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Gọi \(\left\{{}\begin{matrix}n_{Mg}=x\\n_{Zn}=y\end{matrix}\right.\)
\(n_{H_2}=\dfrac{6,72}{22,4}=0,3mol\)
\(Mg+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Mg+H_2\)
x 2x x x ( mol )
\(Zn+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Zn+H_2\)
y 2y y y ( mol )
Ta có:
\(\left\{{}\begin{matrix}24x+65y=11,3\\x+y=0,3\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}x=0,2\\y=0,1\end{matrix}\right.\)
\(\rightarrow\left\{{}\begin{matrix}m_{Mg}=0,2.24=4,8g\\m_{Zn}=0,1.65=6,5g\end{matrix}\right.\)
\(\rightarrow\left\{{}\begin{matrix}\%m_{Mg}=\dfrac{4,8}{11,3}.100=42,47\%\\\%m_{Zn}=100\%-42,47\%=57,53\%\end{matrix}\right.\)
\(m_{CH_3COOH}=60.\left(0,2+0,1\right)=18g\)
\(C\%_{CH_3COOH}=\dfrac{18}{200}.100=9\%\)
\(\left\{{}\begin{matrix}m_{\left(CH_3COO\right)_2Mg}=0,2.142=28,4g\\m_{\left(CH_3COO\right)_2Zn}=0,1.183=18,3g\end{matrix}\right.\)
\(m_{ddspứ}=11,3+200-0,3.2=210,7g\)
\(\rightarrow\left\{{}\begin{matrix}C\%_{\left(CH_3COO\right)_2Mg}=\dfrac{28,4}{210,7}.100=13,47\%\\C\%_{\left(CH_3COO\right)_2Zn}=\dfrac{18,3}{210,7}.100=8,68\%\end{matrix}\right.\)
a)Mg+2CH3COOH→Mg(CH3COO)2+H2
Zn+2CH3COOH→Zn(CH3COO)2+H2
nH2=0,3mol
Gọi a và b lần lượt là số mol của Mg và Zn
\(\left\{{}\begin{matrix}24a+65b=11,3\\a+b=0,3\end{matrix}\right.\)
→a=0,2,b=0,1
→mMg=0,2×24=4,8g
→mZn=0,1×65=6,5g
b)%mMg=\(\dfrac{4,8}{11,3}\)×100%=42,48%
%mZn=\(\dfrac{6,5}{11,3}\)×100%=57,52%
c)nCH3COOH=2nMg+2nZn=0,6mol
→mCH3COOH=0,6×60=36g
→C%CH3COOH=\(\dfrac{36}{200}\)×100%=18%
→nMg(CH3COO)2=nMg=0,2mol
→nZn(CH3COO)2=nZn=0,1mol
→mMg(CH3COO)2=0,2×142=28,4g
→mZn(CH3COO)2=0,1×183=18,3g
nH2=nMg+nZn=0,3mol
→mH2=0,6g
→mddmuối=mhỗnhợp+mddCH3COOH−mH2
→mddmuối=11,3+200−0,6=210,7g
→C%Mg(CH3COO)2=\(\dfrac{28,4}{210,7}\)×100%=13,48%
→C%Zn(CH3COO)2=\(\dfrac{18,3}{210,7}\)×100%=8,69%
nH2=0,1(mol)
PTHH: Mg + 2 HCl -> MgCl2 + H2
0,1__________0,2___________0,1(mol)
MgO + 2 HCl -> MgCl2 + H2O
0,05____0,1___0,05(mol)
mMg=0,1. 24= 2,4(g) -> mMgO=4,4-2,4= 2(g) -> nMgO=0,05((mol)
b) %mMg= (2,4/4,4).100=54,545%
=> %mMgO=45,455%
c) nHCl=0,3(mol) -> mHCl=0,3.36,5=10,95(g)
=> mddHCl=(10,95.100)/7,3=150(g)
$a\big)$
$Zn+2CH_3COOH\to (CH_3COO)_2Zn+H_2$
$ZnO+2CH_3COOH\to (CH_2COO)_2Zn+H_2O$
Theo PT: $n_{Zn}=n_{H_2}=\frac{4,48}{22,4}=0,2(mol)$
$\to \%m_{Zn}=\frac{0,2.65}{21,1}.100\%\approx 61,61\%$
$\to \%m_{ZnO}=100-61,61=38,39\%$
$b\big)$
