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Câu 3:
a)
CTPT xủa X là CnH2n+2O
\(n_{CO_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\Rightarrow n_{C_nH_{2n+2}O}=\dfrac{0,4}{n}\left(mol\right)\)
=> \(n_{H_2O}=\dfrac{\dfrac{0,4}{n}.\left(2n+2\right)}{2}=\dfrac{0,4}{n}\left(n+1\right)\left(mol\right)\)
Mà \(n_{H_2O}=\dfrac{9}{18}=0,5\left(mol\right)\)
=> n = 4
=> CTPT: C4H10O
b) \(n_{C_4H_{10}O}=\dfrac{0,4}{4}=0,1\left(mol\right)\)
=> m = 0,1.74 = 7,4 (g)
c)
(1) \(CH_3-CH_2-CH_2-CH_2OH\)
(2) \(CH_3-CH_2-CH\left(OH\right)-CH_3\)
(3) \(CH_3-C\left(CH_3\right)\left(OH\right)-CH_3\)
(4) \(CH_3-CH\left(CH_3\right)-CH_2OH\)
(5) \(CH_3-CH_2-CH_2-O-CH_3\)
(6) \(CH_3-CH\left(CH_3\right)-O-CH_3\)
(7) \(CH_3-CH_2-O-CH_2-CH_3\)
d)
X là \(CH_3-C\left(CH_3\right)\left(OH\right)-CH_3\) (2-metylpropan-2-ol)
![](https://rs.olm.vn/images/avt/0.png?1311)
Khi cho hh qua dd AgNO3/NH3 thì chỉ có C3H4 pứ do chứa lk 3 đầu mạch còn C3H8 thì không
\(n_{kt}=n_{C3H3Ag}=0,15\left(mol\right)\)
\(PTHH:C_3H_4+AgNO_3+NH_3\rightarrow C_3H_3Ag\downarrow+NH_4NO_3\)
_________0,15______________________0,15_______
\(n_{C3H4}=0,15\left(mol\right)\)
\(m_{C3H4}=0,15.\left(12.3+4\right)=6\left(g\right)\)
\(\Rightarrow m_{C3H8}=8,2-6=2,2\left(g\right)\)
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Câu 1.
\(CH_3COOH+NaOH\rightarrow CH_4\uparrow+Na_2CO_3\)
\(2CH_4\xrightarrow[LLN]{1500^oC}C_2H_2+2H_2\uparrow\)
\(C_2H_2+H_2\underrightarrow{t^o,xtPd}C_2H_4\)
a)\(C_2H_4+HBr\rightarrow C_2H_5Br\)
b)\(C_2H_4+HCl\underrightarrow{as}C_2H_5Cl\)
![](https://rs.olm.vn/images/avt/0.png?1311)
![](https://rs.olm.vn/images/avt/0.png?1311)