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Giả sử các khí đo ở điều kiện sao cho 1 mol khí chiếm thể tích V lít
Gọi số mol CH4, C2H2 là a, b (mol)
=> \(a+b=\dfrac{0,05}{V}\) (1)
\(n_{O_2}=\dfrac{0,11}{V}\left(mol\right)\)
PTHH: CH4 + 2O2 --to--> CO2 + 2H2O
a-->2a---------->a
2C2H2 + 5O2 --to--> 4CO2 + 2H2O
b--->2,5b-------->2b
=> \(2a+2,5b=\dfrac{0,11}{V}\) (2)
(1)(2) => \(\left\{{}\begin{matrix}a=\dfrac{0,03}{V}\left(mol\right)\\b=\dfrac{0,02}{V}\left(mol\right)\end{matrix}\right.\)
=> \(\left\{{}\begin{matrix}\%V_{CH_4}=\dfrac{\dfrac{0,03}{V}.V}{0,05}.100\%=60\%\\\%V_{C_2H_2}=\dfrac{\dfrac{0,02}{V}.V}{0,05}.100\%=40\%\end{matrix}\right.\)
b) \(n_{CO_2}=a+2b=\dfrac{0,07}{V}\left(mol\right)\)
=> \(V_{CO_2}=\dfrac{0,07}{V}.V=0,07\left(l\right)\)
\(\left\{{}\begin{matrix}n_{CH_4}=a\left(mol\right)\\n_{C_2H_4}=b\left(mol\right)\end{matrix}\right.\)\(\Rightarrow a + b = \dfrac{3,36}{22,4} = 0,15(1) \)
\(CH_4 + 2O_2 \xrightarrow{t^o} CO_2 + 2H_2O\\ C_2H_4 + 3O_2 \xrightarrow{t^o} 2CO_2 + 2H_2O\\ n_{CO_2} = a + 2b = \dfrac{4,48}{22,4} = 0,2(2)\)
Từ (1)(2) suy ra: a = 0,1 ; b = 0,05
Suy ra:
\(\%V_{CH_4} = \dfrac{0,1}{0,15}.100\% = 66,67\%\\ \%V_{C_2H_4} = 100\% - 66,67\% = 33,33\%\)
b)
\(C_2H_4 + Br_2 \to C_2H_4Br_2\\ n_{Br_2} = n_{C_2H_4} = 0,05(mol)\\ \Rightarrow m_{Br_2} = 0,05.160 = 8\ gam\)
\(a.C_2H_5OH+3O_2-^{t^o}\rightarrow2CO_2+3H_2O\\ n_{C_2H_5OH}=0,3\left(mol\right)\\ n_{CO_2}=2n_{C_2H_5OH}=0,6\left(mol\right)\\ \Rightarrow V_{CO_2}=0,6.22,4=13,44\left(l\right)\\ b.n_{O_2}=3n_{C_2H_5OH}=0,6\left(mol\right)\\ MàV_{O_2}=\dfrac{1}{5}V_{kk}\\ \Rightarrow V_{kk}=V_{O_2}.5=0,6.22,4.5=67,2\left(l\right)\\ c.n_{NaOH}=0,9\left(mol\right)\\ Tacó:\dfrac{n_{NaOH}}{n_{CO_2}}=\dfrac{0,9}{0,6}=1,5\\ \Rightarrow Tạora2muốiNaHCO_3vàNa_2CO_3\\ Đặt:n_{NaHCO_3}=x\left(mol\right);n_{Na_2CO_3}=y\left(mol\right)\\ \Rightarrow\left\{{}\begin{matrix}x+y=0,6\left(BTnguyento\left(C\right)\right)\\x+2y=0,9\left(BTnguyento\left(Na\right)\right)\end{matrix}\right.\\ \Rightarrow\left\{{}\begin{matrix}x=0,3\\y=0,3\end{matrix}\right.\\ \Rightarrow m_{muối}=0,3.84+0,3.106=57\left(g\right)\)
Gọi số mol CO, CH4 là a, b (mol)
=> \(a+b=\dfrac{5,6}{22,4}=0,25\left(mol\right)\)
\(n_{O_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
PTHH: 2CO + O2 --to--> 2CO2
a--->0,5a
CH4 + 2O2 --to--> CO2 + 2H2O
b--->2b
=> 0,5a + 2b = 0,2
=> a = 0,2 (mol); b = 0,05 (mol)
=> \(\left\{{}\begin{matrix}\%V_{CO}=\dfrac{0,2}{0,25}.100\%=80\%\\\%V_{CH_4}=\dfrac{0,05}{0,25}.100\%=20\%\end{matrix}\right.\)
\(n_{hh}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\\ n_{O_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\\ 2CO+O_2\rightarrow\left(t^o\right)2CO_2\\ CH_4+2O_2\rightarrow\left(t^o\right)CO_2+2H_2O\\ Đặt:n_{CO}=a\left(mol\right);n_{CH_4}=b\left(mol\right)\left(a,b>0\right)\\ \Rightarrow\left\{{}\begin{matrix}a+b=0,25\\0,5a+2b=0,2\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,2\\b=0,05\end{matrix}\right.\\ \Rightarrow\%V_{\dfrac{CO}{hh}}=\%n_{\dfrac{CO}{hh}}=\dfrac{a}{a+b}.100\%=\dfrac{0,2}{0,25}.100=80\%;\%V_{CH_4}=100\%-80\%=20\%\)
\(n_{C_2H_4}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\\ C_2H_4+3O_2\rightarrow\left(t^o\right)2CO_2+2H_2O\\ a,n_{O_2}=3.0,5=1,5\left(mol\right)\\ V_{O_2\left(đktc\right)}=1,5.22,4=33,6\left(l\right)\\ V_{kk\left(đktc\right)}=33,6.5=168\left(l\right)\\ b,n_{CO_2}=n_{H_2O}=2.0,5=1\left(mol\right)\\ m_{CO_2}=44.1=44\left(g\right);m_{H_2O}=18.1=18\left(g\right)\\ c,CO_2+Ca\left(OH\right)_2\rightarrow CaCO_3+H_2O\\ n_{Ca\left(OH\right)_2}=n_{CO_2}=1\left(mol\right)\\ m_{Ca\left(OH\right)_2}=1.74=74\left(g\right)\\ m_{ddCa\left(OH\right)_2}=\dfrac{74.100}{10}=740\left(g\right)\)
a, \(CH_4+2O_2\underrightarrow{^{t^o}}CO_2+2H_2O\)
\(C_2H_4+3O_2\underrightarrow{^{t^o}}2CO_2+2H_2O\)
b, Gọi: \(\left\{{}\begin{matrix}n_{CH_4}=x\left(mol\right)\\n_{C_2H_4}=y\left(mol\right)\end{matrix}\right.\) \(\Rightarrow x+y=\dfrac{4,48}{22,4}=0,2\left(mol\right)\left(1\right)\)
Theo PT: \(n_{O_2}=2n_{CH_4}+3n_{C_2H_4}=2x+3y=\dfrac{15,68}{22,4}=0,7\left(mol\right)\left(2\right)\)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}x=-0,1\\y=0,3\end{matrix}\right.\)
Đến đây thì ra số mol âm, bạn xem lại đề nhé.