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a, \(n_{C_2H_4}=\dfrac{15,68}{22,4}=0,7\left(mol\right)\)
PT: \(C_2H_4+H_2O\underrightarrow{^{t^o,xt}}C_2H_5OH\)
Theo PT: \(n_{C_2H_5OH\left(LT\right)}=n_{C_2H_4}=0,7\left(mol\right)\)
Mà: H = 90%
\(\Rightarrow n_{C_2H_5OH\left(TT\right)}=0,7.90\%=0,63\left(mol\right)\)
\(\Rightarrow m_{C_2H_5OH\left(TT\right)}=0,63.46=28,98\left(g\right)\)
\(\Rightarrow V_{C_2H_5OH}=\dfrac{28,98}{0,8}=36,225\left(ml\right)\)
b, \(C_2H_5OH+O_2\underrightarrow{^{mengiam}}CH_3COOH+H_2O\)
Theo PT: \(n_{CH_3COOH}=n_{C_2H_5OH}=0,63\left(mol\right)\)
\(\Rightarrow m_{CH_3COOH}=0,63.60=37,8\left(g\right)\)
\(\Rightarrow m_{ddCH_3COOH}=\dfrac{37,8}{5\%}=756\left(g\right)\)
\(n_{C_2H_4}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
PTHH: C2H4 + H2O \(\xrightarrow[Axit]{Men.rượu}\) C2H5OH
0,2 0,2
\(m_{C_2H_5OH}=0,2.46.80\%=7,36\left(g\right)\\ V_{C_2H_5OH}=\dfrac{7,36}{0,8}=9,2\left(ml\right)\)
\(n_{C_2H_4}=\dfrac{4,48}{22,4}=0,2mol\)
\(C_2H_4+H_2O\xrightarrow[axit]{lên.men}C_2H_5OH\)
0,2 0,2 ( mol )
\(m_{C_2H_5OH}=0,2.46.80\%=7,36g\)
\(C_{C_2H_5OH}=\dfrac{7,36}{0,8}=9,2ml\)
\(CH_3COOH+NaCl\rightarrow CH_3COONa+HCl\)
\(2CH_3COOH+CaCO_3\rightarrow\left(CH_3COO\right)_2Ca+H_2O+CO_2\)
2 1 1 1 1 (mol)
0,08 0,04 0,04 0,04 0,04 (mol)
\(nCO_2=\dfrac{0,896}{22,4}=0,04\left(mol\right)\)
\(mCaCO_3=0,04.100=4\left(g\right)\)
=> \(mNaCl=12,5-4=8,5\left(g\right)\)
( không thấy hh B )
c ) .
\(CO_2+2NaOH\rightarrow Na_2CO_3+H_2O\)
1 2 1 1 (mol)
0,04 0,08 0,04 0,04 (mol)
\(mNa_2CO_3=0,04.106=4,24\left(g\right)\)
\(mNa_2CO_{3\left(thựctế\right)}=\)\(\dfrac{4,24.85\%}{100\%}=3,604\left(g\right)\)
a, \(n_{CO_2}=\dfrac{0,56}{22,4}=0,025\left(mol\right)\)
PT: \(2CH_3COOH+Na_2CO_3\rightarrow2CH_3COONa+CO_2+H_2O\)
Theo PT: \(n_{CH_3COOH}=2n_{CO_2}=0,05\left(mol\right)\)
\(\Rightarrow C\%_{CH_3COOH}=\dfrac{0,05.60}{100}.100\%=3\%\)
b, Theo PT: \(n_{Na_2CO_3}=n_{CO_2}=0,025\left(mol\right)\Rightarrow m_{Na_2CO_3}=0,025.106=2,65\left(g\right)\)
\(n_{CH_3COONa}=2n_{CO_2}=0,05\left(mol\right)\Rightarrow m_{CH_3COONa}=0,05.82=4,1\left(g\right)\)
c, \(C_2H_5OH+O_2\underrightarrow{^{mengiam}}CH_3COOH+H_2O\)
Theo PT: \(n_{C_2H_5OH\left(LT\right)}=n_{CH_3COOH}=0,05\left(mol\right)\)
Mà: H = 80%
\(\Rightarrow n_{C_2H_5OH\left(TT\right)}=\dfrac{0,05}{80\%}=0,0625\left(mol\right)\)
\(\Rightarrow m_{C_2H_5OH\left(TT\right)}=0,0625.46=2,875\left(g\right)\)
\(\Rightarrow V_{C_2H_5OH}=\dfrac{2,875}{0,8}=3,59375\left(ml\right)\)
\(\Rightarrow V_{C_2H_5OH\left(10^o\right)}=\dfrac{3,59375}{10}.100=35,9375\left(ml\right)\)
a, \(n_{O_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
PT: \(C_2H_6O+3O_2\underrightarrow{t^o}2CO_2+3H_2O\)
Theo PT: \(n_{CO_2}=\dfrac{2}{3}n_{O_2}=\dfrac{2}{15}\left(mol\right)\Rightarrow V_{CO_2}=\dfrac{2}{15}.22,4=\dfrac{224}{75}\left(l\right)\)
