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![](https://rs.olm.vn/images/avt/0.png?1311)
Gọi $n_{Al}= a(mol) ; n_{Fe} = b(mol) \Rightarrow 27a + 56b = 4,44(1)$
$4Al + 3O_2 \xrightarrow{t^o} 2Al_2O_3$
$3Fe + 2O_2 \xrightarrow{t^o} Fe_3O_4$
$Fe_3O_4 + 4H_2 \xrightarrow{t^o} 3Fe + 4H_2O$
B gồm : $Al_2O_3, Fe$
$n_{Al_2O_3} = \dfrac{1}{2}n_{Al} = 0,5a(mol)$
Suy ra: $0,5a.102 + 56b = 5,4(2)$
Từ (1)(2) suy ra a = 0,04 ; b = 0,06
$m_{Al} = 0,04.27 =1,08\ gam$
$m_{Fe} = 0,06.56 = 3,36\ gam$
![](https://rs.olm.vn/images/avt/0.png?1311)
a)
A: H2O
B: O2
C: Al, Al2O3
D: AlCl3, HCl
E: H2
\(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\); \(n_{O_2}=\dfrac{3,584}{22,4}=0,16\left(mol\right)\)
PTHH: 2H2 + O2 --to--> 2H2O
0,2-->0,1------->0,2
=> mH2O(A) = 0,2.18 = 3,6 (g)
\(n_{O_2\left(dư\right)}=0,16-0,1=0,06\left(mol\right)\)
PTHH: 4Al + 3O2 --to--> 2Al2O3
0,08<-0,06------>0,04
=> \(\left\{{}\begin{matrix}m_{Al_2O_3\left(C\right)}=0,04.102=4,08\left(g\right)\\m_{Al\left(C\right)}=2,7-0,08.27=0,54\left(g\right)\end{matrix}\right.\)
b)
nHCl = 0,1.4 = 0,4 (mol)
\(n_{Al\left(C\right)}=\dfrac{0,54}{27}=0,02\left(mol\right)\)
PTHH: 2Al + 6HCl --> 2AlCl3 + 3H2
0,02->0,06---->0,02-->0,03
Al2O3 + 6HCl --> 2AlCl3 + 3H2O
0,04-->0,24---->0,08
=> \(D\left\{{}\begin{matrix}AlCl_3:0,02+0,08=0,1\left(mol\right)\\HCl\left(dư\right):0,4-0,06-0,24=0,1\left(mol\right)\end{matrix}\right.\)
=> \(\left\{{}\begin{matrix}C_{M\left(AlCl_3\right)}=\dfrac{0,1}{0,1}=1M\\C_{M\left(HCl.dư\right)}=\dfrac{0,1}{0,1}=1M\end{matrix}\right.\)
c) VO2(B) = 0,06.22,4 = 1,344 (l)
VH2(E) = 0,03.22,4 = 0,672 (l)
![](https://rs.olm.vn/images/avt/0.png?1311)
B : $CuO,Na_2O,Ag,BaO,Fe_3O_4$
$2Cu + O_2 \xrightarrow{t^o} 2CuO$
$4Na + O_2 \xrightarrow{t^o} 2Na_2O$
$2Ba + O_2 \xrightarrow{t^o} 2BaO$
$3Fe + 2O_2 \xrightarrow{t^o} Fe_3O_4$
C : $Cu,Na_2O,Ag,BaO,Fe$
$CuO + H_2 \xrightarrow{t^o} Cu + H_2O$
$Fe_3O_4 + 4H_2 \xrightarrow{t^o} 3Fe + 4H_2O$
D : $Cu,Ag,Fe$ ; E : $NaOH,Ba(OH)_2$
$Na_2O + H_2O \to 2NaOH$
$BaO + H_2O \to Ba(OH)_2$
F : Ag,Cu ; T : $HCl,FeCl_2$
$Fe + 2HCl \to FeCl_2 + H_2$
![](https://rs.olm.vn/images/avt/0.png?1311)
a) \(n_{Al}=\dfrac{10,8}{27}=0,4\left(mol\right)\)
PTHH: 2Al + 6HCl --> 2AlCl3 + 3H2
0,4---------------------->0,6
=> V = 0,6.22,4 = 13,44 (l)
b)
\(n_{Fe_3O_4}=\dfrac{29}{232}=0,125\left(mol\right)\)
Gọi số mol Fe3O4 pư là a (mol)
PTHH: Fe3O4 + 4H2 --to--> 3Fe + 4H2O
Xét tỉ lệ: \(\dfrac{0,125}{1}< \dfrac{0,6}{4}\) => Hiệu suất tính theo Fe3O4
PTHH: Fe3O4 + 4H2 --to--> 3Fe + 4H2O
a----------------->3a
=> 232(0,125-a) + 56.3a = 22,6
=> a = 0,1
=> \(H\%=\dfrac{0,1}{0,125}.100\%=80\%\)
nAl = 10,8 : 27 = 0,4 (mol)
pthh : Al + 6HCl-t--> AlCl3 + H2
0,4--->2,4 (mol)
=> V= VO2 = 2,4 . 22,4 = 53,76 ( l)
nFe3O4 = 29 : 232 = 0,125 (mol)
pthh Fe3O4 + 4H2 -t--> 3Fe+ 4H2O
0,125----------------->0,375 (mol)
nFe (tt ) = 22,6 : 56 = 0,403 (mol )
%H = 0,375 / 0,403 . 100 % = 93 %
![](https://rs.olm.vn/images/avt/0.png?1311)
a, nFe = 16,8/56 = 0,3 (mol)
PTHH: Fe + 2HCl -> FeCl2 + H2
Mol: 0,3 ---> 0,6 ---> 0,3 ---> 0,3
VH2 = 0,3 . 22,4 = 6,72 (l)
b, nCuO = 20/80 = 0,25 (mol)
PTHH: CuO + H2 -> (t°) Cu + H2O
LTL: 0,25 < 0,3 => H2 dư
Gọi nCuO (p/ư) = a (mol)
=> nCu (sinh ra) = a (mol)
Ta có: 80(0,25 - a) + 64a = 16,4
=> a = 0,225 (mol)
H = 0,225/0,25 = 90%
a, PTHH:
2Cu + O2 -> (t°) 2CuO (1)
CuO + H2 -> (t°) Cu + H2O (2)
2Na + 2H2O -> 2NaOH + H2 (3)
2H2 + O2 -> (t°) 2H2O (4)
b, A: CuO: đồng (II) oxit
B: Cu: đồng
C: H2O: nước
D: H2: hiđro
F: O2: oxi
c, nCu = 12,8/64 = 0,2 (mol)
Theo (1): nCuO = nCu = 0,2 (mol)
Theo (2): nH2O = nCuO = 0,2 (mol)
Theo (3): nH2 = nH2O/2 = 0,2/2 = 0,1 (mol)
Theo (4): nH2O = nH2 = 0,1 (mol)
mH2O = 0,1 . 18 = 1,8 (g)