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![](https://rs.olm.vn/images/avt/0.png?1311)
\(\text{+ nFeCl3= }\frac{19,5}{162,5}=\text{ 0.12 mol}\)
\(\text{+ nAl2(SO4)3= }\frac{27,36}{342}\text{= 0.08 mol}\)
\(\text{+ nH2SO4= }\frac{200}{98}\text{x9.8%= 0.2 mol}\)
\(\text{+ nNaOH=}\frac{77,6}{40}\text{=1.94 mol}\)
+ Cho A + NaOH ta có:
+ Kết tủa B gồm: Fe(OH)3
+ Dd C gồm: NaOH dư ; Na2SO4 ; NaCl ; NaAlO2
\(\text{a) + Chất rắn D là : Fe2O3 0.06 mol}\)
\(\Rightarrow\text{mD= 160x 0.06=9.6 g }\)
b) + mdd C= 400g
\(\text{+ C% NaOH=}\text{5.4%}\)
\(\text{+ C% Na2SO4=}15,62\%\)
\(\text{+ C% NaCl=}5,625\%\)
\(\text{+ C% NaAlO2= }3,28\%\)
nFeCl3 = 0,12
nAl2(SO4)3 = 0,08
nH2SO4 = 0,2
nNaOH = 1,94
Ưu tiên phản ứng trung hòa trước: H2SO4 + 2NaOH —> Na2SO4 + 2H2O
0,2 ——-> 0,4
FeCl3 + 3NaOH —> Fe(OH)3 + 3NaCl
0,12 —-> 0,36
Al2(SO4)3 + 6NaOH —> 2Al(OH)3 + 3Na2SO4
0,08 ———-> 0,48
Sau 3 phản ứng thì còn lại nNaOH = 0,7, sau đó:
Al(OH)3 + NaOH —> NaAlO2 + 2H2O
0,16 ——-> 0,16
Nung kết tủa: 2Fe(OH)3 —> Fe2O3 + 3H2O
0,12 ————>0,06
m = 9,6 gam
Phần dung dịch chứa Na2SO4 (0,44 mol), NaCl (0,36 mol), NaAlO2 (0,16 mol) và NaOH dư (0,54 mol) —> C% ll là 15,62%; 5,625 %; 3,28%; 5,4%.
![](https://rs.olm.vn/images/avt/0.png?1311)
a)
$Fe_2(SO_4)_3 + 6KOH \to 2Fe(OH)_3 + 3K_2SO_4$
b)
$n_{Fe_2(SO_4)_3} = 0,3.1 = 0,3(mol)$
$n_{KOH} = \dfrac{16,8}{56} =0,3(mol)$
Ta thấy :
$n_{KOH} : 3 < n_{Fe_2(SO_4)_3} : 1$ nên $Fe_2(SO_4)_3$ dư
$n_{Fe(OH)_3} = \dfrac{1}{3}n_{KOH} = 0,1(mol)$
$n_{Fe_2O_3} = \dfrac{1}{2}n_{Fe(OH)_3} = 0,05(mol)$
$m_{Fe_2O_3} = 0,05.160 = 8(gam)$
![](https://rs.olm.vn/images/avt/0.png?1311)
Ta có :
\(\text{nFeCL3=0.12 nAl2(SO4)3=0.08 nH2SO4=0.2}\)
a. nNaOH=1.94
\(\text{2NaOH+H2SO4-->Na2SO4+2H2O}\)
0.4................0.2..........................................(mol)
\(\text{nNaOH còn=1.54}\)
\(\text{FeCL3+ 3NaOH-->Fe(OH)+3NaCl}\)
0.12...............0.36............0.12..........................(mol)
\(\text{nNaOH còn =1.18}\)
\(\text{ Al2(SO4)3+ 6NaOH-->2Al(OH3)+3Na2SO4}\)
0.08.....................0.48............0.16.................................(mol)
\(\text{-->nNaOH còn=0.7}\)
\(\text{Al(OH)3+ NaOH-->NaAlO2+2H2O}\)
0.16.................0.16............0.16.......................................(mol)
nNaOh còn =0.54
Nung B 2Fe(OH)3-->Fe2O3+3H2O
0.12 0.06
m=9.6
b.mdd H2SO4 ban đầu =1.14*200=228g
-->MddC=19.5+27.36+228-0.12*107=262.02
m nước cần thêm là 400-mddC=137.98
\(\left\{{}\begin{matrix}\text{c%NaOH dư=0.54*40/400=0.054%}\\\text{c%NaAlO2=0.16*82/400=0.0328%}\end{matrix}\right.\)
![](https://rs.olm.vn/images/avt/0.png?1311)
a,\(\text{CuO+H2SO4}\rightarrow\text{CuSO4+H2O}\)
\(\text{CuSO4+2NaOH}\rightarrow\text{Na2SO4+Cu(OH)2}\)
\(\text{Cu(OH)2}\rightarrow\text{CuO+H2O}\)
\(\text{b) nH2SO4=0,02(mol)}\)
mdd spu=0,02x80+20=21,6(g)
\(\text{C%=0,02x160/21,6=14,81%}\)
c) nNaOH=0,04(mol)
mdd=0,04x40/8%=20(g)
\(\text{d) mcr=0,02x80=1,6(g)}\)
![](https://rs.olm.vn/images/avt/0.png?1311)
\(3NaOH+FeCl_3\rightarrow Fe\left(OH\right)_3+3NaCl\)
\(n_{NaCl}=n_{NaOH}=0,2.3=0,6\left(mol\right)\)
=> \(C_{M\left(NaCl\right)}=\dfrac{0,6}{0,2}=3M\)
\(n_{Fe\left(ỌH\right)_3}=\dfrac{1}{3}n_{NaOH}=0,2\left(mol\right)\)
\(2Fe\left(OH\right)_3-^{t^o}\rightarrow Fe_2O_3+3H_2O\)
Ta có \(n_{Fe_2O_3}=\dfrac{1}{2}n_{Fe\left(OH\right)_3}=0,1\left(mol\right)\)
=> m Fe2O3 = 0,1 . 160=16(g)