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\(a,Đặt:n_{CH_4}=a\left(mol\right);n_{C_4H_{10}}=b\left(mol\right)\left(a,b>0\right)\\ PTHH:CH_4+2O_2\rightarrow\left(t^o\right)CO_2+2H_2O\\ 2C_4H_{10}+13O_2\rightarrow\left(t^o\right)8CO_2+10H_2O\\ \Rightarrow\left\{{}\begin{matrix}16a+58b=7,4\\22,4a+22,4.4b=22\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,1\\b=0,1\end{matrix}\right.\\ \Rightarrow\left\{{}\begin{matrix}m_{CH_4}=0,1.16=1,6\left(g\right)\\m_{C_4H_{10}}=0,1.58=5,8\left(g\right)\end{matrix}\right.\\ b,n_{O_2}=2a+\dfrac{13}{2}b=2.0,1+6,5.0,1=0,85\left(mol\right)\\ \Rightarrow V_{O_2\left(đktc\right)}=0,85.22,4=19,04\left(l\right)\)
a)
\(n_{O_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
\(n_{H_2O}=\dfrac{1,8}{18}=0,1\left(mol\right)\)
PTHH: 2H2 + O2 --to--> 2H2O
0,1<-0,05<-------0,1
2CO + O2 --to--> 2CO2
0,2<--0,1-------->0,2
=> \(\left\{{}\begin{matrix}V_{H_2}=0,1.22,4=2,24\left(l\right)\\V_{CO}=0,2.22,4=4,48\left(l\right)\end{matrix}\right.\)
b) \(m_{CO_2}=0,2.44=8,8\left(g\right)\)
\(n_{O_2}=\dfrac{3,36}{22,4}=0,15mol\)
\(n_{H_2O}=\dfrac{1,8}{18}=0,1mol\)
\(2CO+O_2\rightarrow2CO_2\)
a 0,5a a
\(2H_2+O_2\rightarrow2H_2O\)
0,1 0,05 \(\leftarrow\) 0,1
\(\Sigma n_{O_2}=0,5a+0,05=0,15\)
\(\Rightarrow a=n_{O_2\left(CO\right)}=0,2mol\)
\(V_{CO}=2\cdot0,2\cdot22,4=8,96l\)
\(V_{H_2}=0,1\cdot22,4=2,24l\)
\(m_{CO_2}=0,2\cdot44=8,8g\)
2KMnO4-to>K2MnO4+MnO2+O2
0,3-----------------0,15-----0,15------0,15 mol
n KMnO4=\(\dfrac{47,4}{158}\)=0,3 mol
=>mcr=0,15.197.0,15.87=42,6g
=>VO2=0,15.22,4=3,36l
b) 4P+5O2-to>2P2O5
0,1--------------0,05
nP=\(\dfrac{3,1}{31}\)=0,1 mol
->O2 dư
=>m P2O5=0,05.142=7,1g
mKMnO4 = 47,4/158 = 0,3 (mol)
PTHH: 2KMnO4 -> (t°) K2MnO4 + MnO2 + O2
Mol: 0,3 ---> 0,15 ---> 0,15 ---> 0,15
m = 0,15 . 197 + 0,15 . 87 = 85,2 (g)
V = VO2 = 0,15 . 22,4 = 3,36 (l)
nP = 3,1/31 = 0,1 (mol)
PTHH: 4P + 5O2 -> (t°) 2P2O5
LTL: 0,1/4 < 0,15/5 => O2 dư
nP2O5 = 0,1/2 = 0,05 (mol)
mP2O5 = 0,05 . 142 = 7,1 (g)
a)
\(n_{O_2} = \dfrac{11,2}{22,4} = 0,5(mol)\\ 4P + 5O_2 \xrightarrow{t^o} 2P_2O_5\\ n_P = \dfrac{4}{5}n_{O_2} = 0,4(mol)\\ \Rightarrow m_P = 0,4.31 = 12,4(gam)\)
b)
\(n_{P_2O_5} = \dfrac{2}{5}n_{O_2} = 0,2(mol)\\ \Rightarrow m_{P_2O_5} = 0,2.142 = 28,4(gam)\)
c)
\(2KMnO_4 \xrightarrow{t^o} K_2MnO_4 + MnO_2 + O_2\\ n_{KMnO_4} = 2n_{O_2} = 0,5.2 = 1(mol)\\ \Rightarrow m_{KMnO_4} = 1.158 = 158(gam)\)
\(n_{Cl_2}=a\left(mol\right),n_{O_2}=b\left(mol\right)\)
\(n_{hh}=a+b=0.25\left(mol\right)\left(1\right)\)
BTKL :
\(m_{khí}=23-7.2=15.8\left(g\right)\)
\(\Rightarrow71a+32b=15.8\left(2\right)\)
\(\left(1\right),\left(2\right):a=0.2,b=0.05\)
