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CH3COOH + NaOH $\to$ CH3COONa + H2O
n CH3COOH = n NaOH = 0,05(mol)
=> n C2H5OH = (7,6 - 0,05.60)/46 = 0,1(mol)
\(CH_3COOH + C_2H_5OH \buildrel{{H_2SO_4,t^o}}\over\rightleftharpoons CH_3COOC_2H_5 + H_2O\)
n CH3COOH = 0,05 < n C2H5OH = 0,1 nên hiệu suất tính theo số mol CH3COOH
n CH3COOC2H5 = n CH3COOH pư = 0,05.60% = 0,03 mol
=> m este = 0,03.88 = 2,64 gam
\(n_{CH_3COOC_2H_5}=\dfrac{4,4}{88}=0,05\left(mol\right)\)
PTHH: CH3COOH + C2H5OH --H2SO4(đ),to--> CH3COOC2H5 + H2O
0,05<--------------------------------------0,05
=> \(m_{CH_3COOH\left(lý.thuyết\right)}=0,05.60=3\left(g\right)\)
=> \(m_{CH_3COOH\left(tt\right)}=\dfrac{3.100}{60}=5\left(g\right)\)
a, PT: \(CH_3COOH+C_2H_5OH\underrightarrow{_{H_2SO_{4\left(đ\right)}}}CH_3COOC_2H_5+H_2O\)
b, Ta có: \(n_{CH_3COOH}=\dfrac{30}{60}=0,5\left(mol\right)\)
\(n_{C_2H_5OH}=\dfrac{27,6}{46}=0,6\left(mol\right)\)
Xét tỉ lệ: \(\dfrac{0,5}{1}< \dfrac{0,6}{1}\), ta được C2H5OH.
Theo PT: \(n_{CH_3COOC_2H_5\left(LT\right)}=n_{CH_3COOH}=0,5\left(mol\right)\)
\(\Rightarrow m_{CH_3COOC_2H_5\left(LT\right)}=0,5.88=44\left(g\right)\)
Mà: m CH3COOC2H5 (TT) = 35,2 (g)
\(\Rightarrow H\%=\dfrac{35,2}{44}.100\%=80\%\)
Bạn tham khảo nhé!
a, Ta có: \(n_{CH_3COOH}=\dfrac{9,6}{60}=0,16\left(mol\right)\)
PT: \(Mg+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Mg+H_2\)
Theo PT: \(n_{\left(CH_3COO\right)_2Mg}=\dfrac{1}{2}n_{CH_3COOH}=0,08\left(mol\right)\)
\(\Rightarrow m_{\left(CH_3COO\right)_2Mg}=0,08.142=11,36\left(g\right)\)
b, PT: \(CH_3COOH+C_2H_5OH\underrightarrow{t^o,xt}CH_3COOC_2H_5+H_2O\)
Theo PT: \(n_{CH_3COOC_2H_5\left(LT\right)}=n_{CH_3COOH}=0,16\left(mol\right)\)
\(\Rightarrow m_{CH_3COOC_2H_5\left(LT\right)}=0,16.88=14,08\left(g\right)\)
Mà: thực tế thu được 10,56 (g)
\(\Rightarrow H\%=\dfrac{10,56}{14,08}.100\%=75\%\)
nC2H5OH = 8.05/46 = 0.175 (mol)
nCH3COOH = 36/60 = 0.6 (mol)
nCH3COOC2H5 = 12.32/88 = 0.14 (mol)
C2H5OH + CH3COOH <-H2SO4đ,t0-> CH3COOC2H5 + H2O
1.......................1
0.175................0.6
LTL : 0.175/1 < 0.6/1
=> CH3COOH dư
mCH3COOH (dư) = ( 0.6 - 0.175) * 60 = 25.5 (g)
nCH3COOC2H5 = nC2H5OH = 0.175 (mol)
H% = 0.14/0.175 * 100% = 80%
