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![](https://rs.olm.vn/images/avt/0.png?1311)
Giả sử ban đầu có 100g CaCO3
Gọi số mol CaCO3 phản ứng là a
PTHH: CaCO3 --to--> CaO + CO2
a------------->a------>a
=> mgiảm = mCO2 = 44a (g)
=> \(\dfrac{44a}{100}.100\%=20\%\)
=> a = \(\dfrac{5}{11}\left(mol\right)\)
=> \(H\%=\dfrac{\dfrac{5}{11}.100}{100}.100\%=45,45\%\)
![](https://rs.olm.vn/images/avt/0.png?1311)
\(a,PTHH:2KMnO_4\rightarrow^{t^o}K_2MnO_4+MnO_2+O_2\\ b,n_{O_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\\ \Rightarrow m_{O_2}=0,3\cdot32=9,6\left(g\right)\\ \Rightarrow m_{KMnO_4\left(bđ\right)}=m_{\text{chất rắn}}+m_{O_2}=109,6\left(g\right)\\ c,n_{MnO_2}=0,3\left(mol\right)\\ \Rightarrow m_{MnO_2}=0,3\cdot87=26,1\left(g\right)\\ \Rightarrow\%_{MnO_2}=\dfrac{26,1}{100}\cdot100\%=26,1\%\\ \Rightarrow\%_{KMnO_4}=100\%-26,1\%=73,9\%\)
![](https://rs.olm.vn/images/avt/0.png?1311)
Gọi n KMnO4 = a
n KClO3 = b ( mol )
--> 158a + 122,5 b = 43,3
PTHH :
\(2KClO_3\underrightarrow{t^o}2KCl+3O_2\uparrow\)
0,9b 1,35b
\(2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\uparrow\)
0,9a 0,45a
\(\%Mn=\dfrac{55a}{43,3-32\left(0,45a+1,35b\right)}=24,103\%\)
\(\rightarrow a=0,15\)
\(b=0,16\)
\(m_{KMnO_4}=0,15.158=23,7\left(g\right)\)
\(m_{KClO_3}=0,16.122,5=19,6\left(g\right)\)
![](https://rs.olm.vn/images/avt/0.png?1311)
$2KMnO_4\xrightarrow{t^o}K_2MnO_4+MnO_2+O_2$
$a\bigg)$
$n_{KMnO_4}=\frac{15,8}{158}=0,1(mol)$
Chất rắn sau p/ứ là $K_2MnO_4,MnO_2$
Theo PT: $n_{K_2MnO_4}=n_{MnO_2}=0,05(mol)$
$\to m_{\rm chất\, rắn}=0,05.197+0,05.87=14,2(g)$
$b\bigg)$
Vì $H=80\%\to n_{KMnO_4(p/ứ)}=0,1.80\%=0,08(mol)$
$\to n_{KMnO_4(dư)}=0,02(mol)$
Chất rắn sau p/ứ là $KMnO_4(dư):0,02;K_2MnO_4:0,04;MnO_2:0,04$
$\to m_{\rm chất\, rắn}=0,02.158+0,04.197+0,04.87=14,52(g)$
$c\bigg)$
Bảo toàn KL có:
$m_{O_2}=m_{KMnO_4}-m_{CR}$
$\to m_{O_2}=15,8-14,68=1,12(g)\to n_{O_2}=0,035(mol)$
Theo PT: $n_{KMnO_4(p/ứ)}=2n_{O_2}=0,07(mol)$
$\to H=\dfrac{0,07}{0,1}.100\%=70\%$
![](https://rs.olm.vn/images/avt/0.png?1311)
\(1)PTHH:CaCO_3\xrightarrow{t^o}CaO+CO_2\uparrow\\ n_{CaCO_3}=\dfrac{500.95\%}{100}=4,75(mol)\\ \Rightarrow n_{CaO}=4,75(mol)\\ \Rightarrow m_{CaO}=4,75.56=266(g)\\ \Rightarrow m_{CaO(tt)}=266.80\%=212,8(g)\\ m_{CaCO_3(k p/ứ)}=500.95\%.20\%=95(g)\\ \Rightarrow m_A=95+212,8=307,8(g)\\ 2)\%m_{CaO}=\dfrac{212,8}{307,8}.100\%=69,136\%\\ n_{CO_2}=n_{CaO}=4,75(mol)\\ \Rightarrow V_{CO_2}=4,75.22,4=106,4(l)\)
Đặt :
nCaCO3 = x mol
CaCO3 -to-> CaO + CO2
x___________x
m giảm = mCaCO3 - mCaO = 33
<=> 100x - 56x = 33
<=> x = 0.75
CaCO3 -to-> CaO + CO2
0.75________0.75
mA = 100 - 0.75*100 + 0.75*56 = 67 g
H% = 75/100*100% = 75%