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nCaCl2=0.02(mol)
nAgNO3=0.01(mol)
CaCl2+2AgNO3->Ca(NO3)2+2AgCl
Theo pthh nAgNO3=2nCaCl2
Theo bài ra nAgNO3=0.5 nCaCl2
->CaCl2 dư tính theo AgNO3
nAgCl=nAgNO3->nAgCl2=0.01(mol)
mAgCl2=1.435(g)
nCaCl2 phản ứng:0.005(mol)
nCaCl2 dư=0.02-0.005=0.015(mol)->CM=0.015:(0.03+0.07)=0.15M
nCa(NO3)2=0.005(mol)->CM=0.005:(0.03+0.07)=0.05M
\(n_{BaCl_2}=\dfrac{208.15\%}{208}=0,15\left(mol\right)\\ n_{H_2SO_4}=\dfrac{150.19,6\%}{98}=0,3\left(mol\right)\\ BaCl_2+H_2SO_4\rightarrow BaSO_4\downarrow+2HCl\\ Vì:\dfrac{0,15}{1}< \dfrac{0,3}{1}\Rightarrow H_2SO_4dư\\ n_{H_2SO_4\left(p.ứ\right)}=n_{BaSO_4}=n_{BaCl_2}=0,15\left(mol\right)\\ n_{HCl}=2.0,15=0,3\left(mol\right)\\ n_{H_2SO_4\left(dư\right)}=0,13-0,15=0,15\left(mol\right)\\ m_{HCl}=0,3.36,5=10,95\left(g\right)\\ m_{BaSO_4}=233.0,15=34,95\left(g\right)\\ m_{H_2SO_4\left(dư\right)}=0,15.98=14,7\left(g\right)\\ m_{ddsau}=208+150-34,95=323,05\left(g\right)\\ C\%_{ddHCl}=\dfrac{10,95}{323,05}.100\approx3,39\%\)
\(C\%_{ddH_2SO_4\left(dư\right)}=\dfrac{14,7}{323,05}.100\approx4,55\%\)
a)
$CuCl_2 + 2NaOH \to Cu(OH)_2 + 2NaCl$
$Cu(OH)_2 \xrightarrow{t^o} CuO + H_2O$
b)
$n_{CuCl_2} = 0,01(mol) ; n_{NaOH} = 0,01(mol)$
Ta thấy :
$n_{CuCl_2} : 1 > n_{NaOH} : 2$ nên $CuCl_2$ dư
$n_{CuO} = n_{Cu(OH)_2} = \dfrac{1}{2}n_{NaOH} = 0,005(mol)$
$m_{CuO} = 0,005.80 = 0,4(gam)$
c) $V_{dd} = 0,04 + 0,06 = 0,1(lít)$
$n_{CuCl_2\ dư} = 0,01 - 0,005 = 0,005(mol)$
$n_{NaCl} = n_{NaOH} = 0,01(mol)$
$C_{M_{CuCl_2}} = \dfrac{0,005}{0,1} = 0,05M$
$C_{M_{NaCl}} = \dfrac{0,01}{0,1} = 0,1M$
a,\(m_{BaCl_2}=208.15\%=31,2\left(g\right)\Rightarrow n_{BaCl_2}=\dfrac{31,2}{208}=0,15\left(mol\right)\)
\(m_{H_2SO_4}=150.19,6\%=29,4\left(g\right)\Rightarrow n_{H_2SO_4}=\dfrac{29,4}{98}=0,3\left(mol\right)\)
PTHH: BaCl2 + H2SO4 → BaSO4 + 2HCl
Mol: 0,15 0,15 0,15 0,3
Ta có: \(\dfrac{0,15}{1}< \dfrac{0,3}{1}\) ⇒ BaCl2 hết, H2SO4 dư
\(m_{H_2SO_4dư}=\left(0,3-0,15\right).98=14,7\left(g\right)\)
b, \(m_{BaSO_4}=0,15.233=34,95\left(g\right)\)
\(m_{HCl}=0,3.36,5=10,95\left(g\right)\)
\(n_{CuCl_2}=\dfrac{1,35}{135}=0,01(mol)\\ n_{KOH}=\dfrac{28.10}{100.56}=0,05(mol)\\ a,CuCl_2+2KOH\to Cu(OH)_2\downarrow+2KCl\\ Cu(OH)_2\xrightarrow{t^o}CuO+H_2O\\ \dfrac{n_{CuCl_2}}{1}<\dfrac{n_{KOH}}{2}\Rightarrow KOH\text{ dư}\\ b,n_{CuO}=n_{Cu(OH)_2}=0,01(mol)\\ \Rightarrow m_{CuO}=0,01.80=0,8(g)\)
\(c,n_{KCl}=0,02(mol);n_{KOH(dư)}=0,05-0,01.2=0,03(mol)\\ \Rightarrow m_{Cu(OH)_2}=0,01.98=0,98(g);m_{KCl}=0,02.74,9=1,49(g)\\ \Rightarrow \begin{cases} C\%_{KCl}=\dfrac{1,49}{1,35+28-0,98}.100\%=5,25\%\\ C\%_{KOH(dư)}=\dfrac{0,03.56}{1,35+28-0,98}.100=5,92\% \end{cases}\)
nnacl= 0,03
nagno3= 0,02
agno3+ nacl-> nano3+ agcl
thấy 0,03> 0,02
=> sau pư, nnacl dư= 0,03-0,02= 0,01 mol
mnano3= 0,02* 85= 1,7g
magcl= 0,02*143,5= 2,87g
mnacl dư= 0,01*58,5= 5,85g
mdd sau pư= 10+17=27g
c% nacl dư= 5,85/27*100= 21,67%
c% nano3= 1,7/27*100=6,3%
c%agcl= 2,87/27*100= 10,62%