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\(n_{Mg}=\dfrac{4.8}{24}=0.2\left(mol\right)\)
\(Mg+2HCl\rightarrow MgCl_2+H_2\)
\(0.2.......0.4........................0.2\)
\(C_{M_{HCl}}=\dfrac{0.4}{0.2}=2\left(M\right)\)
\(n_{CuO}=\dfrac{32}{80}=0.4\left(mol\right)\)
\(CuO+H_2\underrightarrow{^{^{t^0}}}Cu+H_2O\)
Lập tỉ lệ : \(\dfrac{0.4}{1}>\dfrac{0.2}{1}\)
=> CuO dư
\(m_{cr}=m_{CuO\left(dư\right)}+m_{Cu}=32-0.2\cdot80+0.2\cdot64=28.8\left(g\right)\)
\(\%Cu=\dfrac{0.2\cdot64}{28.8}\cdot100\%=44.44\%\)
\(\%CuO\left(dư\right)=55.56\%\)
\(n_{Zn}=\dfrac{13}{65}=0,2mol\)
\(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\)
0,2 0,2 0,2 0,2
a)\(V_{H_2}=0,2\cdot22,4=4,48l\)
b)\(m_{ZnSO_4}=0,2\cdot161=32,2g\)
\(m_{ddZnSO_4}=30+200-0,2\cdot2=229,6g\)
\(C\%=\dfrac{m_{ct}}{m_{dd}}\cdot100\%=\dfrac{32,2}{229,6}\cdot100\%=14,02\%\)
c)\(n_{CuO}=\dfrac{24}{80}=0,3mol\)
\(CuO+H_2\rightarrow Cu+H_2O\)
0,3 0,2 0,2
\(m_{rắn}=m_{Cu}=0,2\cdot64=12,8g\)
nZn=1365=0,2molnZn=1365=0,2mol
Zn+H2SO4→ZnSO4+H2Zn+H2SO4→ZnSO4+H2
0,2 0,2 0,2 0,2
a)VH2=0,2⋅22,4=4,48lVH2=0,2⋅22,4=4,48l
b)mH2SO4=0,2⋅98=19,6gmH2SO4=0,2⋅98=19,6g
C%=mctmdd⋅100%=19,6200⋅100%=9,8%C%=mctmdd⋅100%=19,6200⋅100%=9,8%
c)nCuO=2480=0,3molnCuO=2480=0,3mol
CuO+H2→Cu+H2OCuO+H2→Cu+H2O
0,3 0,2 0,2
mrắn=mCu=0,2⋅64=12,8g.
nAl = 5.4/27 = 0.2 (mol)
2Al + 6HCl => 2AlCl3 + 3H2
0.2.......0.6......................0.3
CM HCl = 0.6 / 0.4 = 1.5 (M)
nCuO = 32/80 = 0.4 (mol)
CuO + H2 -to-> Cu + H2O
0.2.......0.2..........0.2
Chất rắn : 0.2 (mol) CuO dư , 0.2 (mol) Cu
%CuO = 0.2*80 / ( 0.2*80 + 0.2*64) * 100% = 55.56%
%Cu = 44.44%
nZn = 13/65 = 0,2 (mol)
PTHH: Zn + H2SO4 -> ZnSO4 + H2
Mol: 0,2 ---> 0,2 ---> 0,2 ---> 0,2
VH2 = 0,2 . 22,4 = 4,48 (l)
nCuO = 32/80 = 0,4 (mol)
PTHH: CuO + H2 -> (r°) Cu + H2O
LTL: 0,4 > 0,2 => CuO dư
nCuO (p/ư) = nCu = 0,2 (mol)
mCuO (dư) = (0,4 - 0,2) . 80 = 16 (g)
mCu = 0,2 . 64 = 12,8 (g)
%mCuO = 16/(16 + 12,8) = 55,55%
%mCu = 100% - 55,55 = 45,45%
`Zn + 2HCl -> ZnCl_2 + H_2`
`0,1` `0,2` `0,1` `(mol)`
`n_[Zn]=[6,5]/65=0,1(mol)`
`a)V_[H_2]=0,1.22,4=2,24(l)`
`b)C%_[HCl]=[0,2.36,5]/200 . 100 =3,65%`
`Zn + HCl -> ZnCl_2 + H_2` `\uparrow`
`n_(Zn) = (6,5)/65 = 0,1 mol`.
`n_(H_2) = 0,1 mol`.
`V(H_2) = 0,1 xx 22,4 = 2,24l`.
`C%(HCl) = (0,2.36,5)/200 xx 100 = 36,5%`.
a, \(n_{Zn}=\dfrac{6,5}{65}=0,1\left(mol\right)\)
PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
____0,1_____0,2______0,1_____0,1 (mol)
\(V_{H_2}=0,1.24,79=2,479\left(l\right)\)
\(m_{ZnCl_2}=0,1.136=13,6\left(g\right)\)
b, \(C_{M_{HCl}}=\dfrac{0,2}{0,1}=1\left(M\right)\)
c, \(n_{CuO}=\dfrac{12}{80}=0,15\left(mol\right)\)
PT: \(CuO+H_2\underrightarrow{t^o}Cu+H_2O\)
Xét tỉ lệ: \(\dfrac{0,15}{1}>\dfrac{0,1}{1}\), ta được CuO dư.
