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a, \(FeCl_3+3NaOH\rightarrow3NaCl+Fe\left(OH\right)_3\)
\(2Fe\left(OH\right)_3\underrightarrow{t^o}Fe_2O_3+3H_2O\)
b, \(n_{FeCl_3}=0,4.2=0,8\left(mol\right)\)
Theo PT: \(n_{NaCl}=3n_{FeCl_3}=2,4\left(mol\right)\)
\(\Rightarrow C_{M_{NaCl}}=\dfrac{2,4}{0,4+0,2}=4\left(M\right)\)
c, \(n_{Fe_2O_3}=\dfrac{1}{2}n_{Fe\left(OH\right)_3}=\dfrac{1}{2}n_{FeCl_3}=0,4\left(mol\right)\)
\(\Rightarrow m_{Fe_2O_3}=0,4.160=64\left(g\right)\)
\(n_{FeCl3}=2.0,4=0,8\left(mol\right)\)
PTHH : \(FeCl_3+3NaOH\rightarrow Fe\left(OH\right)_3+3NaCl\)
0,8----------------------->0,8----------->2,4
b) \(C_{MNaCl}=\dfrac{2,4}{0,4+0,2}=4M\)
c) \(2Fe\left(OH\right)_3\xrightarrow[]{t^o}Fe_2O_3+3H_2O\)
0,8--------------->0,4
\(\Rightarrow a=m_{Fe2O3}=0,4.160=64\left(g\right)\)
\(a,PTHH:3NaOH+FeCl_3\rightarrow3NaCl+Fe\left(OH\right)_3\downarrow\\ 2Fe\left(OH\right)_3\rightarrow^{t^o}Fe_2O_3+3H_2O\uparrow\\ b,n_{FeCl_3}=1,5\cdot0,2=0,3\left(mol\right)\\ \Rightarrow n_{NaOH}=3n_{FeCl_3}=0,9\left(mol\right)\\ \Rightarrow V_{dd_{NaOH}}=\dfrac{0,9}{2}=0,45\left(l\right)\)
Theo đề: \(\left\{{}\begin{matrix}X:Fe\left(OH\right)_3\\A:NaCl\\Y:Fe_2O_3\end{matrix}\right.\)
Theo PT: \(n_{NaCl}=3n_{FeCl_3}=0,9\left(mol\right)\)
\(\Rightarrow C_{M_{NaCl}}=\dfrac{0,9}{0,45+0,2}\approx1,4M\)
\(c,\) Theo PT: \(n_{Fe\left(OH\right)_3}=n_{FeCl_3}=0,3\left(mol\right);n_{Fe_2O_3}=\dfrac{1}{2}n_{Fe\left(OH\right)_3}=0,15\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}m_X=m_{Fe\left(OH\right)_3}=0,3\cdot107=32,1\left(g\right)\\m_Y=m_{Fe_2O_3}=0,15\cdot160=24\left(g\right)\end{matrix}\right.\)
\(n_{CuCl_2}=2.0,2=0,4(mol)\\ n_{NaOH}=2.0,2=0,4(mol)\\ a,CuCl_2+2NaOH\to Cu(OH)_2+2NaCl\\ Cu(OH)_2\xrightarrow{t^o}CuO+H_2O\\ b,\dfrac{n_{CuCl_2}}{1}>\dfrac{n_{NaOH}}{2}\Rightarrow CuCl_2\text{ dư}\\ \Rightarrow n_{CuO}=0,2(mol)\\ \Rightarrow m_{CuO}=0,2.80=16(g)\\ c,n_{CuCl_2(dư)}=0,4-0,2=0,2(mol)\\n_{NaCl}=0,2(mol)\\ \Rightarrow m_{CuCl_2(dư)}=0,2.135=27(g)\\ m_{NaCl}=0,2.58,5=11,7(g)\)
a) \(n_{NaOH}=\dfrac{20}{40}=0,5\left(mol\right)\)
\(CuCl_2+2NaOH\rightarrow Cu\left(OH\right)_2+2NaCl\)
Lập tỉ lệ : \(\dfrac{0,2}{1}< \dfrac{0,5}{2}\)=> Sau phản ứng NaOH dư
\(n_{Cu\left(OH\right)_2}=n_{CuCl_2}=0,2\left(mol\right)\)
Dung dịch nước lọc gồm NaCl (0,4_mol); NaOH dư ( 0,1 mol)
\(Cu\left(OH\right)_2-^{t^o}\rightarrow CuO+H_2O\)
\(n_{CuO}=n_{Cu\left(OH\right)_2}=0,2\left(mol\right)\)
\(a=m_{CuO}=0,2.80=16\left(g\right)\)
