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\(n_{CuSO_4.5H_2O}=n_{CuSO_4}=\dfrac{12,5}{250}=0,05mol\)
\(\Rightarrow C_{MddCuSO_4}=\dfrac{0,05}{0,0875}\approx0,57M\)
Đổi:87,5 ml=0,0875 l
nCuSO4=12,5/250=0,05(mol)
=>CM=0,05/0,0875=0,57 M.
\(a,C\%_A=\dfrac{12,5}{12,5+87,5}.100\%=12,5\%\)
\(b,PTHH:\)
\(CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2\downarrow+Na_2SO_4\)
trc p/u : 0,05 0,15
p/u : 0,05 0,1 0,05 0,05
sau: 0 0,05 0,05 0,05 (mol)
-> sau p/ư NaOH dư .
\(n_{NaOH}=\dfrac{40.15\%}{40}=0,15\left(mol\right)\)
\(n_{CuSO_4}=\dfrac{12,5}{250}=0,05\left(mol\right)\)
\(m_{Cu\left(OH\right)_2}=0,05.98=4,9\left(g\right)\)
\(m_{ddB}=100+40=140\left(g\right)\)
\(C\%_B=\dfrac{4,9}{140}.100\%=3,5\%\)
\(n_{CO_2}=\dfrac{V}{22,4}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\\ n_{NaOH}=\dfrac{m}{M}=\dfrac{m_{dd}.C\%}{M}=\dfrac{200.16\%}{40}=0,8\left(mol\right)\)
Có: \(\dfrac{n_{NaOH}}{n_{CO_2}}=4\)
=> Phản ứng tạo muối Na2CO3
PT:
\(CO_2+2NaOH\rightarrow Na_2CO_3+H_2O\)
0,2. 0,4 0,2
=> dd sau phản ứng có những chất tan là:
\(\left\{{}\begin{matrix}Na_2CO_3:0,2\left(mol\right)\\NaOH:0,4\left(mol\right)\end{matrix}\right.\)
mdd spu=0,2.44+200=208,8(g)
\(\%m_{NaOH}=\dfrac{0,4.40}{208,8}.100\%=7,66\%\\\%m_{Na_2CO_3}=\dfrac{0,2.106}{208,8}.100\%=10,15\% \)
Câu 1:
nAl= 0,1(mol)
PTHH: 2Al + 6 HCl -> 2 AlCl3 + 3 H2
nAlCl3= nAl=0,1(mol)
-> mAlCl3= 133,5 x 0,1= 13,35(g)
mddAlCl3= mAl + mddHCl - mH2 = 2,7 + 200 - 3/2 x 0,1 x 2= 202,4(g)
C%ddAlCl3= (13,35/202,4).100= 6,596%
Tóm tắt
\(V_{H_2\left(đktc\right)}=8,96l\\ C_{\%H_2SO_4}=19,6\%\\ a)m_{Zn}=?\\ m_{ddH_2SO_4}=?\\ b)C_{\%ZnSO_4}=?\)
\(a)n_{H_2}=\dfrac{8,96}{22,4}=0,4mol\\ Zn+H_2SO_4\rightarrow ZnSO_4+H_2\)
0,4 0,4 0,4 0,4
\(m_{Zn}=0,4.65=26g\\ m_{ddH_2SO_4}=\dfrac{0,4.98}{19,6}\cdot100=200g\\ b)C_{\%ZnSO_4}=\dfrac{0,4.161}{26+200-0,4.2}\cdot100=28,6\%\)
B1:
2NaOH+H2SO4\(\rightarrow\)Na2SO4+2H2O
nNaOH=\(\frac{4}{40}=0.1\)mol
=>nH2SO4=\(\frac{1}{2}\)nNaOH=0.05 mol
=>CM=\(\frac{n_{H2SO42}}{V}\)=\(\frac{0.05}{200}\)=2,5.10-4 (M)
B2:
Mg+\(\frac{1}{2}\)O2\(\underrightarrow{t^0}\)MgO (1)
MgO+2HCl\(\rightarrow\)MgCl2+H2O (2)
nMg(1)=\(\frac{0,36}{24}=0,015mol\)
=>nMgO(1)=0,015=nMgO(2)
nHCl(2)=2nMgO(2)=0,03mol
=>CM(HCl)=\(\frac{n_{HCl}}{V}=\frac{0,03}{100}=3.10^{-4}M\)
a, \(CaO+H_2O\rightarrow Ca\left(OH\right)_2\)
b, \(n_{CaO}=\dfrac{11,2}{56}=0,2\left(mol\right)\)
Theo PT: \(n_{Ca\left(OH\right)_2}=n_{CaO}=0,2\left(mol\right)\Rightarrow C_{M_{Ca\left(OH\right)_2}}=\dfrac{0,2}{0,2}=1\left(M\right)\)
c, \(Ca\left(OH\right)_2+H_2SO_4\rightarrow CaSO_4+2H_2O\)
Theo PT: \(n_{H_2SO_4}=n_{Ca\left(OH\right)_2}=0,2\left(mol\right)\)
\(\Rightarrow m_{ddH_2SO_4}=\dfrac{0,2.98}{15\%}=\dfrac{392}{3}\left(g\right)\)
\(\Rightarrow V_{ddH_2SO_4}=\dfrac{\dfrac{392}{3}}{1,05}\approx124,44\left(ml\right)\)