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a)
$2K + 2H_2O \to 2KOH + H_2$
$BaO + H_2O \to Ba(OH)_2$
Theo PTHH :
$n_K = 2n_{H_2} = 0,2(mol)$
$\%m_K = \dfrac{0,2.39}{23,1}.100\% = 33,77\%$
$\%m_{BaO} = 100\%- 33,77\% = 66,23\%$
b)
$n_{BaO} = \dfrac{23,1 - 0,2.39}{153} = 0,1(mol)$
$m_{dd} = 23,1 + 177,1 - 0,1.2 = 200(gam)$
$C\%_{KOH} = \dfrac{0,2.56}{200}.100\% = 5,6\%$
$C\%_{Ba(OH)_2} = \dfrac{0,1.171}{200}.100\% = 8,55\%$
c)
$KOH + HCl \to KCl + H_2O$
$Ba(OH)_2 + 2HCl \to BaCl_2 + 2H_2O$
$n_{HCl} = 2n_{Ba(OH)_2} + n_{KOH} = 0,4(mol)$
$V = \dfrac{0,4}{0,5} = 0,8(lít) = 800(ml)$
a) PTHH: \(K_2O+H_2O\rightarrow2KOH\)
Ta có: \(n_{KOH}=2n_{K_2O}=2\cdot\dfrac{35,25}{94}=0,75\left(mol\right)\)
\(\Rightarrow C_{M_{KOH}}=\dfrac{0,75}{0,75}=1\left(M\right)\)
b) Ta có: \(\left\{{}\begin{matrix}n_{KOH}=0,75\left(mol\right)\\n_{CO_2}=\dfrac{8,4}{22,4}=0,375\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\) Tạo muối trung hòa
PTHH: \(CO_2+2KOH\rightarrow K_2CO_3+H_2O\)
Theo PTHH: \(n_{K_2CO_3}=0,375\left(mol\right)\) \(\Rightarrow m_{K_2CO_3}=0,375\cdot138=51,75\left(g\right)\)
c) PTHH: \(2KOH+H_2SO_4\rightarrow K_2SO_4+2H_2O\)
Theo PTHH: \(n_{H_2SO_4}=0,375\left(mol\right)\)
\(\Rightarrow m_{ddH_2SO_4}=\dfrac{0,375\cdot98}{60\%}=61,25\left(g\right)\) \(\Rightarrow V_{ddH_2SO_4}=\dfrac{61,25}{1,5}\approx40,83\left(ml\right)\)
a) - Dung dịch A chứa chất tan NaOH
mddNaOH= 200(g)
=> C%ddNaOH= (4/200).100=2%
\(a,n_{Fe}=\dfrac{11,2}{56}=0,2(mol)\\ PTHH:Fe+2HCl\to FeCl_2+H_2\\ \Rightarrow n_{HCl}=0,4(mol)\\ \Rightarrow m_{dd_{HCl}}=\dfrac{0,4.36,5}{14,6\%}=100(g)\\ b,n_{H_2}=0,2(mol)\\ \Rightarrow V_{H_2}=0,2.22,4=4,48(l)\\ c,n_{FeCl_2}=0,2(mol)\\ \Rightarrow C\%_{FeCl_2}=\dfrac{0,2.127}{11,2+100-0,2.2}.100\%\approx 22,93\%\)
a, \(n_{K_2O}=\dfrac{4,7}{94}=0,05\left(mol\right)\)
PTHH: K2O + H2O → 2KOH
Mol: 0,05 0,1
b) \(C_{M_{ddKOH}}=\dfrac{0,1}{0,02}=5M\)
c)
PTHH: KOH + HCl → KCl + H2O
Mol: 0,1 0,1 0,1
\(m_{ddHCl}=\dfrac{0,1.36,5.100}{20}=18,25\left(g\right)\)
\(\Rightarrow V_{ddHCl}=\dfrac{18,25}{0,9125}=103,9\left(ml\right)=0,1039\left(l\right)\)
d) \(C_{M_{ddKCl}}=\dfrac{0,1}{0,02+0,1039}=0,8071M\)
Ta có: \(n_{SO_3}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\)
\(a,PTHH:SO_3+H_2O--->H_2SO_4\left(1\right)\)
Ta lại có: \(m_{dd_A}=0,25.80+100=120\left(g\right)\)
Theo PT(1): \(n_{H_2SO_4}=n_{SO_3}=0,25\left(mol\right)\)
\(\Rightarrow m_{H_2SO_4}=0,25.98=24,5\left(g\right)\)
\(\Rightarrow C_{\%_A}=\dfrac{24,5}{120}.100\%=20,42\%\)
\(b.PTHH:2KOH+H_2SO_4--->K_2SO_4+2H_2O\left(2\right)\)
Theo PT(2): \(n_{KOH}=2.n_{H_2SO_4}=2.0,25=0,5\left(mol\right)\)
\(\Rightarrow V_{dd_{KOH}}=\dfrac{0,5}{2}=0,25\left(lít\right)\)
tk
Ta có: nSO3=5,622,4=0,25(mol)nSO3=5,622,4=0,25(mol)
a,PTHH:SO3+H2O−−−>H2SO4(1)a,PTHH:SO3+H2O−−−>H2SO4(1)
Ta lại có: mddA=0,25.80+100=120(g)mddA=0,25.80+100=120(g)
Theo PT(1): nH2SO4=nSO3=0,25(mol)nH2SO4=nSO3=0,25(mol)
⇒mH2SO