\(2M+nCl_2\underrightarrow{^{^{t^0}}}2MCl_n\)
\(4M+nO_2\underrightarrow{^{^{t^0}}}2M_2O_n\)
\(n_M=\dfrac{0.4}{n}+\dfrac{0.2}{n}=\dfrac{0.6}{n}\left(mol\right)\)
\(M_M=\dfrac{7.2}{\dfrac{0.6}{n}}=12n\)
\(n=2\Rightarrow M=24\)
\(M:Mg\)
Gọi $n_{Cl_2} = a ; n_{O_2} = b \Rightarrow a + b = 0,25(1)$
Bảo toàn khối lượng :
$7,2 + 71a + 32b = 23(2)$
Từ (1)(2) suy ra a = 0,2 ; b = 0,05
Gọi n là hóa trị M
$2M + nCl_2 \to 2MCl_n$
$4M + nO_2 \xrightarrow{t^o} 2M_2O_n$
Theo PTHH :
$n_M = \dfrac{2}{n}n_{Cl_2} + \dfrac{4}{n}n_{O_2} = \dfrac{0,6}{n}$
$\Rightarrow \dfrac{0,6}{n}.M = 7,2$
$\Rightarrow M = 12n$
Với n = 2 thì $M = 24(Magie)$
a)
Theo ĐLBTKL: \(m_{Fe\left(bđ\right)}+m_{O_2}=m_X\)
=> \(m_{O_2}=26,4-20=6,4\left(g\right)\)
=> \(n_{O_2}=\dfrac{6,4}{32}=0,2\left(mol\right)\Rightarrow V=0,2.22,4=4,48\left(l\right)\)
b)
PTHH: 3Fe + 2O2 --to--> Fe3O4
0,2------->0,1
=> \(\%m_{Fe_3O_4}=\dfrac{0,1.232}{26,4}.100\%=87,88\%\)
c)
- Nếu dùng KClO3
PTHH: 2KClO3 --to--> 2KCl + 3O2
\(\dfrac{0,4}{3}\)<-----------------0,2
=> \(m_{KClO_3}=\dfrac{0,4}{3}.122,5=\dfrac{49}{3}\left(g\right)\)
- Nếu dùng KMnO4:
PTHH: 2KMnO4 --to--> K2MnO4 + MnO2 + O2
0,4<--------------------------------0,2
=> \(m_{KMnO_4}=0,4.158=63,2\left(g\right)\)
a) \(n_{SO_2}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\)
PTHH: S + O2 --to--> SO2
0,5<-0,5<------0,5
=> mS = 0,5.32 = 16(g)
=> \(\left\{{}\begin{matrix}\%m_S=\dfrac{16}{22,2}.100\%=72,07\%\\\%m_P=\dfrac{22,2-16}{22,2}.100\%=27,93\%\end{matrix}\right.\)
b) \(n_P=\dfrac{22,2-16}{31}=0,2\left(mol\right)\)
PTHH: 4P + 5O2 --to--> 2P2O5
0,2-->0,25----->0,1
=> \(V_{O_2}=0,25.22,4=5,6\left(l\right)\)
c)
PTHH: 2KClO3 --to--> 2KCl + 3O2
0,5<-------------------0,75
=> \(m_{KClO_3}=0,5.122,5=61,25\left(g\right)\)
a) PTHH:
\(S+O_2\rightarrow\left(t^o\right)SO_2\\ 4P+5O_2\rightarrow\left(t^o\right)2P_2O_5\)
- Chất khí mùi hắc là SO2
- Chất rắn sau phản ứng có m(g) là P2O5
Đặt: nS=a(mol); nP=b(mol) (a,b>0) (nguyên, dương)
\(\Rightarrow\left\{{}\begin{matrix}32a+31b=22,2\\22,4a=11,2\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,5\\b=0,2\end{matrix}\right.\\ \Rightarrow\left\{{}\begin{matrix}\%m_S=\dfrac{0,5.32}{22,2}.100\approx72,072\%\\\%m_P\approx100\%-72,072\%\approx27,928\%\end{matrix}\right.\)
b)
\(n_{O_2}=a+\dfrac{5}{4}b=0,5+\dfrac{5}{4}.0,2=0,75\left(mol\right)\\ \Rightarrow V_{O_2\left(đktc\right)}=0,75.22,4=16,8\left(l\right)\)
c)
\(2KClO_3\rightarrow\left(t^o\right)2KCl+3O_2\\ n_{KClO_3}=\dfrac{2}{3}.n_{O_2}=\dfrac{2.0,75}{3}=0,5\left(mol\right)\\ \Rightarrow m_{KClO_3}=122,5.0,5=61,25\left(g\right)\)