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Cu + H2O
a. PTHH: CuO + H2 ---to---> Cu + H2O (1)
Fe2O3 + 3H2 ---to---> 2Fe + 3H2O (2)
Ta có: \(m_{hh}=62,4\left(g\right)\)
=> \(m_{Fe}=62,4-12,8=49,6\left(g\right)\)
b. Theo PT(1): \(n_{H_2}=n_{Cu}=\dfrac{12,8}{64}=0,2\left(mol\right)\)
Theo PT(2):\(n_{H_2}=3.n_{Fe}=3.\dfrac{49,6}{56}\approx2,7\left(mol\right)\)
=> \(n_{H_{2_{\left(2PT\right)}}}=0,2+2,7=2,9\left(mol\right)\)
=> \(V_{H_2}=2,9.22,4=64,96\left(lít\right)\)
a) \(m_{CuO}=\dfrac{20.40}{100}=8\left(g\right)\) => \(n_{CuO}=\dfrac{8}{80}=0,1\left(mol\right)\)
\(m_{Fe_2O_3}=20-8=12\left(g\right)\) => \(n_{Fe_2O_3}=\dfrac{12}{160}=0,075\left(mol\right)\)
PTHH: CuO + H2 --to--> Cu + H2O
0,1--->0,1------>0,1
Fe2O3 + 3H2 --to--> 2Fe + 3H2O
0,075--->0,225----->0,15
=> mCu = 0,1.64 = 6,4 (g)
=> mFe = 0,15.56 = 8,4 (g)
b) \(V_{H_2}=\left(0,1+0,225\right).22,4=7,28\left(l\right)\)
\(Fe_2O_3+3H_2\rightarrow\left(t^o\right)2Fe+3H_2O\\ CuO+H_2\rightarrow\left(t^o\right)Cu+H_2O\\ Đặt:n_{Fe}=a\left(mol\right);n_{Cu}=0,5a\left(mol\right)\\ m_{hhB}=17,6\\ \Leftrightarrow56a+64.0,5a=17,6\\ \Leftrightarrow a=0,2\left(mol\right)\\ \Rightarrow n_{Fe}=0,2\left(mol\right);n_{Cu}=0,1\left(mol\right)\\ a,n_{H_2}=\dfrac{3}{2}.n_{Fe}+n_{Cu}=\dfrac{3}{2}.0,2+0,1=0,4\left(mol\right)\\ \Rightarrow V_{H_2\left(đktc\right)}=0,4.22,4=8,96\left(l\right)\\ b,Fe+2HCl\rightarrow FeCl_2+H_2\\ n_{HCl}=\dfrac{18,25}{36,5}=0,5\left(mol\right)\\ Vì:\dfrac{0,2}{1}< \dfrac{0,5}{2}\Rightarrow HCldư\\ \Rightarrow ddC:FeCl_2,HCldư\\ n_{FeCl_2}=n_{Fe}=0,2\left(mol\right)\Rightarrow m_{FeCl_2}=0,2.127=25,4\left(g\right)\\ n_{HCl\left(dư\right)}=0,5-0,2.2=0,1\left(mol\right)\)
\(\Rightarrow m_{HCl\left(dư\right)}=0,1.36,5=3,65\left(g\right)\)
a, mFe2O3 = 32 . 75% = 24 (g)
nFe2O3 = 24/160 = 0,15 (mol)
mCuO = 32 - 24 = 8 (g)
nCuO = 8/80 = 0,1 (mol)
PTHH:
Fe2O3 + 3H2 -> (t°) 2Fe + 3H2O
0,15 ---> 0,45 ---> 0,3
CuO + H2 -> (t°) Cu + H2O
0,1 ---> 0,1 ---> 0,1
mFe = 0,3 . 56 = 16,8 (g)
mCu = 64 . 0,1 = 6,4 (g)
b, nH2 = 0,1 + 0,45 = 0,55 (mol)
VH2 = 0,55 . 22,4 = 12,32 (l)
c, PTHH:
2Al + 6HCl -> 2AlCl3 + 3H2
11/30 <--- 1,1 <--- 11/30 <--- 0,55
mAl = 11/30 . 27 = 9,9 (g)
mHCl = 1,1 . 36,5 = 40,15 (g)
\(a)Gọi : n_{CuO} = x(mol) \Rightarrow n_{Fe_2O_3} = \dfrac{80a.2}{160}=x(mol)\\ CuO + H_2 \xrightarrow{t^o} Cu + H_2O\\ Fe_2O_3 + 3H_2 \xrightarrow{t^o} 2Fe + H_2O\\ n_{H_2} = x + x = \dfrac{8,96}{22,4} = 0,4(mol)\Rightarrow x = 0,2\\ a = 0,2.80 + 0,2.160 = 48(gam)\\ b)\\ n_{Fe} = 2n_{Fe_2O_3} = 0,4(mol) \Rightarrow m_{Fe} = 0,4.56 = 22,4(gam)\\ n_{Cu} = n_{CuO} = 0,2(mol) \Rightarrow m_{Cu} = 0,2.64 = 12,8(gam)\)
\(\left[O\right]_{KL}+H_2->H_2O\\ n_{H_2O}=n_{H_2}=\dfrac{14,4}{18}=0,8mol\\ v=0,8.22,4=17,92L\\ m_{KL}=m=47,2-16.0,8=34,4g\)
Bài 11:
\(a,n_{Fe_2O_3}=\dfrac{1,6}{160}=0,01\left(mol\right)\\ n_{Cu}=\dfrac{4}{80}=0,05\left(mol\right)\\ PTHH:\\ Fe_2O_3+3H_2\underrightarrow{t^o}2Fe+3H_2O\)
0,01 -----> 0,03 ---> 0,02
\(CuO+H_2\underrightarrow{t^o}Cu+H_2O\)
0,05 ---> 0,05 -> 0,05
\(b,m_{Fe}=0,02.56=1,12\left(g\right)\\ m_{Cu}=0,05.64=3,2\left(g\right)\\ V_{H_2}=\left(0,03+0,05\right).22,4=1,792\left(l\right)\)
Bài 12:
\(n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\\ n_{O\left(trong.oxit\right)}=n_{H_2}=0,15\left(mol\right)\\ n_{Fe\left(trong.oxit\right)}=\dfrac{8-0,15,16}{56}=0,1\left(mol\right)\\ CTHH:Fe_xO_y\\ \Rightarrow x:y=0,1:0,15=2:3\\ CTHH:Fe_2O_3\)
CuO+H2-to>Cu+H2O
0,3-------0,3-----0,3
Fe2O3+3H2-tO>2Fe+3H2O
0,3------0,2
n Fe=0,2 mol
n Cu=0,3 mol
=>VH2=0,3.2,22.4=13,44l
nFe = 11,2 : 56 = 0,2 (mol)
nCu = 19,2 : 64 = 0,3 (mol)
pthh Fe2O3 +3H2 -t-> 2Fe + 3H2O
0,3<----0, 2 (mol)
CuO + H2 --t--> Cu +H2O
0,3<------0,3 (mol)
nH2 = 0,3 + 0,3 = 0,6 (mol)
=> VH2 = 0,6 . 22,4 = 13,44 (l)