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![](https://rs.olm.vn/images/avt/0.png?1311)
\(4Al + 3O_2 \xrightarrow{t^o} 2Al_2O_3\\ 3Fe + 2O_2 \xrightarrow{t^o} Fe_3O_4\\ Fe_3O_4 + 4H_2 \xrightarrow{t^o} 3Fe + 4H_2O\\ Ta\ có :\\ m_O = m_B - m_{hh} = 5,4 - 4,44 = 0,96(mol)\\ n_O = \dfrac{0,96}{32} = 0,03(mol)\\ \Rightarrow n_{Al_2O_3}= \dfrac{1}{3}n_O = 0,01(mol)\\ \Rightarrow n_{Al} = 2n_{Al_2O_3} = 0,02(mol)\\ m_{Al} = 0,02.54 = 1,08(gam)\\ m_{Fe} = 4,44 - 1,08 = 3,36(gam)\)
![](https://rs.olm.vn/images/avt/0.png?1311)
goi x, y la so mol cua Al, Cu
\(n_{O_2}=\dfrac{5,58}{22,4}\approx0,25\left(mol\right)\)
4Al + 3O2 \(\underrightarrow{t^o}\) 2Al2O3
de: x.........0,75x......0,5x
2Cu + O2 \(\underrightarrow{t^o}\) 2CuO
de: y......0,5y.......y
Ta co: 27x + 64y = 23,25
0,75x + 0,5y = 0,25
\(\Rightarrow x\approx0,13;y\approx0,31\)
a, \(m_{Al}=27.0,13\approx3,51g\)
\(\%m_{Al}=\dfrac{3,51}{23,25}.100\approx15,1g\)
\(\%m_{Cu}=100-15,1\approx84,9\%\)
b, \(m_{Al_2O_3}=102.0,5.0,13\approx6,63g\)
\(m_{CuO}=80.0,31\approx24,8g\)
mk thấy số mol hơi lẻ nên k bk đúng hay sai
![](https://rs.olm.vn/images/avt/0.png?1311)
a) Gọi số mol Al, Zn là 2a, a (mol)
PTHH: 4Al + 3O2 --to--> 2Al2O3
2a-->1,5a---------->a
2Zn + O2 --to--> 2ZnO
a---->0,5a------->a
=> \(102a+81a=18,3\)
=> a = 0,1 (mol)
=> \(\left\{{}\begin{matrix}\%m_{Al}=\dfrac{0,2.27}{0,2.27+0,1.65}.100\%=45,378\%\\\%m_{Zn}=\dfrac{0,1.65}{0,2.27+0,1.65}.100\%=54,622\%\end{matrix}\right.\)
b) \(n_{O_2}=1,5a+0,5a=0,2\left(mol\right)\)
=> \(V_{O_2}=0,2.22,4=4,48\left(l\right)\)
![](https://rs.olm.vn/images/avt/0.png?1311)
PTHH:
\(CuO+H_2\) \(\underrightarrow{t^o}\) \(Cu+H_2O\) \(\left(1\right)\)
\(Fe_2O_3+3H_2\) \(\underrightarrow{t^o}\) \(2Fe+3H_2O\) \(\left(2\right)\)
Số mol H2 là 0,6 mol
Gọi số mol H2 tham gia pư 1 là x mol \(\left(0,6>x>0\right)\)
Số mol H2 tham gia pư 2 là \(\left(0,6-x\right)mol\)
Theo PTHH 1:
\(n_{CuO}=n_{H_2}=x\left(mol\right)\)
Theo PTHH 2:
\(n_{Fe_2O_3}=\frac{1}{3}n_{H_2}=\left(0,6-x\right):3\left(mol\right)\)
Theo bài khối lượng hh là 40g
Ta có pt: \(80x+\left(0,6-x\right)160:3=40\)
Giải pt ta được \(x=0,3\)
Vậy \(n_{CuO}=0,3\left(mol\right);n_{Fe_2O_3}=0,1\left(mol\right)\)
\(\%m_{CuO}=\left(0,3.80.100\right):40=60\%\)
\(\%m_{Fe_2O_3}=\left(0,1.160.100\right):40=40\%\)
1)
PTHH: \(2Cu+O_2\) \(\underrightarrow{t^o}\) \(2CuO\)
x x
Gọi số mol Cu phản ứng là x mol ( x >0)
Chất rắn X gồm CuO và Cu
Ta có PT: 80x + 25,6 – 64x = 28,8
Giải PT ta được x = 0,2
Vậy khối lượng các chất trong X là:
\(m_{Cu}\) = 12,8 gam
\(m_{CuO}\) = 16 gam
2)
Gọi kim loại hoá trị II là A.
