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PTHH:
\(Zn+H_2SO_4--->ZnSO_4+H_2\)
\(Cu+H_2SO_4--\times-->\)
a. Ta có: \(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
Theo PT: \(n_{Zn}=n_{H_2}=0,1\left(mol\right)\)
\(\Rightarrow m_{Zn}=0,1.65=6,5\left(g\right)\)
\(\Rightarrow\%_{m_{Zn}}=\dfrac{6,5}{19,3}.100\%=33,7\%\)
\(\%_{m_{Cu}}=100\%-33,7\%=66,3\%\)
b. Theo PT: \(n_{H_2SO_4}=n_{Zn}=0,1\left(mol\right)\)
Đổi 200ml = 0,2 lít
\(\Rightarrow C_{M_{H_2SO_4}}=\dfrac{0,1}{0,2}=0,5M\)
c. Ta có: \(V_{dd_{ZnSO_4}}=V_{dd_{H_2SO_4}}=0,2\left(lít\right)\)
Theo PT: \(n_{ZnSO_4}=n_{Zn}=0,1\left(mol\right)\)
\(\Rightarrow C_{M_{ZnSO_4}}=\dfrac{0,1}{0,2}=0,5M\)
Gọi x, y lần lượt là sô mol của Fe và Mg
Ta có: \(n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
PTHH:
Fe + H2SO4 ---> FeSO4 + H2 (1)
Mg + H2SO4 ---> MgSO4 + H2 (2)
a. Theo PT(1): \(n_{H_2}=n_{Fe}=x\left(mol\right)\)
Theo PT(2): \(n_{H_2}=n_{Mg}=y\left(mol\right)\)
\(\Rightarrow x+y=0,3\) (*)
Theo đề, ta có: 56x + 24y = 10.4 (**)
Từ (*) và (**), ta có HPT:
\(\left\{{}\begin{matrix}x+y=0,3\\56x+24y=10,4\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,1\\y=0,2\end{matrix}\right.\)
\(\Rightarrow m_{Fe}=0,1.56=5,6\left(g\right);m_{Mg}=0,2.24=4,8\left(g\right)\)
b. Ta có: \(n_{hh}=0,1+0,2=0,3\left(mol\right)\)
Theo PT(1,2): \(n_{H_2SO_4}=n_{hh}=0,3\left(mol\right)\)
Đổi 200ml = 0,2 lít
\(\Rightarrow C_{M_{H_2SO_4}}=\dfrac{0,3}{0,2}=1,5M\)
$a\big)$
$Zn+2CH_3COOH\to (CH_3COO)_2Zn+H_2$
$ZnO+2CH_3COOH\to (CH_2COO)_2Zn+H_2O$
Theo PT: $n_{Zn}=n_{H_2}=\frac{4,48}{22,4}=0,2(mol)$
$\to \%m_{Zn}=\frac{0,2.65}{21,1}.100\%\approx 61,61\%$
$\to \%m_{ZnO}=100-61,61=38,39\%$
$b\big)$
$n_{ZnO}=\frac{21,1-0,2.65}{81}=0,1(mol)$
Theo PT: $\sum n_{CH_3COOH}=2n_{Zn}+2n_{ZnO}=0,6(mol)$
$\to C_{M_{CH_3COOH}}=\dfrac{0,6}{\frac{200}{1000}}=3M$
\(n_{H_2}=\dfrac{4,48}{22,4}=0,2mol\)
\(Zn+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Zn+H_2\)
0,2 0,2 ( mol )
\(m_{Zn}=0,2.65=13g\)
\(\%m_{Zn}=\dfrac{13}{21,1}.100=61,61\%\)
\(\%m_{ZnO}=100\%-61,61\%=38,39\%\)
\(Zn+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Zn+H_2\)
0,2 0,4 ( mol )
\(n_{ZnO}=\dfrac{21,1-13}{81}=0,1mol\)
\(ZnO+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Zn+H_2O\)
0,1 0,2 ( mol )
\(C_{M\left(CH_3COOH\right)}=\dfrac{0,4+0,2}{0,2}=3M\)
PTHH\(Na_2CO_3+2HCl\rightarrow2NaCl+H_2O+CO_2\)
tl............1................2.............2.............1.............1..(mol
br 0,1.................0,2......................................0,1(mol)
NaCl không phản ứng đc vsHCl
b)\(n_{CO_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
\(C_{MHCl}=\dfrac{0,2}{0,4}=0,5\left(M\right)\)(đổi 400ml=0,4(l))
c)\(Tacom_{Na_2CO_3}=0,1.106=10,6\left(g\right)\)
\(\Rightarrow\%m_{Na_2CO_3}=\dfrac{10,6}{20}.100=53\%\)
\(\Rightarrow\%mNaCl=100\%-53\%=47\%\)
a) PTHH: \(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)
a_____2a______a_____a (mol)
\(2Al+6HCl\rightarrow2AlCl_3+3H_2\uparrow\)
b_____3b_______b_____\(\dfrac{3}{2}\)b (mol)
Ta lập HPT: \(\left\{{}\begin{matrix}56a+27b=36,1\\a+\dfrac{3}{2}b=\dfrac{21,28}{22,4}=0,95\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}a=0,5\\b=0,3\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}m_{Fe}=0,5\cdot56=28\left(g\right)\\m_{Al}=8,1\left(g\right)\end{matrix}\right.\)
b+c) Theo các PTHH: \(\left\{{}\begin{matrix}n_{HCl}=2a+3b=1,9\left(mol\right)\\n_{FeCl_2}=0,5\left(mol\right)\\n_{AlCl_3}=0,3\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}C_{M_{HCl}}=\dfrac{1,9}{0,2}=9,5\left(M\right)\\C_{M_{FeCl_2}}=\dfrac{0,5}{0,2}=2,5\left(M\right)\\C_{M_{AlCl_3}}=\dfrac{0,3}{0,2}=1,5\left(M\right)\end{matrix}\right.\)
a
\(Mg+2HCl\rightarrow MgCl_2+H_2\)
0,15<-0,15<--0,15<----0,15
\(MgO+2HCl\rightarrow MgCl_2+H_2O\)
0,16-->0,32---->0,16
\(n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
\(m_{Mg}=0,15.24=3,6\left(g\right)\\ m_{MgO}=10-3,6=6,4\left(g\right)\)
b
\(\%m_{Mg}=\dfrac{3,6.100\%}{10}=36\%\\ \%m_{MgO}=\dfrac{6,4.100\%}{10}=64\%\)
c
\(n_{MgO}=\dfrac{6,4}{40}=0,16\left(mol\right)\)
\(CM_{HCl}=\dfrac{0,15+0,32}{0,2}=2,35M\)
d
\(m_{MgCl_2}=\left(0,15+0,16\right).95=29,45\left(g\right)\)
e
\(CM_{MgCl_2}=\dfrac{0,15+0,16}{0,2}=1,55M\)
Đáp án:
Giải thích các bước giải:
a,PTHH:Na2CO3+2HCl→2NaCl+H2O+CO2a,PTHH:Na2CO3+2HCl→2NaCl+H2O+CO2
nCO2=1,1222,4=0,05(mol)nCO2=1,1222,4=0,05(mol)
→mNa2CO3=0,05.106=5,3(g)→mNa2CO3=0,05.106=5,3(g)
mNa2SO4=10−5,3=4,7(g)mNa2SO4=10−5,3=4,7(g)
b, Đổi 200ml = 0,2l
→CMHCl=0,20,1=2M