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![](https://rs.olm.vn/images/avt/0.png?1311)
a)
C2H4 + 3O2 --to--> 2CO2 + 2H2O
2C3H6 + 9O2 --to--> 6CO2 + 6H2O
C2H4O2 + 2O2 --to--> 2CO2 + 2H2O
b)
Quy đổi C2H4, C3H6 thành CnH2n
hh chứa \(\left\{{}\begin{matrix}C_nH_{2n}:a\left(mol\right)\\C_2H_4O_2:b\left(mol\right)\end{matrix}\right.\)
=> 14an + 60b = 13 (1)
PTHH: CnH2n + \(\dfrac{3n}{2}\)O2 --to--> nCO2 + nH2O
a--->1,5an-------->an
C2H4O2 + 2O2 --to--> 2CO2 + 2H2O
b----->2b---------->2b
=> \(n_{CO_2}=an+2b=\dfrac{15,68}{22,4}=0,7\left(mol\right)\) (2)
(1)(2) => an = 0,5; b = 0,1 (mol)
\(V=22,4.\left(1,5an+2b\right)=21,28\left(l\right)\)
c) \(\%m_{C_2H_4O_2}=\dfrac{60.0,1}{13}.100\%=46,154\%\)
![](https://rs.olm.vn/images/avt/0.png?1311)
a, \(CH_4+2O_2\underrightarrow{t^o}CO_2+2H_2O\)
\(C_2H_4+3O_2\underrightarrow{t^o}2CO_2+2H_2O\)
\(2C_2H_2+5O_2\underrightarrow{t^o}4CO_2+2H_2O\)
b, Sửa đề: 17,9 (l) → 17,92 (l)
Ta có: \(n_{CO_2}=\dfrac{17,92}{22,4}=0,8\left(mol\right)=n_C\)
\(n_{H_2O}=\dfrac{18}{18}=1\left(mol\right)\Rightarrow n_H=1.2=2\left(mol\right)\)
⇒ mA = mC + mH = 0,8.12 + 2.1 = 11,6 (g)
Theo ĐLBT KL, có: mA + mO2 = mCO2 + mH2O
⇒ mO2 = 0,8.44 + 18 - 11,6 = 41,6 (g)
\(\Rightarrow n_{O_2}=\dfrac{41,6}{32}=1,3\left(mol\right)\Rightarrow V_{O_2}=1,3.22,4=29,12\left(l\right)\)
![](https://rs.olm.vn/images/avt/0.png?1311)
CH4 + 2O2 t0→ CO2 + 2H2O
C2H4 + 3O2 t0→ 2CO2 + 2H2O
C2H2 + 52 O2 t0→ 2CO2 + 2H2O
-Gọi: nCH4:a(mol)
nC2H4:b(mol)
nC2H2:c(mol)
⇒16a+28b+26c=11(1)
BTNT C ⇒a+2b+2c=0,75(2)
-Phân tích (1)và (2) ta được:
{13a+26b+26c=9,75
=>3a+2b=1,25(3)
16a+32b+32c=12
=>4b+6c=1(4)
-Từ (3) ⇒ \(a=\dfrac{1,25-2b}{3}\)
-Từ (4)⇒\(\dfrac{1-4c}{6}\)
-% CH4 =\(\dfrac{16a}{16a+32b+32c}.100\)
-Thay công thức a và c vào (⋅)
⇒%CH4=\(\dfrac{\dfrac{1,25-2b}{3}16}{16\dfrac{1,25-2b}{3}+28b+26.\dfrac{1-4b}{6}}100=12,12\%\)
![](https://rs.olm.vn/images/avt/0.png?1311)
nO (trong CO2) = 2 . nCO2 = 2 . 26,4/44 = 1,2 (mol)
nO (trong H2O) = nH2O = 13,5/18 = 0,75 (mol)
nO (trong O2) = 1,2 + 0,75 = 1,95 (mol)
nO2 = 1,95/2 = 0,975 (mol)
VO2 = 0,975 . 22,4 = 21,84 (l)
Vkk = 21,84 . 5 = 109,2 (l)
nO (trong CO2) = 2 . nCO2 = 2 . 26,4/44 = 1,2 (mol)
nO (trong H2O) = nH2O = 13,5/18 = 0,75 (mol)
nO (trong O2) = 1,2 + 0,75 = 1,95 (mol)
nO2 = 1,95/2 = 0,975 (mol)
VO2 = 0,975 . 22,4 = 21,84 (l)
Vkk = 21,84 . 5 = 109,2 (l)
![](https://rs.olm.vn/images/avt/0.png?1311)
Gọi a, b lần lượt là số mol CH4, O2
Ta có \(\left\{{}\begin{matrix}a+b=\dfrac{5,6}{22,4}\\16a+32b=5,6\end{matrix}\right.\)
=> \(\left\{{}\begin{matrix}a=0,15\\b=0,1\end{matrix}\right.\)
CH4 + 2O2 → CO2 + 2H2O
0,15.....0,1.......