b) \(m_{NaCl}=0,4.58,5=23,4\left(g\right);m_{NaOH}=0,1.40=4\left(g\right)\)
a.CuCl2 + 2NaOH -> Cu(OH)2 + 2NaCl
0.15 0.3 0.15 0.3
Cu(OH)2 -> CuO + H2O
0.15 0.15
nNaOH = 0.3 mol
\(CM_{CuCl2}=\dfrac{0.15}{2}=0.075M\)
b.Vdd sau phản ứng = 0.2 + 0.15 = 0.35l
\(CM_{NaCl}=\dfrac{0.3}{0.35}=0.86M\)
c.mCuO = \(0.15\times80=12g\)
a) PHTT : Fe +CuSO4 -> FeSO4+Cu
Cu+ HCl -> k phản ứng
khố lượng chất rắn cần tính sau phản ứng là Cu
nCuSO4 =0,2 .1= 0,2 (mol)
theo pt : nCu=nCuSO4 =0,2 mol
=> mCu =0,2 .64 =12,8(g)
b) PTHH : FeSO4 + 2NaOH -> Fe(OH)2 + Na2SO4
Theo phần a) ta có : nFeSO4=nCuSO4=0,2 mol
theo pt :nNaOH= 2nFeSO4 = 0,2.2=0,4 (mol)
=> VddNaOH= 0,4/1=0,4 l
c)
PTHH: 4Fe(OH)2 +O2 +2H2O -> 4Fe(OH)3
Theo phần b ta có:
nFe(OH)2=nFeSO4= 0,2 mol
theo pt : nFe(OH)3=nFe(OH)2 = 0,2 (mol)
=> mFe(OH)3 = 0,2 .(56+(16+1).3)=21,4 (g)
a, PT: \(Mg+2HCl\rightarrow MgCl_2+H_2\)
\(MgCl_2+2NaOH\rightarrow2NaCl+Mg\left(OH\right)_{2\downarrow}\)
\(Mg\left(OH\right)_2\underrightarrow{t^o}MgO+H_2O\)
b, Ta có: \(n_{Mg}=\dfrac{9,6}{24}=0,4\left(mol\right)\)
Theo PT: \(n_{HCl}=2n_{Mg}=0,8\left(mol\right)\)
\(\Rightarrow C_{M_{HCl}}=\dfrac{0,8}{0,2}=4\left(M\right)\)
c, Theo PT: \(n_{MgO}=n_{Mg}=0,4\left(mol\right)\)
\(\Rightarrow m_{MgO}=0,4.40=16\left(g\right)\)
\(n_{CuCl_2}=0,075mol\)
\(n_{NaOH}=0,05.2=0,1mol\)
CuCl2+2NaOH\(\rightarrow\)Cu(OH)2\(\downarrow\)+2NaCl
-Tỉ lệ: \(\dfrac{0,075}{1}>\dfrac{0,1}{2}\)suy ra CuCl2 dư
CuCl2+2NaOH\(\rightarrow\)Cu(OH)2\(\downarrow\)+2NaCl
0,05..\(\leftarrow\)0,1\(\rightarrow\).......0,05\(\rightarrow\)........0,1
a=\(m_{Cu\left(OH\right)_2}=0,05.98=4,9gam\)
\(n_{NaCl}=0,1mol\)
\(n_{CuCl_2\left(dư\right)}=0,075-0,05=0,025mol\)
\(V_{dd}=0,075+0,05=0,125l\)
\(C_{M_{NaCl}}=\dfrac{0,1}{0,125}=0,8M\)
\(C_{M_{CuCl_2}}=\dfrac{0,025}{0,125}=0,2M\)
theo đề bài ta có : \(\left\{{}\begin{matrix}nCuCl2=0,075.1=0,075\left(mol\right)\\nNaOH=0,05.2=0,1\left(mol\right)\end{matrix}\right.\)
PTHH :
\(CuCl2+2NaOH->Cu\left(OH\right)2\downarrow+2NaCl\)
0,05mol.........0,1mol...........0,05mol............0,1mol
Theo pthh ta có : \(nCuCl2=\dfrac{0,075}{1}mol>nNaOH=\dfrac{0,1}{2}mol=>nCuCl2\left(d\text{ư}\right)\) ( tính theo nNaOH)
a) PTHH :
\(Cu\left(OH\right)2-^{t0}->CuO+H2O\)
0,05mol........................0,05mol
=> a = mCuO = 0,05.80 = 4 (g)
b) Ta có :
\(\left\{{}\begin{matrix}CM_{NaCl}=\dfrac{0,1}{0,075+0,05}=0,8\left(M\right)\\CM_{CuCl2\left(d\text{ư}\right)}=\dfrac{0,075-0,05}{0,075+0,05}=0,2\left(M\right)\end{matrix}\right.\)
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