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a) $2Na + 2H_2O \to 2NaOH + H_2$
b) $n_{Na} = \dfrac{2,3}{23} = 0,1(mol)$
Theo PTHH :
$n_{H_2} = \dfrac{1}{2}n_{Na} = 0,05(mol)$
$V_{H_2} = 0,05.22,4 = 1,12(lít)$
c) $n_{CuO} = \dfrac{2,4}{80} = 0,03(mol)$
$CuO + H_2 \xrightarrow{t^o} Cu + H_2O$
Ta thấy :
$n_{CuO} : 1 < n_{H_2} : 1$ nên $H_2$ dư
$n_{Cu} = n_{CuO} = 0,03(mol)$
$m_{Cu} = 0,03.64 = 1,92(gam)$
a.\(n_{Al}=\dfrac{5,4}{27}=0,2mol\)
\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
0,2 0,2 0,3 ( mol )
\(m_{AlCl_3}=0,2.133,5=26,7g\)
\(V_{H_2}=0,3.22,4=6,72l\)
b.\(n_{CuO}=\dfrac{56}{80}=0,7mol\)
\(CuO+H_2\rightarrow\left(t^o\right)Cu+H_2O\)
0,7 < 0,3 ( mol )
0,3 0,3 0,3 ( mol )
\(m_X=m_{CuO\left(dư\right)}+m_{Cu}=\left[\left(0,7-0,3\right).80\right]+\left(0,3.64\right)=51,2g\)
Áp dụng ĐLBTKL :
mAl + mO2 = mAl2O3
8,1 + 4,032 : 22,4 × 32 = 13,86 (g)
\(n_{O_2} = \dfrac{4,032}{22,4} = 0,18(mol)\\ n_{Al} = \dfrac{8,1}{27} = 0,3(mol)\\ 4Al + 3O_2 \xrightarrow{t^o} 2Al_2O_3\\ \dfrac{n_{Al}}{4} = 0,075 < \dfrac{n_{O_2}}{3} = 0,06\)
Suy ra: Al dư
Bảo toàn khối lượng :
\(m = m_{Al\ dư} + m_{Al_2O_3} = m_{Al\ dư} + m_{Al\ pư} + m_{O_2}=m_{Al\ ban\ đầu} + m_{O_2} = 8,1 + 0,18.32 = 13,86(gam)\)
nAl = 5.4/27 = 0.2 (mol)
2Al + 6HCl => 2AlCl3 + 3H2
0.2.......0.6......................0.3
CM HCl = 0.6 / 0.4 = 1.5 (M)
nCuO = 32/80 = 0.4 (mol)
CuO + H2 -to-> Cu + H2O
0.2.......0.2..........0.2
Chất rắn : 0.2 (mol) CuO dư , 0.2 (mol) Cu
%CuO = 0.2*80 / ( 0.2*80 + 0.2*64) * 100% = 55.56%
%Cu = 44.44%
2KMnO4-to>K2MnO4+MnO2+O2
0,14-------------0,07------0,07-------0,07 mol
n KMnO4=\(\dfrac{22,12}{158}\)=0,14 mol
=>a=mcr=0,07.197+0,07.87=23,82g
=>VO2=0,07.22,4=1,568l
b)
2Cu+O2-to>2CuO
0,07-----0,14
n Cu=\(\dfrac{10,24}{64}\)=0,16 mol
Cu dư :0,01 mol
m chất rắn =0,01.64+0,14.80=11,84g
\(n_{FeO}=\dfrac{3.2}{72}=\dfrac{2}{45}\left(mol\right)\)
\(FeO+H_2\underrightarrow{^{^{t^0}}}Fe+H_2O\)
\(\dfrac{2}{45}....\dfrac{2}{45}....\dfrac{2}{45}\)
\(V_{H_2}=\dfrac{2}{45}\cdot22.4=1\left(l\right)\)
\(Fe+\dfrac{3}{2}Cl_2\underrightarrow{^{t^0}}FeCl_3\)
\(\dfrac{2}{45}.............\dfrac{2}{45}\)
\(m_{FeCl_3}=\dfrac{2}{45}\cdot162.5=7.22\left(g\right)\)
a) \(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\)
PTHH: 2Al + 6HCl --> 2AlCl3 + 3H2
0,2---------------------->0,3
=> VH2 = 0,3.22,4 = 6,72 (l)
b)
\(n_{CuO}=\dfrac{32}{80}=0,4\left(mol\right)\)
PTHH: CuO + H2 --to--> Cu + H2O
Xét tỉ lệ: \(\dfrac{0,4}{1}>\dfrac{0,3}{1}\) => CuO dư, H2 hết
PTHH: CuO + H2 --to--> Cu + H2O
0,3<--0,3------->0,3
=> Rắn sau pư gồm \(\left\{{}\begin{matrix}Cu:0,3\left(mol\right)\\CuO\left(dư\right):0,1\left(mol\right)\end{matrix}\right.\)
\(\left\{{}\begin{matrix}\%m_{Cu}=\dfrac{0,3.64}{0,3.64+0,1.80}.100\%=70,59\%\\\%m_{CuO}=\dfrac{0,1.80}{0,3.64+0,1.80}.100\%=29,41\%\end{matrix}\right.\)