b, \(n_{C_2H_6O\left(LT\right)}=\dfrac{1}{3}n_{O_2}=\dfrac{1}{15}\left(mol\right)\)
Mà: H = 90%
\(\Rightarrow n_{C_2H_6O\left(TT\right)}=\dfrac{\dfrac{1}{15}}{90\%}=\dfrac{2}{27}\left(mol\right)\)
\(\Rightarrow m_{C_2H_6O}=\dfrac{2}{27}.46=\dfrac{92}{27}\left(g\right)\)
nCH3COOH = 0.4 (mol)
CH3COOH + Na => CH3COONa + 1/2H2
0.4.................0.4.................................0.2
VH2 = 0.2 * 22.4 = 4.48 (l)
CH3COOH + NaOH => CH3COONa + H2O
0.4......................0.4
mddNaOH = 0.4*40*100/10 = 160 (g)
\(n_{C_2H_5OH}=\dfrac{34,5}{46}=0,75\left(mol\right)\)
PTHH: C2H5OH + 3O2 --to--> 2CO2 + 3H2O
0,75------------------->1,5
=> VCO2 = 1,5.22,4 = 33,6 (l)
PTHH: CH3COOH + C2H5OH --H2SO4(đặc), to--> CH3COOC2H5 + H2O
1,5-------------------------------->1,5
=> meste = 1,5.88 = 132 (g)
\(2C_2H_2+5O_2\rightarrow\left(t^o\right)4CO_2+2H_2O\\ n_{C_2H_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\\ n_{CO_2}=2.0,25=0,5\left(mol\right)\\ a,V_{CO_2\left(đktc\right)}=0,5.22,4=11,2\left(l\right)\\ b,n_{O_2}=\dfrac{5}{2}.0,25=0,625\left(mol\right)\\ V_{O_2\left(đktc\right)}=0,625.22,4=14\left(l\right)\\ V_{kk\left(đkct\right)}=\dfrac{100}{20}.14=70\left(lít\right)\)
\(n_{CO2}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\)
Pt : \(C_6H_{12}O_6\xrightarrow[30-35^oC]{Menrượu}2C_2H_5OH+2CO_2\)
0,5 0,5
a) \(m_{C2H5OH}=0,5.46=23\left(g\right)\)
b) Pt : \(C_2H_5OH+O_2\xrightarrow[]{Mengiấm}CH_3COOH+H_2O\)
0,5 0,5
\(m_{CH3COOH\left(lt\right)}=0,5.60=30\left(g\right)\)
⇒ \(m_{CH3COOH\left(tt\right)}=30.80\%=24\left(g\right)\)
Chúc bạn học tốt
\(C_6H_{12}O_6\underrightarrow{t^o}2C_2H_5OH+2CO_2\uparrow\)(xt : men rượu )
0,5 0,5
\(n_{CO_2}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\)
\(m_{C_2H_5OH}=0,5.46=23\left(g\right)\)
\(C_2H_5OH+O_2\underrightarrow{t^o}CH_3COOH+H_2O\) (men giấm )
0,5 0,5
\(m_{CH_3COOH}=0,5.60=30\left(g\right)\)
\(m_{CH_3COOHtt}=30.80\%=24\left(g\right)\)
a, \(C_2H_4+3O_2\underrightarrow{t^o}2CO_2+2H_2O\)
b, \(n_{C_2H_4}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
Theo PT: \(n_{CO_2}=2n_{C_2H_4}=0,4\left(mol\right)\)
\(\Rightarrow V_{CO_2}=0,4.22,4=8,96\left(l\right)\)
c, \(C_2H_4+H_2O\underrightarrow{xt}C_2H_5OH\)
\(n_{C_2H_5OH\left(LT\right)}=n_{C_2H_4}=0,2\left(mol\right)\)
\(\Rightarrow m_{C_2H_5OH\left(LT\right)}=0,2.46=9,2\left(g\right)\)
Mà: H = 80%
⇒ mC2H5OH (TT) = 9,2.80% = 7,36 (g)
d, nC2H5OH = 0,2.80% = 0,16 (mol)
PT: \(C_2H_5OH+O_2\underrightarrow{^{t^o,xt}}CH_3COOH+H_2O\)
_____0,16______________0,16 (mol)
\(2CH_3COOH+K_2CO_3\rightarrow2CH_3COOK+CO_2+H_2O\)
_______0,16___________________0,16_____0,08 (mol)
m dd sau pư = 7,36 + 200 - 0,08.44 = 203,84 (g)
\(\Rightarrow C\%_{CH_3COOK}=\dfrac{0,16.98}{203,84}.100\%\approx7,7\%\)