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a, PT: \(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
b, Ta có: \(n_{Fe}=\dfrac{19,6}{56}=0,35\left(mol\right)\)
Theo PT: \(n_{H_2}=n_{Fe}=0,35\left(mol\right)\Rightarrow V_{H_2}=0,35.22,4=7,84\left(l\right)\)
c, \(n_{H_2SO_4}=n_{Fe}=0,35\left(mol\right)\Rightarrow C_{M_{H_2SO_4}}=\dfrac{0,35}{0,2}=1,75\left(M\right)\)
d, \(n_{FeSO_4}=n_{Fe}=0,35\left(mol\right)\Rightarrow m_{FeSO_4}=0,35.152=53,2\left(g\right)\)
e, \(C_{M_{FeSO_4}}=\dfrac{0,35}{0,2}=1,75\left(M\right)\)
d, \(n_{H_2SO_4}=0,25.1,6=0,4\left(mol\right)\)
Xét tỉ lệ: \(\dfrac{n_{Fe}}{1}< \dfrac{n_{H_2SO_4}}{1}\), ta được H2SO4 dư.
Theo PT: \(n_{H_2SO_4\left(pư\right)}=n_{Fe}=0,35\left(mol\right)\)
\(\Rightarrow n_{H_2SO_4\left(dư\right)}=0,4-0,35=0,05\left(mol\right)\)
\(\Rightarrow m_{H_2SO_4\left(dư\right)}=0,05.98=4,9\left(g\right)\)
\(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\uparrow\\ n_{H_2}=\dfrac{1,12}{22,4}=0,05\left(mol\right)\\ n_{Zn}=n_{H_2SO_4}=n_{H_2}=0,05\left(mol\right)\\ m_{Zn}=0,05.65=3,25\left(g\right)\\ m_{\text{dd}H_2SO_4}=\dfrac{0,05.98}{19,6\%}=25\left(g\right)\\ V_{\text{dd}H_2SO_4}=\dfrac{25}{1,84}\approx13,587\left(ml\right)\)
a, \(Zn+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Zn+H_2\)
Bạn bổ sung thêm số liệu của khí thoát ra nhé.
a)\(n_{Fe}=\dfrac{14}{56}=0,25\left(mol\right)\)
PTHH: Fe + 2HCl → FeCl2 + H2
Mol: 0,25 0,5 0,25
b) \(C_{M_{ddHCl}}=\dfrac{0,5}{0,5}=1M\)
c) \(V_{H_2}=0,25.22,4=5,6\left(l\right)\)
\(a,Zn+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Zn+H_2\\ n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\\ b,n_{CH_3COOH}=2.0,2=0,4\left(mol\right)\\ C_{MddCH_3COOH}=\dfrac{0,4}{0,4}=1\left(M\right)\\ c,CH_3COOH+KOH\rightarrow CH_3COOK+H_2O\\ n_{CH_3COOK}=n_{CH_3COOH}=0,4\left(mol\right)\\ V_{ddCH_3COOK}=400+400=800\left(ml\right)=0,8\left(l\right)\\ C_{MddCH_3COOK}=\dfrac{0,4}{0,8}=0,5\left(M\right)\)
\(Zn+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Zn+H_2\uparrow\)
0,4 0,2
\(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
\(b,C_{M_{CH_3COOH}}=\dfrac{0,4}{0,4}=1M\)
\(c,CH_3COOH+KOH\rightarrow CH_3COOK+H_2O\)
0,4 0,4 0,4
\(C_{M_{CH_3COOK}}=\dfrac{0,4}{0,4}=1M\)
\(n_{Zn}=\dfrac{3,25}{65}=0,05\left(mol\right)\)
\(Zn+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Zn+H_2\)
0,05 0,1 0,05 0,05 ( mol )
\(V_{H_2}=0,05.22,4=1,12\left(l\right)\)
\(m_{dd_{CH_3COOH}}=\dfrac{0,1.60.100}{20}=30\left(g\right)\)
\(m_{ddspứ}=3,25+30-0,05.2=33,15\left(g\right)\)
\(C\%_{\left(CH_3COO\right)_2Zn}=\dfrac{0,05.183}{33,15}.100=27,6\%\)
a)
\(PTHH:Fe+2HCl\rightarrow FeCl_2+H_2\)
b)
\(n_{Fe}=\dfrac{5,6}{56}=0,1mol\)
Theo PT:\(n_{HCl}=2n_{Fe}=0,2mol\)
\(\Rightarrow C_MHCl=\dfrac{0,2}{0,2}=1M\)
c)
Theo PT:\(n_{H_2}=n_{Fe}=0,1mol\)
\(\Rightarrow V_{H_2}=0,1.22,4=2,24l\)
\(a) Zn + 2CH_3COOH \to (CH_3COO)_2Zn + H_2\\ b) n_{H_2} = n_{Zn} =\dfrac{13}{65} = 0,2(mol)\\ V_{H_2} = 0,2.22,4 = 4,48(lít)\\ c) n_{CH_3COOH} = 2n_{Zn} = 0,4(mol)\\ V_{dd\ CH_3COOH} = \dfrac{0,4}{0,6} = 0,667(lít)\)
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