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![](https://rs.olm.vn/images/avt/0.png?1311)
a, \(n_{HCl}=0,2.0,1=0,02\left(mol\right)=n_{H^+}=n_{Cl^-}\)
\(n_{H_2SO_4}=0,2.0,15=0,03\left(mol\right)=n_{SO_4^{2-}}\) \(\Rightarrow n_{H^+}=2n_{H_2SO_4}=0,06\left(mol\right)\)
\(\Rightarrow\Sigma n_{H^+}=0,02+0,06=0,08\left(mol\right)\)
\(n_{Ba\left(OH\right)_2}=0,3.0,05=0,015\left(mol\right)=n_{Ba^{2+}}\)
\(\Rightarrow n_{OH^-}=2n_{Ba\left(OH\right)_2}=0,03\left(mol\right)\)
\(H^++OH^-\rightarrow H_2O\)
0,03___0,03 (mol) ⇒ nH+ dư = 0,05 (mol)
\(Ba^{2+}+SO_4^{2-}\rightarrow BaSO_4\)
0,015___0,015______0,015 (mol) ⇒ nSO42- dư = 0,015 (mol)
⇒ m = mBaSO4 = 0,015.233 = 3,495 (g)
\(\left[Cl^-\right]=\dfrac{0,02}{0,2+0,3}=0,04\left(M\right)\)
\(\left[H^+\right]=\dfrac{0,05}{0,2+0,3}=0,1\left(M\right)\)
\(\left[SO_4^{2-}\right]=\dfrac{0,015}{0,2+0,3}=0,03\left(M\right)\)
b, pH = -log[H+] = 1
![](https://rs.olm.vn/images/avt/0.png?1311)
\(n_{HCl}=0,1.0,1=0,01\left(mol\right);n_{HCl}=0,3.0,04=0,012\left(mol\right)\)
Dung dịch gồm H+ và Cl-
\(n_{H^+}=0,01+0,012=0,022\left(mol\right)\)
=> \(\left[H^+\right]=\dfrac{0,022}{0,4}=0,055M\)
\(n_{Cl^-}=0,01+0,012=0,022\left(mol\right)\)
=>\(\left[Cl^-\right]=\dfrac{0,022}{0,4}=0,055M\)
Trộn 100ml dung dịch HNO3 0.1M với 400ml dung dịch H2SO4 0.03M
\(n_{HNO_3}=0,1.0,1=0,01\left(mol\right);n_{H_2SO_4}=0,04.0,3=0,012\left(mol\right)\)
Dung dịch sau khi trộn gồm :
\(n_{H^+}=0,01+0,012.2=0,034\left(mol\right)\)
=> \(\left[H^+\right]=\dfrac{0,034}{0,5}=0,068M\)
\(n_{NO_3^-}=0,01\left(mol\right)\)
=>\(\left[NO_3^-\right]=\dfrac{0,01}{0,5}=0,02M\)
\(n_{SO_4^{2-}}=0,012\left(mol\right)\)
=> \(\left[SO_4^{2-}\right]=\dfrac{0,012}{0,5}=0,024M\)
![](https://rs.olm.vn/images/avt/0.png?1311)
Cả 2 đều 0,1M?
\(n_{Na^+}=0,1.0,1+2.0,1.0,1=0,03\left(mol\right)\)
\(\Rightarrow\left[Na^+\right]=\dfrac{0,03}{0,1}=0,3M\)
\(n_{Cl^-}=0,1.0,1=0,01\left(mol\right)\Rightarrow\left[Cl^-\right]=0,1M\)
\(n_{SO_4^{2-}}=0,1.0,1=0,01\left(mol\right)\Rightarrow\left[SO_4^{2-}\right]=0,1M\)
![](https://rs.olm.vn/images/avt/0.png?1311)
a) Ta có: \(n_{Al\left(NO_3\right)_3}=\dfrac{4,26}{213}=0,02\left(mol\right)\) \(\Rightarrow\left\{{}\begin{matrix}n_{Al^+}=0,02\left(mol\right)\\n_{NO_3^-}=0,06\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\left[Al^+\right]=\dfrac{0,02}{0,1}=0,2\left(M\right)\\\left[NO_3^-\right]=\dfrac{0,06}{0,1}=0,6\left(M\right)\end{matrix}\right.\)
b) Ta có: \(\left[Na^+\right]=0,1+0,02\cdot2+0,3=0,304\left(M\right)\)
c) Bạn xem lại đề !!
![](https://rs.olm.vn/images/avt/0.png?1311)
\(n_{HCl}=Cm.V=1.0,1=1mol\)
\(n_{H_2SO_4}=Cm.V=0,5.0,1=0,05mol\)
Thể thích của dd D là 200ml = 0,2l
\([H^+]=\frac{n_{HCl}+2.n_{H_2SO_4}}{V}=\frac{0,1+0,1}{0,2}=1M\)
\([Cl^-]=\frac{n_{HCl}}{V}=\frac{0,1}{0,2}=0,5M\)
\([SO_4^{2-}]=\frac{n_{H_2SO_4}}{V}=\frac{0,05}{0,2}=0,25M\)
Khi cho dd D vào \(Ba\left(OH\right)_2\) chỉ có \(H_2SO_4\) tác dụng, tạo kết tủa
\(H_2SO_4+Ba\left(OH\right)_2\rightarrow BaSO_4+2H_2O\)
\(0,05....\rightarrow0,05mol\)
\(\rightarrow m_{BaSO_4}=n.M=0,05.233=11,65g\)
\(n_{H^+}=0,1.2.0,2=0,04\Rightarrow\left[H^+\right]=\dfrac{0,04}{0,2+0,1}\approx0,13M\)
\(n_{SO_4^{2-}}=0,2.0,1+0,3.0,1=0,05\Rightarrow\left[SO_4^{2-}\right]=\dfrac{0,05}{0,2+0,1}\approx0,17M\)
\(n_{Na^+}=0,3.0,1.2=0,06\Rightarrow\left[Na^+\right]=\dfrac{0,06}{0,2+0,1}\approx0,2M\)