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![](https://rs.olm.vn/images/avt/0.png?1311)
Đáp án A
Giả sử chỉ có Zn ⇒ nZn = 0,09 mol ⇒ nHCl = 0,18 ⇒ V = 180 ml
Nếu chỉ có Mg ⇒ nMg = 0,24 mol ⇒ nHCl = 0,48 ⇒ V = 480 ml
⇒ 180 ml < VHCl < 480 ml
![](https://rs.olm.vn/images/avt/0.png?1311)
\(n_{HCl}=0,16.3,5=0,56\left(mol\right)\)
=> \(n_{H_2O}=\dfrac{0,56}{2}=0,28\left(mol\right)\)
=> nO = 0,28 (mol)
=> m = 16 + 0,28.16 = 20,48 (g)
\(n_{HCl}=0,16.3,5=0,56\left(mol\right)\\ n_{O\left(trong.oxit\right)}=n_{H_2O}=\dfrac{n_{HCl}}{2}=\dfrac{0,56}{2}=0,28\left(mol\right)\\ m=m_{hh.oxit}=m_{hhX}+0,28.16=16+4,48=20,48\left(g\right)\)
![](https://rs.olm.vn/images/avt/0.png?1311)
\(n_{HCl}=0,12.2=0,24\left(mol\right)\)
=> \(n_{H_2O}=0,12\left(mol\right)\)
=> \(n_{O\left(oxit\right)}=0,12\left(mol\right)\)
=> \(n_{O_2}=0,06\left(mol\right)\)
\(n_{Mg}=\dfrac{1,68}{24}=0,07\left(mol\right)\); \(n_{Al}=\dfrac{2,16}{27}=0,08\left(mol\right)\)
Gọi số mol Cl2 là x (mol)
Mg0 - 2e --> Mg+2
0,07->0,14
Al0 - 3e --> Al+3
0,08->0,24
O20 + 4e --> 2O-2
0,06->0,24
Cl20 + 2e --> 2Cl-
x--->2x
Bảo toàn e: 2x + 0,24 = 0,24 + 0,14
=> x = 0,07 (mol)
=> \(\%V_{Cl_2}=\dfrac{0,07}{0,06+0,07}.100\%=53,846\%\)
![](https://rs.olm.vn/images/avt/0.png?1311)
\(a,n_{H_2}=\dfrac{2,576}{22,4}=0,115\left(mol\right)\\ Đặt:n_{Mg}=a\left(mol\right);n_{Al}=b\left(mol\right)\left(a,b>0\right)\\ Mg+2HCl\rightarrow MgCl_2+H_2\\ 2Al+6HCl\rightarrow2AlCl_3+3H_2\\ \Rightarrow\left\{{}\begin{matrix}95a+133,5b=10,475\\a+1,5b=0,115\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,04\\b=0,05\end{matrix}\right.\\ \%m_{Mg}=\dfrac{0,04.24}{0,04.24+0,05.27}.100\approx41,558\%\Rightarrow\%m_{Al}\approx58,442\%\\ b,n_{HCl}=2.n_{H_2}=2.0,115=0,23\left(mol\right)\\ \Rightarrow x=C\%_{ddHCl}=\dfrac{0,23.36,5}{100}.100=8,395\%\)
![](https://rs.olm.vn/images/avt/0.png?1311)
mtăng=mO=3,33-2,13=1,2g
nO=1,2 : 16= 0,075 mol
nH2SO4 = nO(trong oxit)=0,075mol
VddHCl =0,075:2=0,0375 lit=37,5 ml
Ta có: \(m_{H_2SO_4}=90.98\%=88,2\left(g\right)\Rightarrow n_{H_2SO_4}=\dfrac{88,2}{98}=0,9\left(mol\right)\)
\(\Rightarrow n_{H^+}=0,9.2=1,8\left(mol\right)\)
Có: \(2H^++O^{2-}_{\left(trongoxit\right)}\rightarrow H_2O\)
\(\Rightarrow n_{O\left(trongoxit\right)}=\dfrac{1}{2}n_{H^+}=0,9\left(mol\right)\)
Mà: m oxit = mKL + mO (trong oxit) = 44 + 0,9.16 = 58,4 (g)
Cảm ơn bạn:33