH\right)_2\)
Ba(OH)2: bari hydroxit
H2: hydro
b, Ta có: \(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
Theo PT: \(n_{Ba}=n_{H_2}=0,2\left(mol\right)\Rightarrow m_{Ba}=0,2.137=27,4\left(g\right)\)
\(\Rightarrow m_{BaO}=42,7-27,4=15,3\left(g\right)\)
\(n_{H_2}=\dfrac{2,479}{24,79}=0,1\left(mol\right)\)
PTHH:
2K + 2H2O ---> 2KOH + H2
0,2<---------------0,2<----0,1
=> \(\left\{{}\begin{matrix}m_K=0,2.39=7,8\left(g\right)\\m_{K_2O}=12,5-7,8=4,7\left(g\right)\end{matrix}\right.\)
\(n_{K_2O}=\dfrac{4,7}{94}=0,05\left(mol\right)\)
PTHH: K2O + H2O ---> 2KOH
0,05-------------->0,1
=> mKOH = (0,2 + 0,1).56 = 16,8 (g)
\(a,n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\\ PTHH:2K+2H_2O\rightarrow2KOH+H_2\uparrow\\ Theo.pt:n_K=2n_{H_2}=2.0,1=0,2\left(mol\right)\\ m_K=0,2.39=7,8\left(g\right)\\ m_{K_2O}=17,2-7,8=9,4\left(g\right)\\ b,n_{CuO\left(bđ\right)}=\dfrac{12}{80}=0,15\left(mol\right)\\ PTHH:CuO+H_2\underrightarrow{t^o}Cu+H_2O\\ LTL:0,15>0,1\Rightarrow Cu.dư\)
Gọi nCuO (pư) = a (mol)
=> nCu = a (mol)
mchất rắn sau pư = 80(0,15 - a) + 64a = 10,8
=> a = 0,075 (mol)
=> nH2 (pư) = 0,075 (mol)
\(H=\dfrac{0,075}{0,1}=75\%\)
\(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
PT: \(2K+2H_2O\rightarrow2KOH+H_2\)
\(K_2O+H_2O\rightarrow2KOH\)
Theo PT: \(n_K=2n_{H_2}=0,2\left(mol\right)\Rightarrow m_K=0,2.39=7,8\left(g\right)\)
\(\Rightarrow m_{K_2O}=12,4-7,8=4,6\left(g\right)\)
Bảo toàn e :
nO2 = 2 .nH2 = 2 . 2,24 /22,4 = 0,2 (mol)
=> khối lượng oxit = 14,51+ 0,2 . 32 = 20,91 (g)
PT: \(2K+2H_2O\rightarrow2KOH+H_2\)
\(Ba+2H_2O\rightarrow Ba\left(OH\right)_2+H_2\)
\(4K+O_2\underrightarrow{t^o}2K_2O\)
\(2Ba+O_2\underrightarrow{t^o}2BaO\)
Giả sử: \(\left\{{}\begin{matrix}n_K=x\left(mol\right)\\n_{Ba}=y\left(mol\right)\end{matrix}\right.\)
Theo PT: \(\Sigma n_{H_2}=\dfrac{1}{2}n_K+n_{Ba}=\dfrac{1}{2}x+y\left(mol\right)\)
Mà: \(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
\(\Rightarrow\dfrac{1}{2}x+y=0,1\Rightarrow\dfrac{1}{4}x+\dfrac{1}{2}y=0,05\left(1\right)\)
Theo PT: \(\Sigma n_{O_2}=\dfrac{1}{4}n_K+\dfrac{1}{2}n_{Ba}=\dfrac{1}{4}x+\dfrac{1}{2}y\left(mol\right)\)
\(\Rightarrow\Sigma n_{O_2}=0,05\left(mol\right)\)
Theo ĐLBT KL: \(a=m_{oxit}=m_X+m_{O_2}=14,51+0,05.32=16,11\left(g\right)\)
Bạn tham khảo nhé!
\(2Na+2H_2O\rightarrow2NaOH+H_2\\ Na_2O+H_2O\rightarrow2NaOH\\ n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\\ n_{Na}=2.0,3=0,6\left(mol\right)\\ a,m_{Na}=0,6.23=13,8\left(g\right)\\ m_{Na_2O}=26,2-13,8=12,4\left(g\right)\\b, n_{Na_2O}=\dfrac{12,4}{62}=0,2\left(mol\right)\\ n_{NaOH\left(tổng\right)}=n_{Na}+2.n_{Na_2O}=0,6+\dfrac{12,4}{62}=0,8\left(mol\right)\\ m_{c.tan}=m_{NaOH}=0,8.40=32\left(g\right)\\ c,m_{ddNaOH}=m_{hh}+m_{H_2O}-m_{H_2}=26,2+200-0,3.2=225,6\left(g\right)\\ C\%_{ddNaOH}=\dfrac{32}{225,6}.100\approx14,185\%\)
\(n_{KOH}=a\left(mol\right)\)
\(n_{H_2}=\dfrac{0.672}{22.4}=0.03\left(mol\right)\)
\(n_{H_2O}=\dfrac{1}{2}n_{KOH}+n_{Ca\left(OH\right)_2}+2n_{H_2}=0.5a+0.01+2\cdot0.03=0.5a+0.07\left(mol\right)\)
\(BTKL:\)
\(m_X+m_{H_2O}=m_{Ca\left(OH\right)_2}+m_{KOH}+m_{H_2}\)
\(\Rightarrow2.43+\left(0.5a+0.07\right)\cdot18=0.01\cdot74+56a+0.03\cdot2\)
\(\Rightarrow a=0.06\)
\(m_{KOH}=0.06\cdot56=3.36\left(g\right)\)
`2K+2H_2O->2KOH+H_2` (sp: Kali hidroxit, Hidro)
0,2---------------------------0,1 mol
`K_2O+H_2O->2KOH`
`n_(H_2)=((2,24)/(22,4))=0,1 mol`
`->m_(K)=0,2.39=7,8g`
`->m_(K_2O)=17,2-7,8=9,4g`