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a, \(n_{CaCO_3}=\dfrac{41,2}{100}=0,412\left(mol\right)\)
PTHH: CaO + H2O → Ca(OH)2
Mol: 0,412 0,412
PTHH: Ca(OH)2 + CO2 → CaCO3 + H2O
Mol: 0,412 0,412 0,412
\(m_{CaO}=0,412.56=23,072\left(g\right)\)
b, \(V_{CO_2}=0,412.22,4=9,2288\left(l\right)\)
\(m_{Na_2CO_3}=100.16,96\%=16,96\left(g\right)\Rightarrow n_{Na_2CO_3}=\dfrac{16,96}{106}=0,16\left(mol\right)\)
\(m_{BaCl_2}=200.10,4\%=20,8\left(g\right)\Rightarrow n_{BaCl_2}=\dfrac{20,8}{208}=0,1\left(mol\right)\)
PTHH: Na2CO3 + BaCl2 → BaCO3 + 2NaCl
Mol: 0,1 0,1 0,2
Ta có: \(\dfrac{0,16}{1}>\dfrac{0,1}{1}\) ⇒ Na2CO3 dư, BaCl2 hết
mdd sau pứ = 100 + 200 = 300 (g)
\(C\%_{ddNaCl}=\dfrac{0,1.58,5.100\%}{300}=1,95\%\)
\(C\%_{ddNa_2CO_3}=\dfrac{\left(0,16-0,1\right).106.100\%}{300}=2,12\%\)
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PTHH: \(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\uparrow\)
Ta có: \(\left\{{}\begin{matrix}n_{Zn}=\dfrac{6,5}{65}=0,1\left(mol\right)\\n_{H_2SO_4}=0,2\cdot1=0,2\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\) Axit còn dư, Kẽm p/ứ hết
\(\Rightarrow n_{ZnSO_4}=n_{H_2}=0,1\left(mol\right)=n_{H_2SO_4\left(dư\right)}\)
\(\Rightarrow\left\{{}\begin{matrix}V_{H_2}=0,1\cdot22,4=2,24\left(l\right)\\C_{M_{ZnSO_4}}=C_{M_{H_2SO_4\left(dư\right)}}=\dfrac{0,1}{0,2}=0,5\left(M\right)\end{matrix}\right.\)
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29.B
30.A
31.C
32.C
33.D
29.B
30.A
31.C
32.C
33.D