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a, PT: \(CuO+H_2\underrightarrow{t^o}Cu+H_2O\)
\(Fe_2O_3+3H_2\underrightarrow{t^o}2Fe+3H_2O\)
b, Ta có: \(m_{Fe_2O_3}=50.80\%=40\left(g\right)\Rightarrow n_{Fe_2O_3}=\dfrac{40}{160}=0,25\left(mol\right)\)
\(\Rightarrow m_{CuO}=10\left(g\right)\Rightarrow n_{CuO}=\dfrac{10}{80}=0,125\left(mol\right)\)
Theo PT: \(\left\{{}\begin{matrix}n_{Cu}=n_{CuO}=0,125\left(mol\right)\\n_{Fe}=2n_{Fe_2O_3}=0,5\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}m_{Cu}=0,125.64=8\left(g\right)\\m_{Fe}=0,5.56=28\left(g\right)\end{matrix}\right.\)
b, Theo PT: \(n_{H_2}=n_{CuO}+3n_{Fe_2O_3}=0,875\left(mol\right)\)
\(\Rightarrow V_{H_2}=0,875.22,4=19,6\left(l\right)\)
Bạn tham khảo nhé!
a.b.
\(\left\{{}\begin{matrix}n_{Fe_2O_3}=40.80\%=32g\\m_{CuO}=40-32=8g\end{matrix}\right.\)
\(\left\{{}\begin{matrix}n_{Fe_2O_3}=\dfrac{32}{160}=0,2mol\\n_{CuO}=\dfrac{8}{80}=0,1mol\end{matrix}\right.\)
\(CuO+H_2\rightarrow\left(t^o\right)Cu+H_2O\)
0,1 0,1 0,1 ( mol )
\(Fe_2O_3+3H_2\rightarrow\left(t^o\right)2Fe+3H_2O\)
0,2 0,6 0,4 ( mol )
\(V_{H_2}=\left(0,1+0,6\right).22,4=15,68l\)
\(\left\{{}\begin{matrix}m_{Cu}=0,1.64=6,4g\\m_{Fe}=0,4.56=22,4g\end{matrix}\right.\)
\(\rightarrow\left\{{}\begin{matrix}\%m_{Cu}=\dfrac{6,4}{6,4+22,4}.100=22,22\%\\\%m_{Fe}=100\%-22,22\%=77,78\%\end{matrix}\right.\)
c.
\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\) ( Cu không phản ứng với H2SO4 loãng )
0,4 0,4 ( mol )
\(V_{H_2}=0,4.22,4=8,96l\)
\(a,\\ Fe_2O_3+3H_2\rightarrow\left(t^o\right)2Fe+3H_2O\\ Fe_3O_4+4H_2\rightarrow\left(t^o\right)3Fe+4H_2O\)
Loại phản ứng: Phản ứng thế
\(b,n_{Fe}=2.n_{Fe_2O_3}+3.n_{Fe_3O_4}=2.\dfrac{32}{160}+3.0,15=0,85\left(mol\right)\\ m_{Fe}=0,85.56=47,6\left(g\right)\\ c,n_{H_2}=\dfrac{32}{160}.3+4.0,15=1,2\left(mol\right)\\ V_{H_2\left(đktc\right)}=1,2.22,4=28\left(l\right)\)
Em xem sao oxit sắt lại hỏi KL nhôm nha! Vô lí!!!
a) \(m_{CuO}=\dfrac{20.40}{100}=8\left(g\right)\) => \(n_{CuO}=\dfrac{8}{80}=0,1\left(mol\right)\)
\(m_{Fe_2O_3}=20-8=12\left(g\right)\) => \(n_{Fe_2O_3}=\dfrac{12}{160}=0,075\left(mol\right)\)
PTHH: CuO + H2 --to--> Cu + H2O
0,1--->0,1------>0,1
Fe2O3 + 3H2 --to--> 2Fe + 3H2O
0,075--->0,225----->0,15
=> mCu = 0,1.64 = 6,4 (g)
=> mFe = 0,15.56 = 8,4 (g)
b) \(V_{H_2}=\left(0,1+0,225\right).22,4=7,28\left(l\right)\)
a)
CuO + H2 --to--> Cu + H2O
Fe2O3 + 3H2 --to--> 2Fe + 3H2O
b) \(n_{Fe_2O_3}=\dfrac{32.20\%}{160}=0,04\left(mol\right)\)
\(n_{CuO}=\dfrac{32-0,04.160}{80}=0,32\left(mol\right)\)
PTHH: CuO + H2 --to--> Cu + H2O
0,32-->0,32---->0,32
Fe2O3 + 3H2 --to--> 2Fe + 3H2O
0,04-->0,12-------->0,08
=> VH2 = (0,32 + 0,12).22,4 = 9,856 (l)
c)
mCu = 0,32.64 = 20,48 (g)
mFe = 0,08.56 = 4,48 (g)
\(n_{CuO}=2a\left(mol\right)\Rightarrow n_{Fe_2O_3}=a\left(mol\right)\)
\(m_X=80\cdot2a+160a=80\left(g\right)\)
\(\Rightarrow a=0.25\left(mol\right)\)
\(CuO+H_2\underrightarrow{^{^{t^0}}}Cu+H_2O\)
\(Fe_2O_3+3H_2\underrightarrow{^{^{t^0}}}2Fe+3H_2O\)
\(n_{H_2}=0.5+0.25\cdot3=1.25\left(mol\right)\)
\(V_{H_2}=1.25\cdot22.4=28\left(l\right)\)
\(m_{cr}=0.5\cdot64+0.5\cdot56=60\left(g\right)\)
a)
\(m_{CuO}=\dfrac{32.40}{100}=12,8\left(g\right)\) => \(n_{CuO}=\dfrac{12,8}{80}=0,16\left(mol\right)\)
