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1)
Coi \(n_X = 1(mol)\)
Gọi : \(n_{CO_2} = a(mol) ; n_{N_2} = b(mol)\)
Ta có :
\(n_X = a + b = 1(mol)\\ m_X = 44a + 28b = 1.1,225.32(gam)\\ \Rightarrow a = 0,7 ; b = 0,3\)
Vậy :
\(\%V_{CO_2} = \dfrac{0,7}{1}.100\% = 70\%\\ \%V_{N_2} = 100\% - 70\% = 30\%\)
2)
\(n_X = \dfrac{1}{22,4}(mol)\\ \Rightarrow m_X = n.M = \dfrac{1}{22,4}.1,225.32 = 1,75(gam)\)
Gọi số mol O2, CO2 là a, b
Có: \(\overline{M}=\dfrac{32a+44b}{a+b}=19,5.2=39\)
=> \(a=\dfrac{5}{7}b\)
=> \(\left\{{}\begin{matrix}\%V_{O_2}=\dfrac{a}{a+b}.100\%=\dfrac{\dfrac{5}{7}b}{\dfrac{5}{7}b+b}.100\%=41,67\%\\\%V_{CO_2}=\dfrac{b}{a+b}.100\%=\dfrac{b}{\dfrac{5}{7}b+b}.100\%=58,33\%\end{matrix}\right.\)
\(\left\{{}\begin{matrix}\%m_{O_2}=\dfrac{32a}{32a+44b}.100\%=34,188\%\\\%m_{CO_2}=\dfrac{44b}{32a+44b}.100\%=65,812\%\end{matrix}\right.\)
thay a = \(\dfrac{5}{7}b\) thôi bn :)
\(\%m_{O_2}=\dfrac{32a}{32a+44b}.100\%=\dfrac{32.\dfrac{5}{7}b}{32.\dfrac{5}{7}b+44b}.100\%=34,188\%\)
Gọi \(\left\{{}\begin{matrix}n_{SO_2}=a\left(mol\right)\\n_{SO_3}=b\left(mol\right)\end{matrix}\right.\)
\(d_A\)/O2=2,25\(\Rightarrow M_A=72đvC\)
\(\Rightarrow\dfrac{64a+80b}{a+b}=72\)
\(\Rightarrow64a+80b=72a+72b\)
\(\Rightarrow a=b\)
\(\%V_{SO_2}=\%V_{SO_3}=\dfrac{a}{a+b}\cdot100\%=50\%\)
\(\%m_{SO_2}=\dfrac{64a}{64a+80b}\cdot100\%=\dfrac{64a}{64a+80b}\cdot100\%=44,44\%\)
\(\%m_{SO_3}=100\%-44,44\%=55,56\%\)
a)
$n_{Cl_2} : n_{O_2} = 1 : 2$
Suy ra :
$\%V_{Cl_2} = \dfrac{1}{1 + 2}.100\% = 33,33\%$
$\%V_{O_2} = \dfrac{2}{1 + 2}.100\% = 66,67\%$
b)
Coi $n_{Cl_2} = 1 (mol) \Rightarrow n_{O_2} = 2(mol)$
$\%m_{Cl_2} = \dfrac{1.71}{1.71 + 2.32}.100\% = 52,59\%$
$\%m_{O_2} = 100\% -52,59\% = 47,41\%$
c)
$M_A = \dfrac{71.1 + 32.2}{1 + 2} = 45(g/mol)$
$d_{A/B} = \dfrac{45}{28} = 1,607$
\(a.\)
\(GS:\)
\(n_{hh}=1\left(mol\right)\)
\(Đặt:n_{N_2}=a\left(mol\right),n_{CO_2}=b\left(mol\right)\)
\(\Rightarrow a+b=1\left(1\right)\)
\(m_A=28a+44b=18\cdot2=36\left(2\right)\)
\(\left(1\right),\left(2\right):\)
\(a=b=0.5\)
\(\%m_{N_2}=\dfrac{0.5\cdot28}{0.5\cdot28+0.5\cdot44}\cdot100\%=38.89\%\)
\(\%m_{CO_2}=61.11\%\)
\(b.\)
\(\dfrac{n_{N_2}}{n_{CO_2}}=\dfrac{0.5}{0.5}=\dfrac{1}{1}\)
\(n_{N_2}=n_{CO_2}=\dfrac{1}{2}\cdot n_A=\dfrac{0.2}{2}=0.1\left(mol\right)\)
\(Đặt:n_{CO_2}=x\left(mol\right)\)
\(\overline{M}=\dfrac{0.1\cdot28+0.1\cdot44+44x}{0.2+x}=20\cdot2=40\left(\dfrac{g}{mol}\right)\)
\(\Rightarrow x=0.2\)
\(m_{CO_2\left(cầnthêm\right)}=0.2\cdot44=8.8\left(g\right)\)
1, a, + 8.2=16 => CH4
+ 8,5 . 2 = 17 => NH3
+ 16 . 2 =32 => O2
+ 22 . 2 = 44 => CO2
b, + 0,138 . 29 \(\approx4\) => He
+ 1,172 . 29 \(\approx34\) => H2S
+ 2,448 . 29 \(\approx71\Rightarrow Cl_2\)
+ 0,965 . 29 \(\approx28\) => N