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BTKL: mD + mNaHCO3 = mCO2 + mE
mD + 179,88 = 44.0,2 + 492 => mD = 320,92
BTKL: mMg + mddHCl = mH2 + mD
=> 24 . 0,4 + mddHCl = 2 . 0,4 + 320,92 => mddHCl = 312,12
=> C%HCl = 11,69%
\(n_{Fe_2O_3}=\dfrac{8}{160}=0,05\left(mol\right)\)
PTHH: Fe2O3 + 3H2SO4 --> Fe2(SO4)3 + 3H2O
______0,05------>0,15--------->0,05
=> mH2SO4 = 0,15.98 = 14,7(g)
=> \(C\%\left(H_2SO_4\right)=\dfrac{14,7}{100}.100\%=14,7\%\)
\(C\%\left(Fe_2\left(SO_4\right)_3\right)=\dfrac{0,05.400}{8+100}.100\%=18,52\%\)
PTHH: Fe2(SO4)3 + 6NaOH --> 2Fe(OH)3\(\downarrow\) + 3Na2SO4
________0,05----------------------->0,1
=> mFe(OH)3 = 0,1.107=10,7(g)
a/ A+ HCl
CO3 2- + 2H+ ---> H2O+ CO2
dd B trung hòa bởi NaOH--> trong B có Ba(HCO3)2
CO2 + Ba(OH)2 --> BaCO3 + H2O
0.2<---0.25-0.05-------->0.2
2Co2+ Ba(OH)2--> Ba(HCO3)2
0.1<--------0.05<---------0.05
Ba(HCO3)2+ 2NaOH---> BaCO3+ Na2CO3+ 2H2O
0.05<-------------0.1
--> m2= 0.2*197=39,4g
Na2CO3 va K2CO3 : x,y mol
x+y=0.3
138y=106x*2,604
-->x=0.1,y=0.2
--> m1=0.1*106+ 0,2*138=38,2
b/
C%Na2CO3= (0.1*106*100)/ (61,8+ 38,2)=10,6%
C%K2CO3=(0.2*138*100)/(61,8+ 38,2)=27,6%
a) PTHH: \(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)
Ta có: \(n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)=n_{Fe}=n_{FeCl_2}\) \(\Rightarrow\left\{{}\begin{matrix}C\%_{FeCl_2}=\dfrac{0,15\cdot127}{300}\cdot100\%=6,35\%\\m_{Fe}=0,15\cdot56=8,4\left(g\right)\end{matrix}\right.\)
b) PTHH: \(Cu+2H_2SO_{4\left(đ\right)}\xrightarrow[]{t^o}CuSO_4+SO_2\uparrow+2H_2O\)
Ta có: \(n_{Cu}=\dfrac{13,2-8,4}{64}=0,075\left(mol\right)=n_{SO_2}\) \(\Rightarrow V_{SO_2}=0,075\cdot22,4=1,68\left(l\right)\)