Lập tỉ lệ : \(\dfrac{0,15}{1}>\dfrac{0,1}{2}\) => CH4 dư, O2 hết
\(n_{CH_4\left(dư\right)}=0,15-\dfrac{0,1}{2}=0,05\left(mol\right)\)
=> \(V_{CH_4}=0,1.22,4=2,24\left(l\right)\)
\(m_{CO_2}=\dfrac{0,1}{2}.44=2,2\left(g\right)\)
\(m_{H_2O}=0,1.18=1,8\left(g\right)\)
![](https://rs.olm.vn/images/avt/0.png?1311)
a)
2CO + O2 --to--> 2CO2
2H2 + O2 --to--> 2H2O
b) \(n_{H_2O}=\dfrac{12,6}{18}=0,7\left(mol\right)\); \(n_{CO_2}=\dfrac{13,44}{22,4}=0,6\left(mol\right)\)
PTHH: 2CO + O2 --to--> 2CO2
0,6<--0,3<------0,6
2H2 + O2 --to--> 2H2O
0,7<--0,35<------0,7
=> \(\left\{{}\begin{matrix}V_{CO}=0,6.22,4=13,44\left(l\right)\\V_{H_2}=0,7.22,4=15,68\left(l\right)\end{matrix}\right.\)
VO2 = (0,3 + 0,35).22,4 = 14,56 (l)
c) \(M_A=\dfrac{0,6.28+0,7.2}{0,6+0,7}=14\left(g/mol\right)\)
=> \(d_{A/O_2}=\dfrac{14}{32}=0,4375\)
![](https://rs.olm.vn/images/avt/0.png?1311)
\(n_{O_2}=\dfrac{44,8}{22,4}.20\%=0,4(mol)\)
Bảo toàn NT (O): \(n_{O_2}=n_{CO_2}=\dfrac{1}{2}n_{H_2O}\)
\(\Rightarrow n_{CO_2}=0,4(mol);n_{H_2O}=0,8(mol)\\ \Rightarrow V_{CO_2}=0,4.22,4=8,96(g);m_{H_2O}=0,8.18=14,4(g)\)
![](https://rs.olm.vn/images/avt/0.png?1311)
\(n_{hh}=\dfrac{4.48}{22.4}=0.2\left(mol\right)\)
\(n_{C_2H_4}=75\%\cdot0.2=0.15\left(mol\right)\)
\(\Rightarrow n_{C_4H_8}=0.2-0.15=0.05\left(mol\right)\)
\(C_2H_4+3O_2\underrightarrow{^{^{t^0}}}2CO_2+2H_2O\)
\(C_4H_8+6O_2\underrightarrow{^{^{t^0}}}4CO_2+4H_2O\)
\(V_{O_2}=\left(0.15\cdot3+0.05\cdot6\right)\cdot22.4=16.8\left(l\right)\)
\(V_{CO_2}=\left(0.15\cdot2+0.05\cdot4\right)\cdot22.4=11.2\left(l\right)\)
\(\text{a, C2H4 + 3O2 ---> 2CO2 + 2H2O }\)
\(\text{CH4 + 2O2 ---> CO2 + 2H2O}\)
\(\text{C3H4 + 4O2 ----> 3CO2 + 2H2O}\)
b, Ta có :
\(\text{n H2O = 0,7 mol}\)
Dựa vào PTHH, ta thấy: 1 mol.khí nào cũng đều tạo ra 2 mol H2O
\(\Rightarrow\text{n khí = 1/2. n H2O = 0 35 mol}\)
\(\Rightarrow\text{V khí = 0,35.22,4 = 7,84 lít}\)