$n_{ZnO}=\frac{21,1-0,2.65}{81}=0,1(mol)$
Theo PT: $\sum n_{CH_3COOH}=2n_{Zn}+2n_{ZnO}=0,6(mol)$
$\to C_{M_{CH_3COOH}}=\dfrac{0,6}{\frac{200}{1000}}=3M$
\(n_{H_2}=\dfrac{4,48}{22,4}=0,2mol\)
\(Zn+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Zn+H_2\)
0,2 0,2 ( mol )
\(m_{Zn}=0,2.65=13g\)
\(\%m_{Zn}=\dfrac{13}{21,1}.100=61,61\%\)
\(\%m_{ZnO}=100\%-61,61\%=38,39\%\)
\(Zn+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Zn+H_2\)
0,2 0,4 ( mol )
\(n_{ZnO}=\dfrac{21,1-13}{81}=0,1mol\)
\(ZnO+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Zn+H_2O\)
0,1 0,2 ( mol )
\(C_{M\left(CH_3COOH\right)}=\dfrac{0,4+0,2}{0,2}=3M\)
\(n_{H_2}=\dfrac{4.48}{22.4}=0.2\left(mol\right)\)
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
\(0.2.........0.4.........0.2......0.2\)
\(m_{Zn}=0.2\cdot65=13\left(g\right)\Rightarrow m_{ZnO}=14.6-13=1.6\left(g\right)\)
\(\%Zn=\dfrac{13}{14.6}\cdot100\%=89.04\%\)
\(\%ZnO=100\%-89.04\%=10.96\%\)
\(n_{ZnO}=\dfrac{1.6}{81}\approx0.02\left(mol\right)\)
\(ZnO+2HCl\rightarrow ZnCl_2+H_2O\)
\(0.02........0.04........0.02........0.02\)
\(n_{HCl}=0.4+0.04=0.44\left(mol\right)\)
\(C_{M_{HCl}}=\dfrac{0.44}{0.8}=0.55\left(M\right)\)
Eeeee ngồi tính sang chấn thật nó ra số xấu lần mò hơn 20p chưa biết tính sai chỗ nào
a)
Gọi $n_{Fe} = a(mol) ; n_{Al} =b (mol) \Rightarrow 56a + 27b = 11(1)$
$Fe + 2HCl \to FeCl_2 + H_2$
$2Al + 6HCl \to 2AlCl_3 + 3H_2$
Theo PTHH : $n_{H_2} = a + 1,5b = \dfrac{8,96}{22,4} = 0,4(2)$
Từ (1)(2) suy ra : a = 0,1 ; b = 0,2
$\%m_{Fe} = \dfrac{0,1.56}{11}.100\% = 50,9\%$
$\%m_{Al} = 100\% - 50,9\% = 49,1\%$
b) $n_{HCl} = 2n_{H_2} = 0,8(mol)$
$\Rightarrow C_{M_{HCl}} = \dfrac{0,8}{0,4} = 2M$
c)
$C_{M_{FeCl_2}} = \dfrac{0,1}{0,4} = 0,25M$
$C_{M_{AlCl_3}} =\dfrac{0,2}{0,4} = 0,5M$
\(n_{H_2}=\dfrac{2.24}{22.4}=0.1\left(mol\right)\)
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
\(0.1.......0.2......................0.1\)
Chất rắn X : Cu
\(m_{Zn}=0.1\cdot65=6.5\left(g\right)\Rightarrow m_{Cu}=19.3-6.5=12.8\left(g\right)\)
\(n_{Cu}=\dfrac{12.8}{64}=0.2\left(mol\right)\)
\(C_{M_{HCl}}=\dfrac{0.2}{0.2}=1\left(M\right)\)
\(2Cu+O_2\underrightarrow{^{^{t^o}}}2CuO\)
\(0.2........0.1\)
\(m_{tăng}=m_{O_2}=0.1\cdot32=3.2\left(g\right)\)
Sửa đề: 3,785 (l) → 3,7185 (l)
a, \(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
\(Al_2O_3+6HCl\rightarrow2AlCl_3+3H_2O\)
b, Ta có: \(n_{H_2}=\dfrac{3,7185}{24,79}=0,15\left(mol\right)\)