Theo PT: \(n_{CuO\left(pư\right)}=n_{Cu}=n_{H_2}=0,1\left(mol\right)\Rightarrow n_{CuO\left(dư\right)}=0,05\left(mol\right)\)
⇒ m chất rắn = mCuO (dư) + mCu = 0,05.80 + 0,1.64 = 10,4 (g)
a) Zn + 2HCl --> ZnCl2 + H2
b) \(n_{H_2}=\dfrac{6,1975}{24,79}=0,25\left(mol\right)\)
PTHH: Zn + 2HCl --> ZnCl2 + H2
0,25<-0,5<---0,25<--0,25
=> mZn = 0,25.65 = 16,25 (g)
c) mZnCl2 = 0,25.136 = 34 (g)
\(m_{HCl}=50.7,3\%=3,65\left(g\right)\\ n_{HCl}=\dfrac{3,65}{36,5}=0,1\left(mol\right)\\ PTHH:Zn+2HCl\rightarrow ZnCl_2+H_2\\ n_{Zn}=n_{H_2}=n_{ZnCl_2}=\dfrac{1}{2}n_{HCl}=\dfrac{1}{2}.0,1=0,05\left(mol\right)\\ m_{Zn}=0,05.65=3,25\left(g\right)\\ V_{H_2\left(ĐKTC\right)}=0,05.22,4=1,12\left(l\right)\\ m_{ZnCl_2}=0,05.136=6,8\left(g\right)\)
mHCl=50.7,3%=3,65(g) -> nHCl=0,1(mol)
a) PTHH: Zn + 2 HCl -> ZnCl2 + H2
nH2=nZnCl2=nZn=nHCl/2= 0,1/2=0,05(mol)
b) m=mZn=0,05.65=3,25(g)
c) V(H2,đktc)=0,05.22,4=1,12(l)
d) mZnCl2= 136.0,05= 7,8(g)
\(n_{Al}=\dfrac{5.4}{27}=0.2\left(mol\right)\)
\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
\(0.2.........................0.2.......0.3\)
\(m_{AlCl_3}=0.2\cdot133.5=26.7\left(g\right)\)
\(n_{CuO}=\dfrac{32}{160}=0.2\left(mol\right)\)
\(CuO+H_2\underrightarrow{^{t^0}}Cu+H_2O\)
\(1..........1\)
\(0.2........0.3\)
\(LTL:\dfrac{0.2}{1}< \dfrac{0.3}{1}\Rightarrow H_2dư\)
\(n_{Cu}=0.2\left(mol\right)\)
\(m_{Cu}=0.2\cdot64=12.8\left(g\right)\)
Em xem lại đề vì chất rắn chỉ có Cu không có CuO nhé !
a)
$Zn + 2HCl \to ZnCl_2 + H_2$
$n_{ZnCl_2} = n_{Zn} = \dfrac{6,5}{65} = 0,1(mol)$
$m_{ZnCl_2} = 0,1.136 = 13,6(gam)$
b)
$n_{HCl} = 2n_{Zn} = 0,2(mol) \Rightarrow C_{M_{HCl}} = \dfrac{0,2}{0,1} = 2M$
c)
CuO + H_2 \to Cu + H_2O$
$n_{CuO} = 0,125(mol) > n_{H_2} \to $ CuO$ dư
$n_{Cu} = n_{CuO\ pư} = n_{H_2} = 0,1(mol)$
$n_{CuO\ dư} = 0,125 - 0,1 = 0,025(mol)$
$\%m_{Cu} = \dfrac{0,1.64}{0,1.64 + 0,025.80}.100\% = 76,2\%$
$\%m_{CuO} = 23,8\%$
)
Zn+2HCl→ZnCl2+H2Zn+2HCl→ZnCl2+H2
nZnCl2=nZn=6,565=0,1(mol)nZnCl2=nZn=6,565=0,1(mol)
mZnCl2=0,1.136=13,6(gam)mZnCl2=0,1.136=13,6(gam)
b)
nHCl=2nZn=0,2(mol)⇒CMHCl=0,20,1=2MnHCl=2nZn=0,2(mol)⇒CMHCl=0,20,1=2M
c)
CuO + H_2 \to Cu + H_2O$
nCuO=0,125(mol)>nH2→nCuO=0,125(mol)>nH2→ CuO$ dư
nCu=nCuO pư=nH2=0,1(mol)nCu=nCuO pư=nH2=0,1(mol)
nCuO dư=0,125−0,1=0,025(mol)nCuO dư=0,125−0,1=0,025(mol)
%mCu=0,1.640,1.64+0,025.80.100%=76,2%%mCu=0,1.640,1.64+0,025.80.100%=76,2%
%mCuO=23,8%