PTHH: \(A+2HCl\rightarrow ACl_2+H_2\)
Số mol \(H_2\)= 0,1 mol
Theo PTHH: \(n_A=n_{H_2}\)= 0,1 (mol)
Theo bài \(m_A\) = 2,4 gam \(\Rightarrow\) \(M_A\) = 2,4 : 0,1 = 24 gam
Vậy kim loại hoá trị II là Mg
![](https://rs.olm.vn/images/avt/0.png?1311)
Gọi số mol Al, Na trong a gam hỗn hợp là x, y (mol)
=> 27x + 23y = a (1)
PTHH: 4Al + 3O2 --to--> 2Al2O3
x---------------->0,5x
4Na + O2 --to--> 2Na2O
y---------------->0,5y
=> 102.0,5x + 62.0,5y = 1,64.a
=> 51x + 31y = 1,64a (2)
(1)(2) => 51x + 31y = 1,64(27x + 23y)
=> 6,72x = 6,72y
=> x = y
\(\left\{{}\begin{matrix}\%m_{Al}=\dfrac{27x}{27x+23y}.100\%=54\%\\\%m_{Na}=\dfrac{23y}{27x+23y}.100\%=46\%\end{matrix}\right.\)
![](https://rs.olm.vn/images/avt/0.png?1311)
- Đặt \(\left\{{}\begin{matrix}n_{Al}=a\left(mol\right)\\n_{Mg}=b\left(mol\right)\end{matrix}\right.\Rightarrow27a+24b=10,2\left(1\right)\)
Khí thu được sau p/ứ là khí H2: \(n_{H_2}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\)
\(2Al+6HCl\rightarrow2AlCl_3+3H_2\uparrow\)
2 3 (mol)
a 3/2 a (mol)
\(Mg+2HCl\rightarrow MgCl_2+H_2\uparrow\)
1 1 (mol)
b b (mol)
Từ hai PTHH trên ta có: \(\dfrac{3}{2}a+b=0,5\left(2\right)\)
\(\left(1\right),\left(2\right)\) ta có hệ: \(\left\{{}\begin{matrix}27a+24b=10,2\\\dfrac{3}{2}a+b=0,5\end{matrix}\right.\)
Giải ra ta có \(\left\{{}\begin{matrix}a=0,2\left(mol\right)\\b=0,2\left(mol\right)\end{matrix}\right.\)
a) \(\%Al=\dfrac{m_{Al}}{m_{hh}}.100\%=\dfrac{0,2.27}{10,2}.100\%\approx52,94\%\)
\(\%Mg=100\%-\%Al=100\%-52,94=47,06\%\)
b)
\(3H_2+Fe_2O_3\rightarrow^{t^0}2Fe+3H_2O\)
3 1 2 (mol)
0,5 1/6 1/3 (mol)
\(m_{Fe}=\dfrac{1}{3}.56=\dfrac{56}{3}\left(g\right)\)
\(m_{Fe_2O_3\left(pứ\right)}=\dfrac{1}{6}.160=\dfrac{80}{3}\left(g\right)\)
\(m_{Fe_2O_3\left(dư\right)}=60-m_{Fe}=60-\dfrac{56}{3}=\dfrac{124}{3}\left(g\right)\)
\(a=\dfrac{124}{3}+\dfrac{80}{3}=68\left(g\right)\)
![](https://rs.olm.vn/images/avt/0.png?1311)
a) PTHH : \(2Zn+O_2-t^o->2ZnO\)
b) \(n_{Zn}=\dfrac{19,5}{65}=0,3\left(mol\right)\)
Theo PTHH : \(n_{O2}=\dfrac{1}{2}n_{Zn}=0,15\left(mol\right)\)
=> \(V_{O2}=0,15.22,4=3,36\left(l\right)\)
c) Theo PTHH : \(n_{ZnO}=n_{Zn}=0,3\left(mol\right)\)
=> \(m_{ZnO}=0,3.81=24,3\left(g\right)\)
vậy ...
\(\begin{array}{l} a,\ PTHH:2Zn+O_2\xrightarrow{t^o} 2ZnO\\ b,\\ n_{Zn}=\dfrac{19,5}{65}=0,3\ (mol)\\ Theo\ pt:\ n_{O_2}=\dfrac{1}{2}n_{Zn}=0,15\ (mol)\\ \Rightarrow V_{O_2}=0,15\times 22,4=3,36\ (l)\\ c,\\ Theo\ pt:\ n_{ZnO}=n_{Zn}=0,3\ (mol)\\ \Rightarrow m_{ZnO}=0,3\times 81=24,3\ (g)\end{array}\)
![](https://rs.olm.vn/images/avt/0.png?1311)
a) PTHH: \(2CO+O_2\underrightarrow{t^o}2CO_2\) (1)
\(4H_2+O_2\underrightarrow{t^o}2H_2O\) (2)
b) Ta có: \(\left\{{}\begin{matrix}\Sigma n_{O_2}=\dfrac{9,6}{32}=0,3\left(mol\right)\\n_{CO_2}=\dfrac{8,8}{44}=0,2\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}n_{O_2\left(1\right)}=0,1mol\\n_{O_2\left(2\right)}=0,2mol\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}m_{CO}=0,1\cdot28=2,8\left(g\right)\\m_{H_2}=0,2\cdot2=0,4\left(g\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}\%m_{CO}=\dfrac{2,8}{2,8+0,4}\cdot100\%=87,5\%\\\%m_{H_2}=12,5\%\end{matrix}\right.\)
c) PTHH: \(2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\uparrow\)
Theo PTHH: \(n_{KMnO_4}=2n_{O_2}=0,6mol\)
\(\Rightarrow m_{KMnO_4}=0,6\cdot158=94,8\left(g\right)\)
2Ca + O2 \(\rightarrow\)2CaO (1)
2Zn + O2 \(\rightarrow\)2ZnO (2)
nO2=\(\dfrac{8}{32}=0,25\left(mol\right)\)
Đặt nCa=a
nZn=b
Ta có:
\(\left\{{}\begin{matrix}40a+65b=27,5\\0,5.\left(a+b\right)=0,25\end{matrix}\right.\)
=>a=0,2;b=0,3
mCa=40.0,2=8(g)
%mCa=\(\dfrac{8}{27,5}.100\%=29,1\%\)
%mZn=100-29,1=70,9%
b;
mchất rắn=mKL +mO=27,5+8=35,5(g)
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