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+PTHH:
(RCOO)3C3H5 + 3NaOH => 3RCOONa + C3H5(OH)3
nNaOH = m/M = 130/40 = 3.25 (mol)
===> nRCOONa = 3.25 (mol)
===> n(RCOO)3C3H5 = 13/12 (mol)
(RCOO)3C3H5 = m/n = \(\frac{964.2}{\frac{13}{12}}\) = 890
===> 3.(R + 44) + 41 = 890
===> R = 239
===> mRCOONa = n.M = 994.5 (g)
PTHH: \(\left(RCOO\right)_3C_3H_5+3NaOH\rightarrow3RCOONa+C_3H_5\left(OH\right)_3\)
Áp dụng ĐLBTKL:
\(m_{hhaxit.béo}=8,58+1,2-0,368=9,412\left(kg\right)\\ \rightarrow m_{xà.phòng}=9,412.\left(100\%-60\%\right)=3,7648\left(kg\right)\)
n CO2=\(\dfrac{6,72}{22,4}\)=0,3 mol
n NaOH=\(2.0,225\)=0,45 mol
T=\(\dfrac{0,3}{0,45}\)=\(\dfrac{2}{3}\)
=>Tạo ra 2 muối NaHCO3 và Na2CO3
2NaOH+CO2->Na2CO3+H2O
0,45-------0,225-------0,225
Na2CO3+H2O+CO2->2NaHCO3
0,075------------0,075--------0,15 mol
=>m NaHCO3=0,15.84=12,6g
=>m Na2CO3= 0,15.106=15,9g
\(n_{NaOH}=0,09.0,5=0,045\left(mol\right)\)
PTHH:
\(\left(RCOO\right)_3C_3H_5+3NaOH\rightarrow3RCOONa+C_3H_5\left(OH\right)_3\)
0,015<-------------0,045------------>0,045
\(\rightarrow M_{\left(RCOO\right)_3C_3H_5}=\dfrac{13,35}{0,015}=890\left(\dfrac{g}{mol}\right)\\ \rightarrow M_R=239\\ \rightarrow R:-C_{17}H_{35}\)
\(\rightarrow m_{xà.phòng}=786.0,045=35,37\left(g\right)\)
CTCT: (C17H35COO)3C3H5
a) \(n_{CO_2}=\dfrac{13,44}{22,4}=0,6\left(mol\right)\)
\(n_{NaOH}=2.0,2=0,4\left(mol\right)\)
Xét tỉ lệ \(\dfrac{n_{NaOH}}{n_{CO_2}}=\dfrac{0,4}{0,6}=0,67\) => Tạo ra muối NaHCO3
b)
PTHH: NaOH + CO2 --> NaHCO3
0,4------------->0,4
=> \(m_{NaHCO_3}=0,4.84=33,6\left(g\right)\)
Đáp án A
PTHH tổng quát:
R C O O 3 C 3 H 5 + 3 N a O H → t 0 3 R C O O N a + C 3 H 5 O H 3
\(m_{CH_3COOH}=\dfrac{80.9}{100}=7,2\left(g\right)\)
\(n_{CH_3COOH}=\dfrac{7,2}{60}=0,12\left(mol\right)\)
PTHH :
\(15CH_3COOH+10NaHCO_3\rightarrow10CH_3COONa+2H_2O+20CO_2\uparrow\)
0,12 0,08 0,08 0,016 0,16
\(a,m_{NaHCO_3}=84.0,08=6,72\left(g\right)\)
\(m_{ddNaHCO_3}=\dfrac{6,72.100}{4,2}=160\left(g\right)\)
\(b,m_{CH_3COONa}=0,08.82=6,56\left(g\right)\)
\(m_{H_2O}=0,016.18=0,288\left(g\right)\)
\(m_{CO_2}=0,16.44=7,04\left(g\right)\)
\(m_{ddCH_3COONa}=80+160-0,288-7,04=232,672\left(g\right)\)
\(C\%=\dfrac{6,56}{232,672}\approx2,82\%\)
