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$n_{Na} = \dfrac{4,6}{23} = 0,2(mol)$
$2Na + 2H_2O \to 2NaOH + H_2$
$n_{H_2} = \dfrac{1}{2}n_{Na} = 0,1(mol)$
$n_{NaOH} = n_{Na} = 0,2(mol)$
Sau phản ứng :
$m_{dd} = 4,6 + 120,6 - 0,1.2 = 125(gam)$
$C\%_{NaOH} = \dfrac{0,2.40}{125}.100\% =6,4\%$
2Na+ 2H2O→ 2NaOH+ H2
(mol) 0,2 0,2 0,2 0,1 nNa=\(\dfrac{m}{M}=\dfrac{4,6}{23}=0,2\)(mol)
\(n_{H_2O}=\dfrac{m}{M}=\dfrac{120,6}{18}=6,7\)(mol)
Xét tỉ lệ:
Na H2O
\(\dfrac{0,2}{2}\) < \(\dfrac{6,7}{2}\)
=> Na phản ứng hết, nước dư
\(m_{H_2}\)=n.M=0,1.2=0,2(g)
mdd sau phản ứng = mNa+ \(m_{H_2O}\)-\(m_{H_2}\)
= 4,6 +120,6 -0,2= 125(g)
mNaOH=n.M= 0,2.40=8(g)
C%NaOH=\(\dfrac{8}{125}.100\%=0,064\%\)
\(m_{ddA}=m_{NaOH}+m_{H_2O}=2+120=122\left(g\right)\)
\(C\%_{ddA}=\dfrac{2}{122}.100\simeq1,639\%\)
\(Na+HCl \to NaCl+\frac{1}{2}H_2\\ n_{Na}=2n_{H_2}=2.0,4=0,8(mol)\\ m_{Na}=0,8.23=18,4(g)\)
nNa=4,6/23=0,2(mol)
PTHH: Na + H2O -> NaOH + 1/2 H2
0,2_______________0,2____0,1(mol)
mddNaOH=4,6+100-0,1.2=104,4(g)
mNaOH=0,2.40=8(g)
=>C%ddNaOH= (8/104,4).100=7,663%
=> Chọn B (gần nhất)
a) - Dung dịch A chứa chất tan NaOH
mddNaOH= 200(g)
=> C%ddNaOH= (4/200).100=2%
Dd B chứa NaOH.
PT: \(NaOH+HCl\rightarrow NaCl+H_2O\)
Ta có: \(n_{NaCl}=\dfrac{4,68}{58,5}=0,08\left(mol\right)\)
Theo PT: \(n_{NaOH\left(80\left(g\right)dd\right)}=n_{NaCl}=0,08\left(mol\right)\)
\(\Rightarrow n_{NaOH\left(200\left(g\right)dd\right)}=\dfrac{0,08.200}{80}=0,2\left(mol\right)\)
PT: \(2Na+2H_2O\rightarrow2NaOH+H_2\)
\(Na_2O+H_2O\rightarrow2NaOH\)
Ta có: \(\left\{{}\begin{matrix}23n_{Na}+62n_{Na_2O}=5,4\\n_{Na}+2n_{Na_2O}=0,2\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}n_{Na}=0,1\left(mol\right)\\n_{Na_2O}=0,05\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow n_{H_2}=\dfrac{1}{2}n_{Na}=0,05\left(mol\right)\)
Ta có: m dd B = mA + mH2O - mH2
⇒ 200 = 5,4 + mH2O - 0,05.2
⇒ mH2O = 194,7 (g)
\(Na+H_2O \to NaOH + \frac{1}{2}H_2\\ n_{Na}=\frac{4,6}{23}=0,2(mol)\\ n_{NaOH}=n_{Na}=0,2(mol)\\ CM_{NaOH}=\frac{0,2}{0,1}=2M\)
\(2Na+2HCl\rightarrow 2NaCl+H_2\\ n_{Na}=\frac{5,75}{23}=0,25mol\\ n_{Na}=n_{HCl}=0,25mol\\ m_{HCl_{dd}}=\frac{0,25.36,5.100}{18,25}=50g\)
Na2O+H2O->2NaOH
0,2----------------0,4 mol
2NaOH+CO2->Na2CO3+H2O
0,4--------0,2
n Na2O=12,4\62=0,2 mol
=>C% NaOH=0,4.40\12,4+120 .100=3 %
=>m CO2=0,2.44=8,8g
\(n_{Na}=\dfrac{4,6}{23}=0,2\left(mol\right)\)
PTHH: 2Na + 2H2O → 2NaOH + H2
Mol: 0,2 0,2 0,1
mdd sau pứ = 4,6 + 120 - 0,2.2 = 124,2 (g)
\(C\%_{ddNaOH}=\dfrac{0,2.40.100\%}{124,2}=6,44\%\)
\(m_{ddA}=m_{Na}+m_{H_2O}=4,6+120=124,6\left(g\right)\)
\(C\%_{ddA}=\dfrac{4,6}{124,6}.100\simeq3,692\%\)