\(n_{Fe_2O_3}=\dfrac{32-12,8}{160}=0,12\left(mol\right)\)
PTHH: CuO + H2 --to--> Cu + H2O
0,16->0,16---->0,16
Fe2O3 + 3H2 --to--> 2Fe + 3H2O
0,12-->0,36----->0,24
=> \(V_{H_2}=\left(0,16+0,36\right).22,4=11,648\left(l\right)\)
b)
mCu = 0,16.64 =10,24 (g)
mFe = 0,24.56 = 13,44 (g)
c)
\(n_{HCl}=\dfrac{18,25}{36,5}=0,5\left(mol\right)\)
PTHH: Fe + 2HCl --> FeCl2 + H2
Xét tỉ lệ: \(\dfrac{0,24}{1}< \dfrac{0,5}{2}\) => HCl dư, Fe hết
PTHH: Fe + 2HCl --> FeCl2 + H2
0,24------------------->0,24
=> \(V_{H_2}=0,24.22,4=5,376\left(l\right)\)
Bài 1:
a) PTHH: \(Fe_2O_3+3H_2\xrightarrow[]{t^o}2Fe+2H_2O\)
\(CuO+H_2\xrightarrow[]{t^o}Cu+H_2O\)
b) Ta có: \(\left\{{}\begin{matrix}m_{Fe_2O_3}=20\cdot80\%=16\left(g\right)\\m_{CuO}=20-16=4\left(g\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}n_{Fe_2O_3}=\dfrac{16}{160}=0,1\left(mol\right)\\n_{CuO}=\dfrac{4}{80}=0,05\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow n_{H_2}=3n_{Fe_2O_3}+n_{CuO}=0,35\left(mol\right)\) \(\Rightarrow V_{H_2}=0,35\cdot22,4=7,84\left(l\right)\)
c) Theo các PTHH: \(\left\{{}\begin{matrix}n_{Fe}=2n_{Fe_2O_3}=0,2\left(mol\right)\\n_{Cu}=n_{CuO}=0,05\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow m_{hhB}=m_{Fe}+m_{Cu}=0,2\cdot56+0,05\cdot64=14,4\left(g\right)\)
Bài 2:
PTHH: \(Fe_2O_3+3H_2\xrightarrow[]{t^o}2Fe+3H_2O\)
\(CuO+H_2\xrightarrow[]{t^o}Cu+H_2O\)
a) Vì khối lượng Cu bằng \(\dfrac{6}{5}\) khối lượng Fe
\(\Rightarrow\left\{{}\begin{matrix}m_{Cu}=\dfrac{26,4}{6+5}\cdot6=14,4\left(g\right)\\m_{Fe}=26,4-14,4=12\left(g\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}n_{Cu}=\dfrac{14,4}{64}=0,225\left(mol\right)\\n_{Fe}=\dfrac{12}{56}=\dfrac{3}{14}\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow n_{H_2}=\dfrac{3}{2}n_{Fe}+n_{Cu}=\dfrac{9}{28}+0,225=\dfrac{153}{280}\left(mol\right)\) \(\Rightarrow V_{H_2}=\dfrac{153}{280}\cdot22,4=12,24\left(l\right)\)
b) Theo các PTHH: \(\left\{{}\begin{matrix}n_{Fe_2O_3}=\dfrac{1}{2}n_{Fe}=\dfrac{3}{28}\left(mol\right)\\n_{CuO}=n_{Cu}=0,225\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}m_{Fe_2O_3}=\dfrac{3}{28}\cdot160\approx17,14\left(g\right)\\m_{CuO}=0,225\cdot80=18\left(g\right)\end{matrix}\right.\) \(\Rightarrow m_{hh}=35,14\left(g\right)\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Fe_2O_3}=\dfrac{17,14}{35,14}\cdot100\%\approx48,78\%\\\%m_{CuO}=51,22\%\end{matrix}\right.\)
Dùng H2 để khử 50g hỗn hợp CuO và Fe2O3,trong đó Fe2O3 chiếm 80% khối lượng hỗn hợp
A. Viết PTHH
B. Tính khối lượng mỗi kim loại thu được
C. Tính thể tích khí H2 cần dùng
----
a) mFe2O3= 80%.50=40(g)
=> nFe2O3= 40/160= 0,25(mol)
mCuO= 50-40=10(g)
=> nCuO= 10/80= 0,125(mol)
b) PTHH: Fe2O3 +3 H2 -to-> 2 Fe +3 H2O
0,25_________0,75_________0,5(mol)
CuO + H2 -to-> Cu + H2O
0,125__0,125___0,125(mol)
m(kim loại)= 0,5.56+0,125.64= 36(g)
c) V(H2,Đktc)= (0,75+0,125).22,4=19,6(l)
a)\(CuO+H2-->Cu+H2O\)
)\(Fe2O3+3H2-->2Fe+3H2O\)
b) \(m_{Fe2O3}=50.80\%=40\left(g\right)\)
\(m_{CuO}=50-40=10\left(g\right)\)
c)\(n_{Fe2O3}=\frac{40}{160}=0,25\left(mol\right)\)
\(n_{H2}=3n_{Fe2O3}=0,75\left(mol\right)\)
\(n_{CuO}=\frac{10}{80}=0,125\left(mol\right)\)
\(n_{H2}=n_{CuO}=0,125\left(mol\right)\)
\(\sum n_{H2}=0,125+0,75=0,875\left(mol\right)\)
\(V_{H2}=0,875.22,4=19,6\left(l\right)\)