Theo PT: \(n_{Al}=\dfrac{2}{3}n_{H_2}=0,1\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Al}=\dfrac{0,1.27}{40}.100\%=6,75\%\\\%m_{Al_2O_3}=93,25\%\end{matrix}\right.\)
c, \(n_{Al_2O_3}=\dfrac{40.93,25\%}{102}=\dfrac{373}{1020}\left(mol\right)\)
Theo PT: \(n_{HCl}=3n_{Al}+6n_{Al_2O_3}=\dfrac{212}{85}\left(mol\right)\)
\(\Rightarrow V_{HCl}=\dfrac{\dfrac{212}{85}}{2}=\dfrac{106}{85}\left(l\right)\approx1247,06\left(ml\right)\)
d, \(n_{AlCl_3}=n_{Al}+2n_{Al_2O_3}=\dfrac{212}{255}\left(mol\right)\)
\(\Rightarrow m_{AlCl_3}=\dfrac{212}{255}.133,5=\dfrac{9434}{85}\left(g\right)\)
e, \(C_{M_{AlCl_3}}=\dfrac{\dfrac{212}{255}}{\dfrac{106}{85}}=\dfrac{2}{3}\left(M\right)\)
Gọi \(\left\{{}\begin{matrix}n_{Mg}=a\left(mol\right)\\n_{Zn}=b\left(mol\right)\end{matrix}\right.\)
\(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
PTHH:
Mg + 2CH3COOH ---> (CH3COO)2Mg + H2
a---->2a-------------------->a------------------>a
Zn + 2CH3COOH ---> (CH3COO)2Zn + H2
b---->2b------------------->b------------------>b
=> \(\left\{{}\begin{matrix}24a+65b=8,9\\a+b=0,2\end{matrix}\right.\Leftrightarrow a=b=0,1\left(mol\right)\)
=> \(\left\{{}\begin{matrix}\%m_{Mg}=\dfrac{0,1.24}{8,9}.100\%=27\%\\\%m_{Zn}=100\%-27\%=73\%\end{matrix}\right.\)
=> \(C\%_{CH_3COOH}=\dfrac{\left(0,1.2+0,1.2\right).60}{200}.100\%=12\%\)
\(m_{dd}=200+8,9-0,2.2=208,5\left(g\right)\)
=> \(\left\{{}\begin{matrix}C\%_{\left(CH_3COO\right)_2Mg}=\dfrac{0,1.142}{208,5}.100\%=6,81\%\\C\%_{\left(CH_3COO\right)_2Zn}=\dfrac{0,1.183}{208,5}.100\%=8,78\%\end{matrix}\right.\)
\(n_{H_2}=\dfrac{4,48}{22,4}=0,2mol\)
Gọi \(\left\{{}\begin{matrix}n_{Mg}=x\\n_{Zn}=y\end{matrix}\right.\) ( mol )
\(\rightarrow24x+65y=8,9\left(g\right)\) (1)
\(Mg+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Mg+H_2\uparrow\)
x 2x x x ( mol )
\(Zn+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Zn+H_2\uparrow\)
y 2y y y ( mol )
\(\rightarrow x+y=0,2\left(mol\right)\) (2)
\(\left(1\right);\left(2\right)\rightarrow\left\{{}\begin{matrix}x=0,1\\y=0,1\end{matrix}\right.\)
\(\rightarrow\left\{{}\begin{matrix}\%m_{Mg}=\dfrac{0,1.24}{8,9}.100\%=26,96\%\\\%m_{Zn}=100\%-26,96\%=73,04\%\end{matrix}\right.\)
\(m_{CH_3COOH}=\left(2.0,1+2.0,1\right).60=24g\)
\(C\%_{CH_3COOH}=\dfrac{24}{200}.100\%=12\%\)
\(\left\{{}\begin{matrix}m_{\left(CH_3COO\right)_2Mg}=0,1.142=14,2g\\m_{\left(CH_3COO\right)_2Zn}=0,1.183=18,3g\end{matrix}\right.\)